Exam 2: Structure and Properties of Organic Molecules

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Which functional groups below indicate the presence of two atoms connected by a triple bond?

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What kind on molecular orbital (σ, σ*, π, or π*) results when the two atomic orbitals shown below interact in the manner indicated? What kind on molecular orbital (σ, σ<sup>*</sup>, π, or π<sup>*</sup>) results when the two atomic orbitals shown below interact in the manner indicated?

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How many π bonds are present in the molecule shown? How many π bonds are present in the molecule shown?

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What kind of molecular orbital (σ, σ*, π, or π*) results when the two atomic orbitals shown below interact in the manner indicated? What kind of molecular orbital (σ, σ<sup>*</sup>, π, or π<sup>*</sup>) results when the two atomic orbitals shown below interact in the manner indicated?

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What is the approximate value of any HCC bond angle in H2C=CHCCl3?

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Which of the following functional groups is  not \textbf{ not } present in the HIV protease inhibitor drug called Saquinavir?

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Are the two compounds shown below best described as  cis-trans isomers, constitutional isomers, ‾\underline{\text{ cis-trans isomers, constitutional isomers, }} or  not isomeric? ‾\underline{\text{ not isomeric? }}  Are the two compounds shown below best described as  \underline{\text{ cis-trans isomers, constitutional isomers, }}    or  \underline{\text{   not isomeric? }}

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Circle the coplanar atoms in 1-ethylcyclopentene shown below. Circle the coplanar atoms in 1-ethylcyclopentene shown below.

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The HCC bond angle in allene (H2C=C=CH2) is approximately what?

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Vildagliptin is a recently released antidiabetic drug (J. Med. Chem. 2010, 7902). How many degrees of unsaturation are in Vildagliptin? Vildagliptin is a recently released antidiabetic drug (J. Med. Chem. 2010, 7902). How many degrees of unsaturation are in Vildagliptin?

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What is the approximate value of the CCC bond angle in CH3CH2CH2OH?

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The molecule shown below contains ________ sigma bonds and ________ pi bonds. The molecule shown below contains ________ sigma bonds and ________ pi bonds.

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Are the two compounds shown below best described as  cis-trans isomers, constitutional isomers, ‾\underline{\text{ cis-trans isomers, constitutional isomers, }} or  not isomeric? ‾\underline{\text{ not isomeric? }}  Are the two compounds shown below best described as  \underline{\text{  cis-trans isomers, constitutional isomers,  }}  or  \underline{\text{ not isomeric?  }}

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Provide the skeletal structures of the five constitutional isomers with molecular formula C6H14.

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Which of the molecules below is an ester?

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Choose the correct hybridization for the atom indicated in the molecule below. CH3CH2CH2CH3 ↑

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How many sp hybridized carbon atoms are present in the molecule shown? How many sp<sup> </sup>hybridized carbon atoms are present in the molecule shown?

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Are the two compounds shown below best described as cis-trans isomers, constitutional isomers, or not isomeric? Are the two compounds shown below best described as cis-trans isomers, constitutional isomers, or not isomeric?

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Which of the following statements is correct?

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Are the two compounds shown below best described as cis-trans isomers, constitutional isomers, ‾\underline{\text{cis-trans isomers, constitutional isomers, }} or  not isomeric? ‾\underline{\text{ not isomeric? }}  Are the two compounds shown below best described as  \underline{\text{cis-trans isomers, constitutional isomers,   }}   or \underline{\text{ not isomeric?  }}

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