Exam 15: Principles of Chemical Equilibrium

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Two moles of NH3 are initially present for the reaction: 2 NH3(g) ⇌ N2(g) + 3 H2(g) At equilibrium there is 1.00 mol NH3. How many moles of H2 are present at equilibrium?

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Choose the correct statement about a container in which the chemical equilibrium is established: 2 SO2(g) + O2(g) ⇌ 2 SO3(g) + heat

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For CO2(g) + H2(g) ⇌ CO(g) + H2O(g), Kc = [CO][H2]/[CO2][H2], if there are 1.43 mols each of CO and H2, 0.572 mol H2 and 4.572 mols CO2, in a 4.0 L container at equilibrium, what is Kc?

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Consider the equilibrium system: N2O4(g) ⇌ 2 NO2(g) for which Kp = 0.1134 at 25°C and ΔH°rxn = 58.03 kJ/mol. Assuming that the total pressure inside the container is 1.00 atm at equilibrium and that initially only N2O4 was present inside the container, compute PNO2 at equilibrium.

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Consider the following equilibrium reaction: PCl3(g) + Cl2(g) ⇌ PCl5(g) Kc = 96.2 The equilibrium constant for the decomposition of PCl5(g) to PCl3(g) and Cl2(g) is ________.

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Which of the following keep the equilibrium position unchanged?

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Choose the correct statement about the equilibrium: N2(g) + 3 H2(g) ⇌ 2 NH3(g), Kp = 1 × 10-4 atm-2

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Changes in temperature cause change in the equilibrium position.

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For the reaction: H2(g) + I2(g) ⇌ 2 HI(g), Kc = 92.0 When equilibrium concentrations of HI and I2 are [HI] = 0.115 M and [I2] = 0.250 M, the equilibrium concentration of [H2] is:

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Consider the following gas phase reaction at 25°C. N2(g) + C2H2(g) ⇌ 2 HCN(g) 600 mol N2(g) and 1.750 mol C2H2(g) are placed in a 1.000 L vessel and the mixture is allowed to react. At equilibrium, there are 1.587 mol N2(g) in the mixture. What is Kc for this reaction at 25 °C?

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Given the following reactions, 2PCl3(g) ⇌ 2P(g) + 3Cl2(g) Kc = 0.0667 PCl3(g) + Cl2(g) ⇌ PCl5(g) Kc = 4.0 Calculate Kc for the reaction below. 2P(g) + 5Cl2(g) ⇌ 2PCl5(g)

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Write the equilibrium constant expression for the reaction: 3 Sn(s) + 4 HNO3(aq) + H2O(l) ⇌ 3 H2SnO3(s) + 4 NO(g)

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For the reaction: CH4(g) + 2 H2O(g) ⇌ CO2(g) + 4 H2(g) ΔH° = +190 kJ when catalyst is added:

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For the following reaction O2(g) ⇌ 2O(g) What conditions favor production of oxygen atoms?

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Write the equilibrium expression Kc for the reaction: sodium sulfite(aq) + chloric acid (aq) ⇌ sodium chlorite(aq) + sulfur dioxide(g) + water(l).

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Consider the equilibrium system: N2O4(g) ⇌ 2NO2(g) for which Kp = 0.1134 at 25°C and ΔH°rxn = 58.03 kJ/mol. Assuming that the total pressure inside the container is 10 atm at equilibrium and that initially only N2O4 was present inside the container, compute PNO2 at equilibrium.

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At 35°C, Kp = 0.315 for the reaction N2O4(g) ⇌ 2 NO2(g), if the initial pressure of NO2(g) in a container is 3.00 atm, what is the equilibrium pressure of N2O4(g)?

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A mixture containing 0.0392 M A(g) and 0.0452 M B(g) is allowed to come to equilibrium at 300 K. The reaction: 3 A(g) + 2 B(g) ⇌ C(g) + D(g) occurs. At equilibrium, [C] = 0.00128 M. What is the value of Kc?

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Write the equilibrium constant expression for the following reaction: 2 KI(aq) + H2O2(aq) ⇌ 2 KOH(aq) + I2(aq)

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For the reaction: 2 Cl2(g) + 2 H2O(g) ⇌ 4 HCl(g) + O2(g), Kp = 6.4 × 10-6 at 500 K. If a fixed volume is filled with initial concentrations of these gases at 227°C such that [Cl2] = 0.5 M, [H2O] = 0.40 M, [HCl] = 0.5 M, and [O2] = 0.015 M, in which direction will the reaction proceed?

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