Exam 15: Principles of Chemical Equilibrium
Exam 1: Matter - Its Properties and Measurement94 Questions
Exam 2: Atoms and the Atomic Theory100 Questions
Exam 3: Chemical Compounds100 Questions
Exam 4: Chemical Reactions100 Questions
Exam 5: Introduction to Reactions in Aqueous Solutions97 Questions
Exam 6: Gases100 Questions
Exam 7: Thermochemistry101 Questions
Exam 8: Electrons in Atoms100 Questions
Exam 9: The Periodic Table and Some Atomic Properties96 Questions
Exam 10: Chemical Bonding I: Basic Concepts97 Questions
Exam 11: Chemical Bonding II: Additional Aspects97 Questions
Exam 12: Intermolecular Forces: Liquids and Solids102 Questions
Exam 13: Solutions and Their Physical Properties100 Questions
Exam 14: Chemical Kinetics92 Questions
Exam 15: Principles of Chemical Equilibrium99 Questions
Exam 16: Acids and Bases100 Questions
Exam 17: Additional Aspects of Acid-Base Equilibria99 Questions
Exam 18: Solubility and Complex-Ion Equilibria95 Questions
Exam 19: Spontaneous Change: Entropy and Free Energy101 Questions
Exam 20: Electrochemistry103 Questions
Exam 21: Main Group Elements I: Groups 1, 2, 13, and 14116 Questions
Exam 22: Main Group Elements II: Groups 18, 17, 16, 15, and Hydrogen100 Questions
Exam 23: The Transition Elements102 Questions
Exam 24: Complex Ions and Coordination Compounds100 Questions
Exam 25: Nuclear Chemistry 1-41100 Questions
Exam 26: Structures of Organic Compounds96 Questions
Exam 27: Reactions of Organic Compounds94 Questions
Exam 28: Chemistry of the Living State99 Questions
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For the reaction CO(g) + 3 H2(g) ⇌ H2O(g) + CH4(g) , Kc = 190 at 1000 K. If a vessel is filled with these gases such that the initial concentrations are [CO] = 0.025, [H2] = 0.045, [H2O] = 0.025, and [CH4] = 0.046M, in which direction will a reaction occur and why?
(Multiple Choice)
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Consider the following reaction: POCl3(g) ⇌ POCl(g) + Cl2(g) Kc = 0.450
A sample of pure POCl3(g) was placed in a reaction vessel and allowed to decompose according to the above reaction. At equilibrium, the concentrations of POCl(g) and Cl2(g) were each 0.150 M. What was the initial concentration of POCl3(g)?
(Multiple Choice)
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4.000 mol chlorine and 2.000 mol bromine were placed in a 50.0 L container and kept at 293 K until equilibrium was achieved for the reaction: Br2(l) + Cl2(g) ⇌ 2 BrCl(g)
At the point of equilibrium there were 82.63 g of Br2(ℓ). Determine the total pressure in the 50.0 L container at equilibrium.
(Multiple Choice)
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What is the value for Kc if [CO] = 0.025, [H2] = 0.013 and [CH3OH] = 0.0028 for the following reaction? CH3OH(g) ⇌ CO(g) + 2 H2(g)
(Multiple Choice)
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For the reaction PCl5 (g) ⇌ PCl3 (g) + Cl2 (g) Kc = 0.0454 at 261°C. If a vessel is filled with these gases such that the initial concentrations are [PCl5] = 0.2 M, [PCl3] = 0.20 M, and [Cl2] = 2.25 M, in which direction will a reaction occur and why?
(Multiple Choice)
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In the reaction: 2 N2O(g) + N2H4(g) ⇌ 3 N2(g) + 2 H2O(g),
One starts with 0.10 mol N2O and 0.25 mol N2H4 in a 10.0 L container. If there are 0.06 mol N2O at equilibrium, how many moles of N2 are present?
(Multiple Choice)
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4.000 mol chlorine and 2.000 mol bromine were placed in a 50.0 L container and kept at 293 K until equilibrium was achieved for the reaction: Br2(l) + Cl2(g) ⇌ BrCl(g)
At the point of equilibrium there were 82.63 g of Br2(l). Compute the value of Kc for this reaction.
(Multiple Choice)
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For the reaction: CH4(g) + 2H2O(g) ⇌ CO2(g) + 4H2(g) ΔH° = +190 kJ add H2(g):
(Multiple Choice)
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For the reaction: CH4(g) + 2 H2O(g) ⇌ CO2(g) + 4 H2(g) ΔH° = +190 kJ raise the temperature to 1200 K:
(Multiple Choice)
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Consider the following reaction at a certain temperature. 2SO3(g) ⇌ 2SO2(g) + O2(g)
When the initial concentration of SO3(g) is 0.128 M, the concentration of oxygen gas at equilibrium is found to be 0.0130 M. Calculate Kc for this reaction.
(Multiple Choice)
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Consider the following equation: N2O4(g) ⇌ 2 NO2(g) Kc = 5.8 × 10-3
If the initial concentration of N2O4(g) = 0.040 M and the initial concentration of NO2(g) is 0 M, what is the equilibrium concentration of N2O4(g)?
(Multiple Choice)
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Write the equilibrium constant expression for the following reaction: 6 CO2(g) + 6 H2O(l) ⇌ C6H12O6(s) + 6 O2(g)
(Multiple Choice)
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What is the equilibrium constant expression for: 4 NH3(g) + 5 O2(g) ⇌ 4 NO(g) + 6 H2O(g)
(Multiple Choice)
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Consider the reaction: CH4(g) + 4 Cl2(g) ⇌ CCl4(l) + 4 HCl(g) ΔH° -398 kJ/mol
The equilibrium is displaced to the right if:
(Multiple Choice)
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Consider the equilibrium system: N2O4(g) ⇌ 2 NO2(g) for which Kp = 0.1134 at 25°C and ΔH°rxn = 58.03 kJ/mol. Assume that 1 mole of N2O4 and 2 moles of NO2 are introduced into a 5.0 liter container. What will be the equilibrium value of [N2O]?
(Multiple Choice)
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Consider the equilibrium system: N2O4(g) ⇌ 2 NO2(g) for which Kp = 0.1134 at 25°C and ΔH°rxn = 58.03 kJ/mol. Assuming that the total pressure inside the container is 1.00 atm at equilibrium and that initially only N2O4 was present inside the container, compute PN2O4 at equilibrium.
(Multiple Choice)
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Consider the equilibrium system: N2O4(g) ⇌ 2 NO2(g) for which Kp = 0.1134 at 25°C and ΔH°rxn = 58.03 kJ/mol. Assuming that the total pressure inside the container is 10 atm at equilibrium and that initially only N2O4 was present inside the container, compute PN2O4 at equilibrium.
(Multiple Choice)
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