Exam 14: Electrochemistry

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If the standard free energy change for combustion of 1 mole of CH4(g)is -818 kJ.mol-1,calculate the standard voltage that could be obtained from a fuel cell using this reaction.

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A cell that uses bromine to oxidize hydrogen to H+ under standard conditions at 298 K has a negative potential?

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If E ∘\circ for the following cell is 0.36 V at 25 ∘\circ C Pb(s)|PbSO4(s)|SO42-(aq,0.60 M)m H+(aq,0.70 M)|H2(g,192.5 kPa)|Pt How is the Nernst equation for the cell properly expressed at this temperature?

(Multiple Choice)
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What is E for the half-reaction below? H2(g,1.00 atm) →\rightarrow 2H+(aq,1.00 M)+ 2e-

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The products of the electrolysis of CuSO4(aq)are

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Calculate E ∘\circ for the following cell. Zn(s)|Zn2+(aq)m Cl-(aq)|AgCl(s)|Ag(s)

(Multiple Choice)
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The standard potential of the cell Pb(s)|PbSO4(s)|SO42-(aq)m Pb2+(aq)|Pb(s) Is +0.23 V at 25 ∘\circ C.Calculate the Ksp of PbSO4.

(Multiple Choice)
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If 8686 C of charge is passed through molten magnesium chloride,calculate the number of moles of Mg(l)produced.

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Use the following diagram of a cell to answer questions Use the following diagram of a cell to answer questions   -In the cell shown above,A is a standard Ag<sup>+</sup>/Ag electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is +0.80 V,what is the equation for the cell reaction? -In the cell shown above,A is a standard Ag+/Ag electrode connected to a standard hydrogen electrode (SHE).If the voltmeter reading is +0.80 V,what is the equation for the cell reaction?

(Multiple Choice)
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The standard voltage of the cell Pt|H2(g)|H+(aq)m Cl-(aq)|AgCl(s)|Ag(s) Is +0.22 V at 25 ∘\circ C.Calculate the equilibrium constant for the reaction below. 2AgCl(s)+ H2(g) →\rightarrow 2Ag(s)+ 2H+(aq)+ 2Cl-(aq)

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Consider the reaction: 2Ag+(aq)+ Cu(s) →\rightarrow Cu2+(aq)+ 2Ag(s) If the standard potentials of Ag+ and Cu2+ are +0.80 V and +0.34 V,respectively,calculate the value of E ∘\circ for the given reaction.

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Which of the following is the strongest reducing agent?

(Multiple Choice)
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If the standard potential for Ti3+(aq)/Ti2+(aq)is -0.37 V and the standard potential for Ti2+(aq)/Ti(s)is -1.63 V,calculate the standard potential for Ti3+(aq)+ 3e- →\rightarrow Ti(s).

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Consider the following cell: Ag(s)|Ag+(aq,0.100 M)mAg+(aq,0.100 M)|Ag(s) What is the voltage of this cell?

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How many electrons appear in the balanced half reaction: NO3-(aq)F →\rightarrow NO(g),in acidic solution?

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Which of the following occurs when HCl(aq),Cu(s),and Fe(s)are mixed under standard conditions?

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Which species will reduce Br2 but not V3+?

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How long will it take to deposit 0.00235 moles of gold by electrolysis of KAuCl4(aq)using a current of 0.214 amperes?

(Multiple Choice)
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Use the following to answer questions Use the following to answer questions   -The galvanic cell shown above uses the half-cells Pb<sup>2+</sup>/Pb and Zn<sup>2+</sup>/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or lead. -The galvanic cell shown above uses the half-cells Pb2+/Pb and Zn2+/Zn,and a salt bridge containing KCl(aq).The voltmeter gives a positive voltage reading.The electrode B could be inert platinum metal or lead.

(True/False)
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Given the half reaction: NO3-(aq) →\rightarrow NO(g),in acidic solution,how many electrons appear in the half-reaction when it is properly balanced?

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