Exam 15: Chemical Equilibrium

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Acetic acid is a weak acid that dissociates into the acetate ion and a proton in aqueous solution: HC2H3O2 (aq) Acetic acid is a weak acid that dissociates into the acetate ion and a proton in aqueous solution: HC<sub>2</sub>H<sub>3</sub>O<sub>2</sub> (aq)   C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup> (aq)+ H<sup>+</sup> (aq) At equilibrium at 25 °C a 0.100 M solution of acetic acid has the following concentrations: [HC<sub>2</sub>H<sub>3</sub>O<sub>2</sub>] = 0.0990 M, [C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup>] = 1.33 × 10<sup>-3</sup> M, and [H<sup>+</sup>] = 1.33 × 10<sup>-3</sup> M. The equilibrium constant, K<sub>eq</sub>, for the ionization of acetic acid at 25°C is __________. C2H3O2- (aq)+ H+ (aq) At equilibrium at 25 °C a 0.100 M solution of acetic acid has the following concentrations: [HC2H3O2] = 0.0990 M, [C2H3O2-] = 1.33 × 10-3 M, and [H+] = 1.33 × 10-3 M. The equilibrium constant, Keq, for the ionization of acetic acid at 25°C is __________.

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Which of the following expressions is the correct equilibrium-constant expression for the reaction below? CO2 (s)+ H2O (l) Which of the following expressions is the correct equilibrium-constant expression for the reaction below? CO<sub>2</sub> (s)+ H<sub>2</sub>O (l)   H<sup>+</sup> (aq)+ HCO<sub>3</sub><sup>-</sup> (aq) H+ (aq)+ HCO3- (aq)

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The Keq for the equilibrium below is 5.4 × 1013 at 480.0°C. 2NO (g)+ O2 (g) The K<sub>eq</sub> for the equilibrium below is 5.4 × 10<sup>13</sup> at 480.0°C. 2NO (g)+ O<sub>2</sub> (g)   2NO<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? NO<sub>2</sub> (g)   NO (g)+ 1/2 O<sub>2</sub> (g) 2NO2 (g) What is the value of Keq at this temperature for the following reaction? NO2 (g) The K<sub>eq</sub> for the equilibrium below is 5.4 × 10<sup>13</sup> at 480.0°C. 2NO (g)+ O<sub>2</sub> (g)   2NO<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? NO<sub>2</sub> (g)   NO (g)+ 1/2 O<sub>2</sub> (g) NO (g)+ 1/2 O2 (g)

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The effect of a catalyst on a chemical reaction is to react with product, effectively removing it and shifting the equilibrium to the right.

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Kp = 0.0198 at 721 K for the reaction 2HI (g) K<sub>p</sub> = 0.0198 at 721 K for the reaction 2HI (g)   H<sub>2</sub> (g)+ I<sub>2</sub> (g) In a particular experiment, the partial pressures of H<sub>2</sub> and I<sub>2</sub> at equilibrium are 0.836 and 0.701 atm, respectively. The partial pressure of HI is __________ atm. H2 (g)+ I2 (g) In a particular experiment, the partial pressures of H2 and I2 at equilibrium are 0.836 and 0.701 atm, respectively. The partial pressure of HI is __________ atm.

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Of the following equilibria, only __________ will shift to the left in response to a decrease in volume.

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In which of the following reactions would increasing pressure at constant temperature change the concentrations of reactants and products, based on Le Châteliers principle?

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Consider the following chemical reaction: CO (g)+ 2H2 (g) Consider the following chemical reaction: CO (g)+ 2H<sub>2</sub> (g)   CH<sub>3</sub>OH(g) At equilibrium in a particular experiment, the concentrations of CO and H<sub>2</sub> were 0.15 M and0.36 M,respectively. What is the equilibrium concentration of CH<sub>3</sub>OH? The value of K<sub>eq</sub> for this reaction is 14.5 at the temperature of the experiment. CH3OH(g) At equilibrium in a particular experiment, the concentrations of CO and H2 were 0.15 M and0.36 M,respectively. What is the equilibrium concentration of CH3OH? The value of Keq for this reaction is 14.5 at the temperature of the experiment.

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The number obtained by substituting starting reactant and product concentrations into an equilibrium-constant expression is known as the __________.

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The relationship between the concentrations of reactants and products of a system at equilibrium is given by the law of mass action.

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Phosphorous trichloride and phosphorous pentachloride equilibrate in the presence of molecular chlorine according to the reaction: PCl3 (g)+ Cl2 (g) Phosphorous trichloride and phosphorous pentachloride equilibrate in the presence of molecular chlorine according to the reaction: PCl<sub>3</sub> (g)+ Cl<sub>2</sub> (g)   PCl<sub>5</sub> (g) An equilibrium mixture at 450 K contains PPCl<sub>3</sub> = 0.124 atm, PCl<sub>2</sub> = 0.157 atm, and PPCl<sub>5</sub> = 1.30 atm. What is the value of K<sub>p</sub> at this temperature? PCl5 (g) An equilibrium mixture at 450 K contains PPCl3 = 0.124 atm, PCl2 = 0.157 atm, and PPCl5 = 1.30 atm. What is the value of Kp at this temperature?

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The equilibrium-constant expression for a reaction written in one direction is the __________ of the one for the reaction written for the reverse direction.

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