Exam 15: Chemical Equilibrium

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At elevated temperatures, molecular hydrogen and molecular bromine react to partially form hydrogen bromide: H2 (g)+ Br2 (g) At elevated temperatures, molecular hydrogen and molecular bromine react to partially form hydrogen bromide: H<sub>2</sub> (g)+ Br<sub>2 </sub>(g)   2HBr (g) A mixture of 0.682 mol of H<sub>2</sub> and 0.440 mol of Br<sub>2</sub> is combined in a reaction vessel with a volume of 2.00 L. At equilibrium at 700 K, there are 0.556 mol of H<sub>2</sub> present. At equilibrium, there are __________ mol of Br<sub>2</sub> present in the reaction vessel. 2HBr (g) A mixture of 0.682 mol of H2 and 0.440 mol of Br2 is combined in a reaction vessel with a volume of 2.00 L. At equilibrium at 700 K, there are 0.556 mol of H2 present. At equilibrium, there are __________ mol of Br2 present in the reaction vessel.

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The Keq for the equilibrium below is 7.52 × 10-2 at 480.0°C. 2Cl2 (g)+ 2H2O (g) The K<sub>eq</sub> for the equilibrium below is 7.52 × 10<sup>-2</sup> at 480.0°C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 4HCl (g)+ O<sub>2</sub> (g)   2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g) 4HCl (g)+ O2 (g) What is the value of Keq at this temperature for the following reaction? 4HCl (g)+ O2 (g) The K<sub>eq</sub> for the equilibrium below is 7.52 × 10<sup>-2</sup> at 480.0°C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 4HCl (g)+ O<sub>2</sub> (g)   2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g) 2Cl2 (g)+ 2H2O (g)

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The equilibrium-constant expression depends on the __________ of the reaction.

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The equilibrium constant for reaction 1 is K. The equilibrium constant for reaction 2 is __________. (1)SO2 (g)+ (1/2)O2 (g) The equilibrium constant for reaction 1 is K. The equilibrium constant for reaction 2 is __________. (1)SO<sub>2</sub> (g)+ (1/2)O<sub>2</sub> (g)   SO<sub>3</sub> (g) (2)2SO<sub>3</sub> (g)   2SO<sub>2</sub> (g)+ O<sub>2</sub> (g) SO3 (g) (2)2SO3 (g) The equilibrium constant for reaction 1 is K. The equilibrium constant for reaction 2 is __________. (1)SO<sub>2</sub> (g)+ (1/2)O<sub>2</sub> (g)   SO<sub>3</sub> (g) (2)2SO<sub>3</sub> (g)   2SO<sub>2</sub> (g)+ O<sub>2</sub> (g) 2SO2 (g)+ O2 (g)

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The expression for Kp for the reaction below is __________. 4CuO (s)+ CH4 (g) The expression for K<sub>p</sub> for the reaction below is __________. 4CuO (s)+ CH<sub>4</sub> (g)   CO<sub>2</sub> (g)+ 4Cu (s)+ 2H<sub>2</sub>O (g) CO2 (g)+ 4Cu (s)+ 2H2O (g)

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The Keq for the equilibrium below is 7.52 × 10-2 at 480.0°C. 2Cl2 (g)+ 2H2O (g) The K<sub>eq</sub> for the equilibrium below is 7.52 × 10<sup>-2</sup> at 480.0°C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2HCl (g)+   O<sub>2</sub> (g)   Cl<sub>2</sub> (g)+ H<sub>2</sub>O (g) 4HCl (g)+ O2 (g) What is the value of Keq at this temperature for the following reaction? 2HCl (g)+ The K<sub>eq</sub> for the equilibrium below is 7.52 × 10<sup>-2</sup> at 480.0°C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2HCl (g)+   O<sub>2</sub> (g)   Cl<sub>2</sub> (g)+ H<sub>2</sub>O (g) O2 (g) The K<sub>eq</sub> for the equilibrium below is 7.52 × 10<sup>-2</sup> at 480.0°C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2HCl (g)+   O<sub>2</sub> (g)   Cl<sub>2</sub> (g)+ H<sub>2</sub>O (g) Cl2 (g)+ H2O (g)

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For the endothermic reaction CaCO3 (s) For the endothermic reaction CaCO<sub>3</sub> (s)   CaO (s)+ CO<sub>2</sub> (g) Le Châtelier's principle predicts that __________ will result in an increase in the number of moles of CO<sub>2</sub>. CaO (s)+ CO2 (g) Le Châtelier's principle predicts that __________ will result in an increase in the number of moles of CO2.

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If the reaction quotient Q for a reaction is less than the value of the equilibrium constant K for that reaction at a given temperature, __________ must be converted to __________ for the system to reach equilibrium.

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Which of the following expressions is the correct equilibrium-constant expression for the equilibrium between dinitrogen tetroxide and nitrogen dioxide? N2O4 (g) Which of the following expressions is the correct equilibrium-constant expression for the equilibrium between dinitrogen tetroxide and nitrogen dioxide? N<sub>2</sub>O<sub>4</sub> (g)   2NO<sub>2</sub> (g) 2NO2 (g)

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At 1000.0 K, the equilibrium constant for the reaction 2NO (g)+ Br2 (g) At 1000.0 K, the equilibrium constant for the reaction 2NO (g)+ Br<sub>2</sub> (g)   2NOBr (g) Is K<sub>p</sub> = 0.017. Calculate K<sub>p</sub> for the reverse reaction, 2NOBr (g)   2NO (g)+ Br<sub>2 </sub>(g). 2NOBr (g) Is Kp = 0.017. Calculate Kp for the reverse reaction, 2NOBr (g) At 1000.0 K, the equilibrium constant for the reaction 2NO (g)+ Br<sub>2</sub> (g)   2NOBr (g) Is K<sub>p</sub> = 0.017. Calculate K<sub>p</sub> for the reverse reaction, 2NOBr (g)   2NO (g)+ Br<sub>2 </sub>(g). 2NO (g)+ Br2 (g).

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A reaction vessel is charged with hydrogen iodide, which partially decomposes to molecular hydrogen and iodine: 2HI (g) A reaction vessel is charged with hydrogen iodide, which partially decomposes to molecular hydrogen and iodine: 2HI (g)   H<sub>2</sub>(g)+ I<sub>2</sub>(g) When the system comes to equilibrium at 425 °C, P<sub>HI</sub> = 0.708 atm, and PH<sub>2</sub> = PI<sub>2</sub> = 0.0960 atm. The value of K<sub>p</sub> at this temperature is __________. H2(g)+ I2(g) When the system comes to equilibrium at 425 °C, PHI = 0.708 atm, and PH2 = PI2 = 0.0960 atm. The value of Kp at this temperature is __________.

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The value of Keq for the equilibrium N2 (g)+ O2 (g) The value of K<sub>eq</sub> for the equilibrium N<sub>2</sub> (g)+ O<sub>2</sub> (g)   2 NO (g) Is 4.2 × 10<sup>-31</sup> at 27 °C. What is the value of K<sub>eq</sub> for the equilibrium below? 4 NO (g)   2 N<sub>2</sub> (g)+ 2 O<sub>2</sub> (g) 2 NO (g) Is 4.2 × 10-31 at 27 °C. What is the value of Keq for the equilibrium below? 4 NO (g) The value of K<sub>eq</sub> for the equilibrium N<sub>2</sub> (g)+ O<sub>2</sub> (g)   2 NO (g) Is 4.2 × 10<sup>-31</sup> at 27 °C. What is the value of K<sub>eq</sub> for the equilibrium below? 4 NO (g)   2 N<sub>2</sub> (g)+ 2 O<sub>2</sub> (g) 2 N2 (g)+ 2 O2 (g)

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Consider the following reaction at equilibrium: 2CO2 (g) Consider the following reaction at equilibrium: 2CO<sub>2</sub> (g)   2CO (g)+ O<sub>2</sub> (g)ΔH° = -514 kJ Le Châtelier's principle predicts that an increase in temperature will __________. 2CO (g)+ O2 (g)ΔH° = -514 kJ Le Châtelier's principle predicts that an increase in temperature will __________.

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The Keq for the equilibrium below is 7.73 × 10-2 at 500.0°C. 2Cl2 (g)+ 2H2O (g) The K<sub>eq</sub> for the equilibrium below is 7.73 × 10<sup>-2</sup> at 500.0°C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? Cl<sub>2</sub> (g)+ H<sub>2</sub>O (g)   2HCl (g)+   O<sub>2</sub> (g) 4HCl (g)+ O2 (g) What is the value of Keq at this temperature for the following reaction? Cl2 (g)+ H2O (g) The K<sub>eq</sub> for the equilibrium below is 7.73 × 10<sup>-2</sup> at 500.0°C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? Cl<sub>2</sub> (g)+ H<sub>2</sub>O (g)   2HCl (g)+   O<sub>2</sub> (g) 2HCl (g)+ The K<sub>eq</sub> for the equilibrium below is 7.73 × 10<sup>-2</sup> at 500.0°C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? Cl<sub>2</sub> (g)+ H<sub>2</sub>O (g)   2HCl (g)+   O<sub>2</sub> (g) O2 (g)

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In which of the following reactions would increasing pressure at constant temperature not change the concentrations of reactants and products, based on Le Châtelier's principle?

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The Keq for the equilibrium below is 5.4 × 1013 at 480.0°C. 2NO (g)+ O2 (g) The K<sub>eq</sub> for the equilibrium below is 5.4 × 10<sup>13</sup> at 480.0°C. 2NO (g)+ O<sub>2</sub> (g)   2NO<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 4NO (g)+ 2O<sub>2</sub> (g)   4NO<sub>2</sub> (g) 2NO2 (g) What is the value of Keq at this temperature for the following reaction? 4NO (g)+ 2O2 (g) The K<sub>eq</sub> for the equilibrium below is 5.4 × 10<sup>13</sup> at 480.0°C. 2NO (g)+ O<sub>2</sub> (g)   2NO<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 4NO (g)+ 2O<sub>2</sub> (g)   4NO<sub>2</sub> (g) 4NO2 (g)

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Consider the following reaction at equilibrium: C (s)+ H2O (g) Consider the following reaction at equilibrium: C (s)+ H<sub>2</sub>O (g)   CO (g)+ H<sub>2</sub> (g) Which of the following conditions will increase the partial pressure of CO? CO (g)+ H2 (g) Which of the following conditions will increase the partial pressure of CO?

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The value of Keq for the following reaction is 0.25: SO2 (g)+ NO2 (g) The value of K<sub>eq</sub> for the following reaction is 0.25: SO<sub>2</sub> (g)+ NO<sub>2</sub> (g)   SO<sub>3</sub> (g)+ NO (g) The value of K<sub>eq</sub> at the same temperature for the reaction below is __________. 2SO<sub>2</sub> (g)+ 2NO<sub>2</sub> (g)   2SO<sub>3</sub> (g)+ 2NO (g) SO3 (g)+ NO (g) The value of Keq at the same temperature for the reaction below is __________. 2SO2 (g)+ 2NO2 (g) The value of K<sub>eq</sub> for the following reaction is 0.25: SO<sub>2</sub> (g)+ NO<sub>2</sub> (g)   SO<sub>3</sub> (g)+ NO (g) The value of K<sub>eq</sub> at the same temperature for the reaction below is __________. 2SO<sub>2</sub> (g)+ 2NO<sub>2</sub> (g)   2SO<sub>3</sub> (g)+ 2NO (g) 2SO3 (g)+ 2NO (g)

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Given the following reaction at equilibrium at 300.0 K: NH4HS (s) Given the following reaction at equilibrium at 300.0 K: NH<sub>4</sub>HS (s)   NH<sub>3</sub> (g)+ H<sub>2</sub>S (g) If pNH<sub>3</sub> = pH<sub>2</sub>S = 0.109 atm, K<sub>p</sub> = __________. NH3 (g)+ H2S (g) If pNH3 = pH2S = 0.109 atm, Kp = __________.

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The value of Keq for the equilibrium H2 (g)+ I2 (g) The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g)+ I<sub>2</sub> (g)   2 HI (g) Is 54.0 at 427°C. What is the value of K<sub>eq</sub> for the equilibrium below? HI (g)   1/2 H<sub>2</sub> (g)+ 1/2 I<sub>2</sub> (g) 2 HI (g) Is 54.0 at 427°C. What is the value of Keq for the equilibrium below? HI (g) The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g)+ I<sub>2</sub> (g)   2 HI (g) Is 54.0 at 427°C. What is the value of K<sub>eq</sub> for the equilibrium below? HI (g)   1/2 H<sub>2</sub> (g)+ 1/2 I<sub>2</sub> (g) 1/2 H2 (g)+ 1/2 I2 (g)

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