Exam 20: Electrochemistry

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Table 20.1 Half Reaction E°(V) F2 (g) + 2e- → 2F- (aq)+2.87 Cl2 (g) + 2e- → 2Cl- (aq)+1.359 Br2 (l) + 2e- → 2Br- (aq)+1.065 O2 (g) + 4H+ (aq) + 4e- → 2H2O (l) +1.23 Ag+ + e- → Ag (s)+0.799 Fe3+ (aq) + e- → Fe2+ (aq)+0.771 I2 (s) + 2e- → 2I- (aq)+0.536 Cu2+ + 2e- → Cu (s)+0.34 2H+ + 2e- → H2 (g) 0 Pb2+ + 2e- → Pb (s)-0.126 Ni2+ + 2e- → Ni (s)-0.28 Li+ + e- → Li (s)-3.05 -Which of the halogens in Table 20.1 is the strongest oxidizing agent?

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In a half reaction, the amount of a substance that is reduced or oxidized is directly proportional to the number of electrons generated in the cell.

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One of the differences between a voltaic cell and an electrolytic cell is that in an electrolytic cell, ________.

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Galvanized iron is iron coated with ________.

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The lead-containing reactant(s)consumed during recharging of a lead-acid battery is/are ________.

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Which element is reduced in the reaction below? Fe2+ + H+ + Cr2O72- → Fe3+ + Cr3+ + H2O

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Which substance is serving as the reducing agent in the following reaction? 14H+ + Cr2O72- + 3Ni → 3Ni2+ + 2Cr3+ + 7H2O

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________ is the oxidizing agent in the reaction below. Cr2O72- + 6S2O32- + 14H+ → 2Cr3+ + 3S4O62- + 7H2O

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Which element is reduced in the following reaction? Fe2S3 + 12HNO3 → 2Fe(NO3)3 + 3S + 6NO2 + 6H2O

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Table 20.1 Half Reaction E°(V) F2 (g) + 2e- → 2F- (aq)+2.87 Cl2 (g) + 2e- → 2Cl- (aq)+1.359 Br2 (l) + 2e- → 2Br- (aq)+1.065 O2 (g) + 4H+ (aq) + 4e- → 2H2O (l) +1.23 Ag+ + e- → Ag (s)+0.799 Fe3+ (aq) + e- → Fe2+ (aq)+0.771 I2 (s) + 2e- → 2I- (aq)+0.536 Cu2+ + 2e- → Cu (s)+0.34 2H+ + 2e- → H2 (g) 0 Pb2+ + 2e- → Pb (s)-0.126 Ni2+ + 2e- → Ni (s)-0.28 Li+ + e- → Li (s)-3.05 -Which one of the following types of elements is most likely to be a good oxidizing agent?

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The major product of a hydrogen fuel cell is ________.

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What is the coefficient of Fe3+ when the following equation is balanced? CN- + Fe3+ → CNO- + Fe2+ (basic solution)

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Table 20.2 Table 20.2   -The standard cell potential (E°<sub>cell</sub>)for the voltaic cell based on the reaction below is ________ V. 3Sn<sup>4+</sup> (aq) + 2Cr (s) → 2Cr<sup>3+</sup> (aq) + 3Sn<sup>2+</sup> (aq) -The standard cell potential (E°cell)for the voltaic cell based on the reaction below is ________ V. 3Sn4+ (aq) + 2Cr (s) → 2Cr3+ (aq) + 3Sn2+ (aq)

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In the electrochemical cell using the redox reaction below, the cathode half-reaction is ________. 2H+ (s) + Sn (s) → Sn2+ (aq) + H2 (g)

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In the galvanic cell using the redox reaction below, the reduction half-reaction is ________. Zn (s) + Cu2+ (aq) → Zn2+ (aq) + Cu (s)

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The electrode where reduction occurs is called the anode.

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How many grams of Ca metal are produced by the electrolysis of molten CaBr2 using a current of 30.0 amp for 8.0 hours?

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How many grams of Cu are obtained by passing a current of 12 A through a solution of CuSO4 for 15 minutes?

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What is the oxidation number of sulfur in the S2O32- ion?

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How many kilowatt-hours of electricity are used to produce 4.50 kg of magnesium in the electrolysis of molten MgCl2 with an applied emf of 5.00 V?

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