Exam 12: Organic Acids and Bases

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Which of the following solutions is most likely to have the highest pH?

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C

In the formation of a thioester bond, the involved hydrogen atoms:

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B

When propanthiol (structure shown below) ionizes in water, a product of the reaction is: CH3-CH2-CH2-SH

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C

What is the basis for classifying amines as primary, secondary, or tertiary?

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Consider the structures given below. Consider the structures given below.   Fill in the blanks with appropriate letter (A,B,C,D,E,F). -Structure ___________________ would exist as a positive ion at pH 4. Fill in the blanks with appropriate letter (A,B,C,D,E,F). -Structure ___________________ would exist as a positive ion at pH 4.

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Using structural formulas, write the equation for the ionization of p-cresol (show below) in water. Using structural formulas, write the equation for the ionization of p-cresol (show below) in water.

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The following compound undergoes oxidative decarboxylation using coenzyme A (CoA) as the thiol. The following compound undergoes oxidative decarboxylation using coenzyme A (CoA) as the thiol.   Which of the following is a product of this reaction? Which of the following is a product of this reaction?

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The following compounds are constitutional isomers. Which has the lowest boiling point?

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Consider the structures given below. Consider the structures given below.   Fill in the blanks with appropriate letter (A,B,C,D,E,F). -Structure__________________ and structure _______________ could react to form ethyldimethylammonium propanoate. Fill in the blanks with appropriate letter (A,B,C,D,E,F). -Structure__________________ and structure _______________ could react to form ethyldimethylammonium propanoate.

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The following illustrates an amine acting as hydrogen bond donor with water. The following illustrates an amine acting as hydrogen bond donor with water.

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The amine shown below is a tertiary amine. The amine shown below is a tertiary amine.

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The name of the following alkylammonium salt is: The name of the following alkylammonium salt is:

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What is the name of the following substance? CH3-NH-CH2−CH2-CH3

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The following compound contains a thioester bond. The following compound contains a thioester bond.

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Which of the following solutions is most likely to have the lowest pH?

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One of the necessary components for fatty acid synthesis is a complex of malonic acid (shown below) and CoA. One of the necessary components for fatty acid synthesis is a complex of malonic acid (shown below) and CoA.   The structure of this complex at physiological pH would be:  The structure of this complex at physiological pH would be: One of the necessary components for fatty acid synthesis is a complex of malonic acid (shown below) and CoA.   The structure of this complex at physiological pH would be:

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Consider the structures given below. Consider the structures given below.   Fill in the blanks with appropriate letter (A,B,C,D,E,F). -Structure __________________ is a secondary amine. Fill in the blanks with appropriate letter (A,B,C,D,E,F). -Structure __________________ is a secondary amine.

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The salt of propanoic acid and the sodium ion would be named as sodium propanoate.

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Draw the structure of the products of both steps of the oxidative decarboxylation of the following substance in the presence of coenzyme A. Use CoA to represent the portion of the molecule that does not change in the reaction. Draw the structure of the products of both steps of the oxidative decarboxylation of the following substance in the presence of coenzyme A. Use CoA to represent the portion of the molecule that does not change in the reaction.

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Which of the following compounds would be the most likely to undergo decarboxylation when simply heated?

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