Exam 18: Electrochemistry

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Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of Cd and Ag+ in the balanced reaction? Cd(s)+ Ag+(aq)→ Ag(s)+ Cd2+(aq)

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Nickel can be plated from aqueous solution according to the following half reaction.How long would it take (in minutes)to plate 29.6 g of nickel at 4.7 A? Ni2+(aq)+ 2 e⁻ → Ni(s)

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A voltaic cell is constructed with two silver-silver chloride electrodes,where the half-reaction is AgCl(s)+ e- → Ag(s)+ Cl-(aq)E° = +0.222 V The concentrations of chloride ion in the two compartments are 0.0222 M and 2.22 M,respectively.The cell emf is ________ V.

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Which of the following is the strongest reducing agent? Which of the following is the strongest reducing agent?

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What is undergoing reduction in the redox reaction represented by the following cell notation? Fe(s)∣ Fe3+(aq)∣∣ Cl2(g)∣ Cl⁻(aq)∣ Pt

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Use the tabulated half-cell potentials below to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. Pb2+(aq)+ Cu(s)→ Pb(s)+ Cu2+(aq) Use the tabulated half-cell potentials below to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. Pb<sup>2+</sup>(aq)+ Cu(s)→ Pb(s)+ Cu<sup>2+</sup>(aq)

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Why,if we multiply a reaction by 2,don't we multiply its E°red by 2?

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What is the shorthand notation that represents the following galvanic cell reaction? Pb(s)+ Cu(NO3)2(aq)→ Pb(NO3)2(aq)+ Cu(s)

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The most useful ore of aluminum is bauxite,in which Al is present as hydrated oxides,Al2O3 · xH2O The number of kilowatt-hours of electricity required to produce 4.00 kg of aluminum from electrolysis of compounds from bauxite is ________ when the applied emf is 5.00 V.

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Which of the following reactions would have the smallest value of K at 298 K?

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How many grams of nickel metal are plated out when a constant current of 15.0 A is passed through aqueous NiCl2 for 60.0 minutes?

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The electrolysis of molten AlCl3 for 3.25 hr with an electrical current of 15.0 A produces ________ g of aluminum metal.

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How many electrons are transferred in the following reaction? (The reaction is unbalanced. ) Fe2+(aq)+ K(s)→ Fe(s)+ K+(aq)

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For the galvanic cell reaction,expressed below using shorthand notation,what half-reaction occurs at the cathode? Zn(s)∣ Zn2+(aq)∣∣ Ni2+(aq)∣ Ni(s)

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Using the following standard reduction potentials, Fe3+(aq)+ e- → Fe2+(aq)E° = +0.77 V Ni2+(aq)+ 2 e- → Ni(s)E° = -0.26 V Calculate the standard cell potential for the galvanic cell reaction given below,and determine whether or not this reaction is spontaneous under standard conditions. Ni2+(aq)+ 2 Fe2+(aq)→ 2 Fe3+(aq)+ Ni(s)

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Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Al(s)∣ Al3+(aq,0.115 M)∣∣ Al3+(aq,3.89 M)∣ Al(s) Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Al(s)∣ Al<sup>3+</sup>(aq,0.115 M)∣∣ Al<sup>3+</sup>(aq,3.89 M)∣ Al(s)

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For a galvanic cell that uses the following two half-reactions, Cr2O72-(aq)+ 14 H+(aq)+ 6 e- → 2 Cr3+(aq)+ 7 H2O(l) Pb(s)→ Pb2+(aq)+ 2 e- How many moles of Pb(s)are oxidized by three moles of Cr2O72-?

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Determine the cell notation for the redox reaction given below. Sn(s)+ 2 Ag⁺(aq)→ Sn2+(aq)+ 2 Ag(s)

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Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Al and F2 in the balanced reaction? Al(s)+ F2(g)→ Al3+(aq)+ F-(aq)

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Determine which of the following pairs of reactants will result in a spontaneous reaction at 25°C.

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