Exam 6: Thermochemistry

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According to the following thermochemical equation,what mass of H2O (in g)must form in order to produce 975 kJ of energy? SiO2(s)+ 4 HF(g)→ SiF4(g)+ 2 H2O(l)ΔH°rxn = -184 kJ

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D

Use the information provided to determine ΔH°rxn for the following reaction: ΔH°f (kJ/mol)3 Fe2O3(s)+ CO(g)→ 2 Fe3O4(s)+ CO2(g)ΔH°rxn = ? kJ Fe2O3(s)-824 Fe3O4(s)-1118 CO(g)-111 CO2(g)-394

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C

A sample of 5.23 kg of aluminum absorbs heat,which raises the temperature 50.0°C.Determine the amount of heat absorbed,in kJ,if the specific heat capacity of aluminum is 0.903 J/g°C.

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C

Give the temperature and pressure for the standard state for a liquid.

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A 6.55 g sample of aniline (C6H5NH2,molar mass = 93.13 g/mol)was combusted in a bomb calorimeter with a heat capacity of 14.25 kJ/°C.If the initial temperature was 32.9°C,use the information below to determine the value of the final temperature of the calorimeter. 4 C6H5NH2(l)+ 35 O2(g)→ 24 CO2(g)+ 14 H2O(g)+ 4 NO2(g) ΔH°rxn = -1.28 × 104 kJ

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Identify an energy source that is not renewable.

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Which of the following is true if ΔEsys = -95 J?

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Which of the following processes is endothermic?

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When 50.0 mL of 0.400 M Ca(NO3)2 is added to 50.0 mL of 0.800 M NaF,CaF2 precipitates,as shown in the net ionic equation below.The initial temperature of both solutions is 23.0°C.Assuming that the reaction goes to completion,and that the resulting solution has a mass of 100.00 g and a specific heat of 4.18 J/(g ∙ °C),calculate the final temperature of the solution. Ca2+(aq)+ 2 F-(aq)→ CaF2(s)ΔH° = -11.5 kJ

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Describe the energy changes that occur when a book is held 6 ft off the floor and then dropped.

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An exothermic reaction has

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Explain the difference between ΔH and ΔE.

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Calculate the standard enthalpy of sublimation (Δsub H°)at 298K for water using the following thermochemical equations H2O(s)= H2O(l);Δfus H° = +6.1 kJ mol-1 H2O(l)= H2O(g);Δvap H° = +44.0 kJ mol-1

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At constant pressure,the combustion of 15.0 g of C2H6(g)releases 777 kJ of heat.Calculate ΔH for the reaction given below. 2 C2H6(g)+ 7 O2(g)→ 4 CO2(g)+ 6 H2O(l)

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A block of metal initially at 70°C is submerged in water initially at 25°C in a coffee cup.Which of the following is true?

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A 50.0-g sample of liquid water at 25.0°C is mixed with 29.0 g of water at 45.0°C.The final temperature of the water is ________°C.

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Using the following equation for the combustion of octane,calculate the heat of reaction for 100.0 g of octane.The molar mass of octane is 114.33 g/mole. 2 C8H18 + 25 O2 → 16 CO2 + 18 H2O ΔH°rxn = -11018 kJ

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Which of the following statements is true?

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When 0.455 g of anthracene,C14H10,is combusted in a bomb calorimeter that has a water jacket containing 500.0 g of water,the temperature of the water increases by 8.63°C.Assuming that the specific heat of water is 4.18 J/(g ∙ °C),and that the heat absorption by the calorimeter is negligible,estimate the enthalpy of combustion per mole of anthracene.

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Use the standard reaction enthalpies given below to determine ΔH°rxn for the following reaction: 2 S(s)+ 3 O2(g)→ 2SO3(g)ΔH°rxn = ? Given: SO2(g)→ S(s)+ O2(g)ΔH°rxn = +296.8 kJ 2 SO2(g)+ O2(g)→ 2 SO3(g)ΔH°rxn = -197.8 kJ

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