Exam 18: Electrochemistry

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Given that E°red = -1.66 V for Al3+/Al at 25°C,find E° and E for the concentration cell expressed using shorthand notation below. Al(s)∣ Al3+(1.0 × 10-5 M)∣∣ Al3+(0.100 M)∣ Al(s)

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Which of the following metals,if coated onto iron,would prevent the corrosion (oxidation)of iron?

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Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn2+(aq,0.022 M)Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn<sup>2+</sup>(aq,0.022 M) Ag<sup>+</sup>(aq,2.7 M)∣ Ag(s)  Ag+(aq,2.7 M)∣ Ag(s) Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s)∣ Sn<sup>2+</sup>(aq,0.022 M) Ag<sup>+</sup>(aq,2.7 M)∣ Ag(s)

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How many seconds are required to produce 4.00 g of aluminum metal from the electrolysis of molten AlCl3 with an electrical current of 12.0 A?

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Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of H2C2O4 and H2O in the balanced reaction? MnO4⁻(aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

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What is the reducing agent in the redox reaction represented by the following cell notation? Ni(s)∣ Ni2+(aq)∣∣ Ag+(aq)∣ Ag(s)

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Use the tabulated half-cell potentials below to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. 3 I2(s)+ 2 Fe(s)→ 2 Fe3+(aq)+ 6 I⁻(aq) Use the tabulated half-cell potentials below to calculate the equilibrium constant (K)for the following balanced redox reaction at 25°C. 3 I<sub>2</sub>(s)+ 2 Fe(s)→ 2 Fe<sup>3+</sup>(aq)+ 6 I⁻(aq)

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A voltaic cell is constructed with two Zn2+-Zn electrodes,where the half-reaction is Zn2+(aq)+ 2e- → Zn(s)E° = -0.763 V The concentrations of zinc ion in the two compartments are 5.50 M and 1.11 × 10-2 M,respectively.The cell emf is ________ V.

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Give the criteria for a nonspontaneous reaction.

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Identify oxidation.

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Use the tabulated half-cell potentials below to calculate ΔG° for the following redox reaction. 2 Al(s)+ 3 Mg2+(aq)→ 2 Al3+(aq)+ 3 Mg(s) Use the tabulated half-cell potentials below to calculate ΔG° for the following redox reaction. 2 Al(s)+ 3 Mg<sup>2+</sup>(aq)→ 2 Al<sup>3+</sup>(aq)+ 3 Mg(s)

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Match the following. -Q < K

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What is the balanced equation for the galvanic cell reaction expressed using shorthand notation below? Ni(s)∣ Ni2+(aq)∣∣ Cl2(g)∣ Cl-(aq)∣ C(s)

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Match the following. -ΔG° < 0

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What mass of aluminum can be plated onto an object in 755 minutes at 5.80 A of current?

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Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Cu(s)∣ Cu2+(aq,0.0032 M)∣∣ Cu2+(aq,4.48 M)∣ Cu(s) Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Cu(s)∣ Cu<sup>2+</sup>(aq,0.0032 M)∣∣ Cu<sup>2+</sup>(aq,4.48 M)∣ Cu(s)

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Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced. ) Mg(s)+ Cu2+(aq)→ Cu(s)+ Mg2+(aq) Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C.(The equation is balanced. ) Mg(s)+ Cu<sup>2+</sup>(aq)→ Cu(s)+ Mg<sup>2+</sup>(aq)

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Give the type of battery that most cars contain.

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What is the oxidizing agent in the redox reaction represented by the following cell notation? Sn(s)∣ Sn2+(aq)∣∣ Ag+(aq)∣ Ag(s)

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Based on the following information, Cl2(g)+ 2 e- → 2 Cl-(aq)E° = +1.36 V Mg2+(aq)+ 2 e- → 2 Mg(s)E° = -2.37 V Which of the following chemical species is the strongest reducing agent?

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