Exam 14: Chemical Equilibrium

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Cyclohexane (C6H12)undergoes a molecular rearrangement in the presence of AlCl3 to form methylcyclopentane (MCP)according to the equation: C6H12 ⇌ MCP If Kc = 0.143 at 25 °C for this reaction, predict the direction in which the system will shift if the initial concentrations of C6H12 and MCP are 0.0400 mol L-1 and 0.0200 mol L-1, respectively. The system

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Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(CO)eq = 6.8 × 10-11 atm, P(O2)eq = 1.3 × 10-3 atm, P(CO2)eq = 0.041 atm. 2 CO(g)+ O2(g)⇌ 2 CO2(g)

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Consider the following reaction and its equilibrium constant: 4CuO(s)+ CH4(g)⇌ CO2(g)+ 4Cu(s)+ 2H2O(g)Kc = 1.10 A reaction mixture contains 0.22 mol L-1 CH4, 0.67 mol L-1 CO2 and 1.3 mol L-1 H2O. Which of the following statements is TRUE concerning this system?

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The equilibrium constant is given for two of the reactions below. Determine the value of the missing equilibrium constant. A(g)+ 2B(g)⇌ AB2(g) Kc = 59 AB2(g)+ B(g)⇌ AB3(g)Kc = ? A(g)+ 3B(g)⇌ AB3(g)Kc = 478

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Which of the following statements is correct?

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Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [PCl5]eq = 0.56 mol L-1, [PCl3]eq = 0.23 mol L-1, [Cl2]eq = 4.4 mol L-1. PCl5(g)⇌ PCl3(g)+ Cl2(g)

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Express the equilibrium constant for the following reaction: Express the equilibrium constant for the following reaction:   + 6CN<sup>-</sup>(aq)⇌   + 6H<sub>2</sub>O(l) + 6CN-(aq)⇌ Express the equilibrium constant for the following reaction:   + 6CN<sup>-</sup>(aq)⇌   + 6H<sub>2</sub>O(l) + 6H2O(l)

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How will equilibrium be affected for a reaction having the same number of moles of gaseous reactants and products if the pressure is increased?

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For which of the following reactions will Kc = Kp?

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Consider the following reaction, equilibrium concentrations, and equilibrium constant at a particular temperature. Determine the equilibrium concentration of H2O(g). C2H4(g)+ H2O(g)⇌ C2H5OH(g)Kc = 9.0 × 103 M-1 [C2H4]eq = 0.015 mol L-1 [C2H5OH]eq = 1.69 mol L-1

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For the following reaction, what is △n required in the conversion of Kc to Kp? KClO3(s)⇌ KClO(s)+ O2(g)

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Consider the following reaction at equilibrium. What effect will reducing the volume of the reaction mixture have on the system? CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g)

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Express the equilibrium constant for the following reaction: H2(g)+ Br2(g)⇌ 2HBr(g)

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Consider the following reaction at equilibrium. What effect will decreasing the temperature have on the system? CO2(g)+ 2H2O(l)⇌ CH4(g)+ 2O2(g)ΔH° = +890 kJ

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For which of the following reactions will Kc = Kp?

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Express the equilibrium constant for the following reaction: N2(g)+ 3H2(g)⇔ 2NH3(g)

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The equilibrium constant is given for two of the reactions below. Determine the value of the missing equilibrium constant. A(g)+ B(g)⇌ AB(g) K = 0.24 AB(g)+ A(g)⇌ A2B(g)K = 3.8 2A(g)+ B(g)⇌ A2B(g)K = ?

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For the following reaction, what is △n required in the conversion of Kc to Kp? 2Na(s)+ 2H2O(l)⇌ 2NaOH(aq)+ H2(g)

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Match the following. -Q < K

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For the following reaction, what is △n required in the conversion of Kc to Kp? P4(s)+ 5O2(g)⇌ P4O10(s)

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