Exam 14: Chemical Equilibrium

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Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(NOCl)eq = 0.22 atm, P(NO)eq = 0.10 atm, P(Cl2)eq = 0.081 atm. 2NOCl(g)⇌ 2NO(g)+ Cl2(g)

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The following reaction is exothermic. Which change will shift the equilibrium to the left? 2SO2(g)+ O2(g)⇌ 2SO3(g)

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Consider the following reaction, equilibrium concentrations, and equilibrium constant at a particular temperature. Determine the equilibrium concentration of NO2(g). N2O4(g)⇌ 2NO2(g) Kc = 0.21 M [N2O4]eq = 0.039 mol L-1

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The equilibrium constant is given for one of two reactions below. Determine the value of the missing equilibrium constant. N2O4(g)⇌ 2NO2(g)K = 1.46 2N2O4(g)⇌ 4NO2(g)K = ?

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Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g) A reaction mixture initially contains 0.86 bar NO and 0.86 bar SO3. Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

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Consider the following reaction at equilibrium. What effect will adding 1 mole of Ar to the reaction mixture have on the system? 2H2S(g)+ 3O2(g)⇌ 2H2O(g)+ 2SO2(g)

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Consider the following reaction, equilibrium concentrations, and equilibrium constant at a particular temperature. Determine the equilibrium concentration of SO3(g). 2SO2(g)+ O2(g)⇌ 2SO3(g) Kc = 1.7 × 108 M-1 [SO2]eq = 0.0034 mol L-1 [O2]eq = 0.0018 mol L-1

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Calculate P (NO)eq, if P(NOCl)eq = 0.33 bar, P(Cl2)eq = 0.50 bar, and Kp = 1.9 × 10-2 bar . 2NOCl(g)⇌ 2NO(g)+ Cl2(g)

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The equilibrium constant is equal to 5.00 L mol-1 at 1300 K for the reaction: 2SO2(g)+ O2(g)⇌ 2SO3(g) If initial concentrations are [SO2] = 6.00 mol L-1, [O2] = 0.45 mol L-1, and [SO3] = 9.00 mol L-1, the system is

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Consider the following reaction, equilibrium concentrations, and equilibrium constant at a particular temperature. Determine the equilibrium concentration of CO2(g). NH2COONH4(s)⇌ 2NH3(g)+ CO2(g)Kc = 1.58 × 10-8 M3 [NH3]eq = 2.9 × 10-3 mol L-1

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Consider the following reaction: CH4(g)+ 2H2S(g)⇌ CS2(g)+ 4H2(g) A reaction mixture initially contains 0.50 mol L-1 CH4 and 0.75 mol L-1 H2S. If the equilibrium concentration of H2 is 0.44 mol L-1, find the equilibrium constant (mol L-1)for the reaction.

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Phosphorus pentachloride decomposes to phosphorus trichloride at high temperatures according to the equation: PCl5(g)⇌ PCl3(g)+ Cl2(g) At 250° 0.125 mol L-1 PCl5 is added to the flask. If Kc = 1.80 mol L-1, what are the equilibrium concentrations of each gas?

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How is the reaction quotient different from an equilibrium constant for a given reaction?

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Consider the following reaction, equilibrium concentrations, and equilibrium constant at a particular temperature. Determine the equilibrium pressure of H2. D2(g)+ H2(g)⇌ 2HD(g)Kp = 1.80 P(D2)eq = 1.1 × 10-3 bar P(HD)eq = 2.7 × 10-3 bar

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The equilibrium constant is given for one of two reactions below. Determine the value of the missing equilibrium constant. 2HD(g)⇌ H2(g)+ D2(g) K = 0.28 2H2(g)+ 2D2(g)⇌ 4HD(g)K = ?

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Can the Kp and Kc for a reaction ever have the same value? Why or why not?

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Why aren't solids or liquids included in an equilibrium expression?

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Consider the following reaction at equilibrium. What effect will increasing the pressure of the reaction mixture have on the system? 2H2S(g)+ 3O2(g)⇌ 2H2O(g)+ 2SO2(g)

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Match the following. -Q > K

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For the following reaction, what is Δn required in the conversion of Kc to Kp? 2SO2(g)+ O2(g)⇌ 2SO3(g)

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