Exam 18: Electrochemistry

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What element is being reduced in the following (unbalanced)redox reaction? Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)

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D

Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25 °C. (The equation is balanced.) Mg(s)+ Cu2+(aq)→ Cu(s)+ Mg2+(aq) Mg2+(aq)+ 2 e⁻ → Mg(s) E° = -2.38 V Cu2+(aq)+ 2 e⁻ → Cu(s) E° = +0.34 V

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C

The standard emf for the cell using the overall cell reaction below is +0.48 V: Zn(s)+ Ni2+ (aq)→ Zn2+ (aq)+ Ni(s) The emf generated by the cell when [Ni2+] = 2.50 mol L-1 and [Zn2+] = 0.100 mol L-1 is The standard emf for the cell using the overall cell reaction below is +0.48 V: Zn(s)+ Ni<sup>2+</sup> (aq)→ Zn<sup>2+</sup> (aq)+ Ni(s) The emf generated by the cell when [Ni<sup>2+</sup>] = 2.50 mol L<sup>-1</sup> and [Zn<sup>2+</sup>] = 0.100 mol L<sup>-1</sup> is

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C

Why is sugar water not a good conductor of current?

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What is the balanced equation for the galvanic cell reaction expressed using shorthand notation below? Ni(s)∣ Ni2+(aq)∣∣ Cl2(g)∣ Cl-(aq)∣ C(s)

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Which of the following is the weakest oxidizing agent?

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Which of the following statements is true for the cell diagram below? Zn(s)∣ Zn2+(aq) Which of the following statements is true for the cell diagram below? Zn(s)∣ Zn<sup>2+</sup>(aq)   Cu<sup>2+</sup>(aq)∣ Cu(s) Cu2+(aq)∣ Cu(s)

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Nickel can be plated from aqueous solution according to the following half-reaction. How long would it take (in min)to plate 29.6 g of nickel at 4.7 A? Ni2+(aq)+ 2 e⁻ → Ni(s)

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Balance the following redox reaction if it occurs in basic solution. What are the coefficients in front of Al and F2 in the balanced reaction? Al(s)+ F2(g)→ Al3+(aq)+ F-(aq)

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Which of the following is the weakest oxidizing agent?

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Which of the following is the strongest reducing agent?

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Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 2 5°C. (The equation is balanced.) Pb(s)+ Br2(l)→ Pb2+(aq)+ 2 Br⁻(aq) Pb2+(aq)+ 2 e⁻ → Pb(s) E° = -0.13 V Br2(l)+ 2 e⁻ → 2 Br⁻(aq)E° = +1.07 V

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A galvanic cell consists of one half-cell that contains Ag(s)and Ag+(aq), and one half-cell that contains Cu(s)and Cu2+(aq). What species are produced at the electrodes under standard conditions? Ag+(aq)+ e- → Ag(s)E° = +0.80 V Cu2+(aq)+ 2 e- → Cu(s)E° = +0.34 V

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Balance the following redox reaction if it occurs in acidic solution. What are the coefficients in front of H⁺ and Fe3+ in the balanced reaction? Fe2+(aq)+ MnO4⁻(aq)→ Fe3+(aq)+ Mn2+(aq)

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Balance the following redox reaction if it occurs in acidic solution. What are the coefficients in front of H2C2O4 and H2O in the balanced reaction? MnO4⁻ (aq)+ H2C2O4(aq)→ Mn2+(aq)+ CO2(g)

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Which of the following metals will dissolve in nitric acid but not hydrochloric acid?

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What is undergoing oxidation in the redox reaction represented by the following cell notation? Pb(s)∣ Pb2+(aq) What is undergoing oxidation in the redox reaction represented by the following cell notation? Pb(s)∣ Pb<sup>2+</sup>(aq)   H<sup>+</sup>(aq)∣ H<sub>2</sub>(g)∣ Pt(s) H+(aq)∣ H2(g)∣ Pt(s)

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What is the oxidizing agent in the redox reaction represented by the following cell notation? Ni(s)∣ Ni2+(aq) What is the oxidizing agent in the redox reaction represented by the following cell notation? Ni(s)∣ Ni<sup>2+</sup>(aq)   Ag<sup>+</sup>(aq)∣ Ag(s) Ag+(aq)∣ Ag(s)

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Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25 °C. (The equation is balanced.) 3Cl2(g)+ 2Fe(s)→ 6Cl⁻(aq)+ 2Fe3+(aq) Cl2(g)+ 2 e⁻ → 2Cl⁻(aq)E° = +1.36 V Fe3+(aq)+ 3 e⁻ → Fe(s)E° = -0.04 V

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Balance the following redox reaction if it occurs in acidic solution. What are the coefficients in front of Cd and Ag+ in the balanced reaction? Cd(s)+ Ag+(aq)→ Ag(s)+ Cd2+(aq)

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