Exam 14: Chemical Equilibrium

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Kc is 1.67 × 1020 mol3 L-3 at 25 °C for the formation of iron(III)oxalate complex ion: Fe3+(aq)+ 3C2O42-(aq)⇌ [Fe(C2O4)3]3-(aq) If 0.0200 mol L-1 Fe3+ is initially mixed with 1.00 mol L-1 oxalate ion, what is the concentration of Fe3+ ion at equilibrium?

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Consider the following reaction at equilibrium. What effect will reducing the pressure of the reaction mixture have on the system? Xe(g)+ 2F2(g)⇌ XeF4(g)

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Phosphorus trichloride and phosphorus pentachloride equilibrate in the presence of molecular chlorine according to the following reaction: Phosphorus trichloride and phosphorus pentachloride equilibrate in the presence of molecular chlorine according to the following reaction:   (g)+   (g)→   (g) An equilibrium mixture at 450 K contains   = 0.124 bar,   = 0.157 bar, and   = 1.30 bar. What is the value of K<sub>p</sub> at this temperature? (g)+ Phosphorus trichloride and phosphorus pentachloride equilibrate in the presence of molecular chlorine according to the following reaction:   (g)+   (g)→   (g) An equilibrium mixture at 450 K contains   = 0.124 bar,   = 0.157 bar, and   = 1.30 bar. What is the value of K<sub>p</sub> at this temperature? (g)→ Phosphorus trichloride and phosphorus pentachloride equilibrate in the presence of molecular chlorine according to the following reaction:   (g)+   (g)→   (g) An equilibrium mixture at 450 K contains   = 0.124 bar,   = 0.157 bar, and   = 1.30 bar. What is the value of K<sub>p</sub> at this temperature? (g) An equilibrium mixture at 450 K contains Phosphorus trichloride and phosphorus pentachloride equilibrate in the presence of molecular chlorine according to the following reaction:   (g)+   (g)→   (g) An equilibrium mixture at 450 K contains   = 0.124 bar,   = 0.157 bar, and   = 1.30 bar. What is the value of K<sub>p</sub> at this temperature? = 0.124 bar, Phosphorus trichloride and phosphorus pentachloride equilibrate in the presence of molecular chlorine according to the following reaction:   (g)+   (g)→   (g) An equilibrium mixture at 450 K contains   = 0.124 bar,   = 0.157 bar, and   = 1.30 bar. What is the value of K<sub>p</sub> at this temperature? = 0.157 bar, and Phosphorus trichloride and phosphorus pentachloride equilibrate in the presence of molecular chlorine according to the following reaction:   (g)+   (g)→   (g) An equilibrium mixture at 450 K contains   = 0.124 bar,   = 0.157 bar, and   = 1.30 bar. What is the value of K<sub>p</sub> at this temperature? = 1.30 bar. What is the value of Kp at this temperature?

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Consider the following reaction and its equilibrium constant: I2(g)⇌ 2I(g)Kp = 0.209 atm A reaction mixture contains 0.89 atm I2 and 1.77 atm I. Which of the following statements is TRUE concerning this system?

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Define Le Châtelier's principle.

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At 900.0 K, the equilibrium constant (Kp)for the following reaction is 0.345 bar-1: 2SO2 + O2(g)→ 2SO3(g) At equilibrium, the partial pressure of SO2 is 35.0 bar and that of O2 is 15.9 bar. The partial pressure of SO3 is ________ bar.

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Match the following. -K << 1

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For the isomerization reaction: butane ⇌ isobutane Kp equals 25.0 at 500 °C. If the initial pressures of butane and isobutane are 20.0 atm and 0.0 atm, respectively, what are the pressures of the two gases at equilibrium?

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The following reaction is exothermic. Which change will shift the equilibrium to the left? 2SO2(g)+ O2(g)⇌ 2SO3(g)

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The decomposition of ammonia is 2NH3(g)→ N2(g)+ 3H2(g). If Kp is 1.5 × 103 bar2 at 400 °C, what is the partial pressure of ammonia at equilibrium when the partial pressure of N2(g)is 0.10 bar and that of H2(g)is 0.15 bar?

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Identify the change that will always shift the equilibrium to the right.

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Express the equilibrium constant for the following reaction: P4(s)+ 5O2(g)⇌ P4O10(s)

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Give the direction of the reaction if K >> 1.

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Why is a thermodynamic equilibrium constant unitless?

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Cyclohexane, C6H12, undergoes a molecular rearrangement in the presence of AlCl3 to form methylcyclopentane, CH3C5H9, according to the equation: C6H12 ⇌ CH3C5H9 If Kc = 0.143 at 25 °C for this reaction, find the equilibrium concentrations of C6H12 and CH3C5H9 if the initial concentrations are 0.200 mol L-1 and 0.075 mol L-1, respectively.

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In a reaction mixture containing only products, what is the value of Q?

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For the reaction: N2(g)+ 2O2(g)⇌ 2NO2(g), Kc = 8.3 × 10-10 M-1 at 25 °C. What is the concentration of N2 gas at equilibrium when the concentration of NO2 is five times the concentration of O2 gas?

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Express the equilibrium constant for the following reaction: 2NH3(g)⇔ N2(g)+ 3H2(g)

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At a certain temperature the equilibrium constant, Kc, equals 0.11 for the reaction: 2ICl(g)⇌ I2(g)+ Cl2(g) What is the equilibrium concentration of ICl if 0.45 mol of I2 and 0.45 mol of Cl2 are initially mixed in a 2.0 L flask?

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Consider the following reaction at equilibrium. What effect will reducing the volume of the reaction mixture have on the system? Xe(g)+ 2F2(g)⇌ XeF4(g)

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