Exam 6: Energy Changes,reaction Rates,and Equilibrium

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The reversible reaction: PCl3(g)+ Cl2(g) The reversible reaction: PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)   PCl<sub>5</sub>(g),has K = 0.5. Based on the molecular art shown below,what can be inferred about the reaction conditions?  PCl5(g),has K = 0.5. Based on the molecular art shown below,what can be inferred about the reaction conditions? The reversible reaction: PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)   PCl<sub>5</sub>(g),has K = 0.5. Based on the molecular art shown below,what can be inferred about the reaction conditions?

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When the pressure of a reaction at equilibrium decreases,in which direction does the equilibrium shift?

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The equilibrium constant expression for the reversible reaction: CHCl3(g)+ 3 HCl(g) The equilibrium constant expression for the reversible reaction: CHCl<sub>3</sub>(g)+ 3 HCl(g)   CH<sub>4</sub>(g)+ 3 Cl<sub>2</sub>(g)is   . CH4(g)+ 3 Cl2(g)is The equilibrium constant expression for the reversible reaction: CHCl<sub>3</sub>(g)+ 3 HCl(g)   CH<sub>4</sub>(g)+ 3 Cl<sub>2</sub>(g)is   . .

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When the equilibrium constant for a reaction is much less than one (K < 1),the concentration of the products is larger than the concentration of the reactants.

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Changes in potential energy occur in chemical reactions.

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One step in the metabolism of glucose is depicted below. Which statement best describes how the equilibrium system would respond if the amount of dihydroxyacetone phosphate is decreased? One step in the metabolism of glucose is depicted below. Which statement best describes how the equilibrium system would respond if the amount of dihydroxyacetone phosphate is decreased?

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Once equilibrium is reached in a chemical reaction,reactants stop forming products.

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A reversible reaction in which K = 9.65 × 10-14 contains a negligible amount of reactants at equilibrium.

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The ΔH for the reaction depicted by the energy diagram below is ________. The ΔH for the reaction depicted by the energy diagram below is ________.

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Consider the reversible reaction at equilibrium: N2(g)+ O2(g) Consider the reversible reaction at equilibrium: N<sub>2</sub>(g)+ O<sub>2</sub>(g)   2 NO(g). What is the effect of removing some N<sub>2</sub>(g)from the equilibrium system? 2 NO(g). What is the effect of removing some N2(g)from the equilibrium system?

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Which of the following is ALWAYS necessary for a chemical reaction to occur between two reactants,A and B?

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When reactants can come together and form products,and products can come together to re-form reactants,the reaction is called a ________ reaction.

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Heat is absorbed in an ________ reaction.

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Bond breaking is endothermic.

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Le Châtelier's principle is a general rule used to explain the effect of a change in reaction conditions on equilibrium.

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In order to cause an endothermic equilibrium reaction to shift in a direction to form more products,the reaction must be heated.

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Consider the reaction,3 NO2(g)+ H2O(l)→ 2 HNO3(aq)+ NO(g),where ΔH = -137 kJ. How many kilojoules are released when 92.3 g of NO2 reacts?

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A chemical reaction requires 31.39 kJ. How many kilocalories does this correspond to?

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Bond dissociation energies are always positive numbers.

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An equilibrium constant with a value of 8.0 × 106 indicates that at equilibrium ________.

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