Exam 6: Energy Changes,reaction Rates,and Equilibrium

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In the reaction: 2 C2H6(g)+ 7 O2(g)→ 4 CO2(g)+ 6 H2O(g),increasing the concentration of C2H6(g)will ________.

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D

Which K value below is consistent with an equilibrium system in which the products are favored?

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B

Consider the reversible reaction: PCl3(g)+ Cl2(g) Consider the reversible reaction: PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)   PCl<sub>5</sub>(g),where K = 0.5. Since K < 1,[PCl<sub>5</sub>] must be less than 1 M. PCl5(g),where K = 0.5. Since K < 1,[PCl5] must be less than 1 M.

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False

Which bond is the weakest?

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Increasing the concentration of the reactants in a chemical reaction increases the number of collisions,and the reaction rate increases.

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Activation energy is the minimum amount of energy necessary for a reaction to occur.

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Reactions with high Ea are generally fast reactions.

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A reversible reaction has reached equilibrium when which condition is established?

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An endothermic reaction is one in which energy is absorbed and ΔH is negative (-).

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Energy is the capacity to do work.

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Consider the reaction,C2H4(g)+ H2(g)→ C2H6(g),where ΔH = -137 kJ. How many kilojoules are released when 55.3 g of C2H4 reacts?

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Consider the following reversible reaction at equilibrium: C­6­H12O6 (aq)+ 6 O2(g) Consider the following reversible reaction at equilibrium: C­<sub>6­</sub>H<sub>12</sub>O<sub>6</sub> (aq)+ 6 O<sub>2</sub>(g)   6 CO<sub>2</sub>(g)+ 6 H<sub>2</sub>O(l). If oxygen gas is removed from the reaction vessel,the equilibrium will shift to the right. 6 CO2(g)+ 6 H2O(l). If oxygen gas is removed from the reaction vessel,the equilibrium will shift to the right.

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The stronger the bond,the higher its bond dissociation energy.

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For an endothermic reaction at equilibrium,increasing the temperature ________.

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Breaking a chemical bond requires energy.

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As a general rule,a reaction rate ________ for each 10 °C the temperature is raised.

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The rusting of iron is described by the reaction: 4 Fe(s)+ 3 O2(g)→ 2 Fe2O3(s). The formation of rust on an exposed piece of iron typically takes several months. Which of the following is NOT a reasonable assumption about this chemical reaction?

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Exothermic reactions involve the formation of products having lower energy than the reactants.

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The law of conservation of energy states that ________.

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Consider the following reversible reaction at equilibrium: CO(g)+ Cl2(g) Consider the following reversible reaction at equilibrium: CO(g)+ Cl<sub>2</sub>(g)   COCl<sub>2</sub>(g). If the pressure inside the reaction vessel is increased,the equilibrium will shift to the left. COCl2(g). If the pressure inside the reaction vessel is increased,the equilibrium will shift to the left.

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