Exam 8: Acids and Bases

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A buffer solution contains carbonic acid (H2CO3) and sodium bicarbonate (NaHCO3), each at a concentration of 0.100 M.The relevant equilibrium is shown below.What is the pH of this buffer solution? H2CO3(aq) + H2O(l) A buffer solution contains carbonic acid (H<sub>2</sub>CO<sub>3</sub>) and sodium bicarbonate (NaHCO<sub>3</sub>), each at a concentration of 0.100 M.The relevant equilibrium is shown below.What is the pH of this buffer solution? H<sub>2</sub>CO<sub>3</sub>(aq) + H<sub>2</sub>O(l)   H<sub>3</sub>O<sup>+</sup>(aq) + HCO<sub>3</sub>−(aq) K<sub>a</sub> = 4.5 × 10<sup>−7</sup> H3O+(aq) + HCO3−(aq) Ka = 4.5 × 10−7

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The concentration of a weak acid or base affects its degree of dissociation in water.

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Which of the following is an example of a diprotic acid?

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The combination of a weak acid and a strong acid form a buffer solution.

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If the hydronium ion concentration of an aqueous solution at 25°C is 5 × 10-6 M, what is the hydroxide ion concentration?

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A buffer solution contains acetic acid (HC2H3O2) at a concentration of 0.225 M and sodium acetate (NaC2H3O2) at a concentration of 0.164 M.The value of Ka for acetic acid is 1.75 × 10-5.What is the pH of this buffer solution?

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What is the pH of a 1.0 × 10−4 M solution of KOH?

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A sample of black coffee was measured to have [H3O+] = 7.94 × 10−6.What is TRUE about this solution?

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For the reaction shown below, which of the following correctly represents a conjugate acid-base pair? HCO2H(aq) + H2O(l) For the reaction shown below, which of the following correctly represents a conjugate acid-base pair? HCO<sub>2</sub>H(aq) + H<sub>2</sub>O(l)   H<sub>3</sub>O<sup>+</sup>(aq) + HCO<sub>2</sub>−(aq) H3O+(aq) + HCO2−(aq)

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According to Arrhenius' theory of acids and bases, acids increase the hydrogen ion concentration in water.

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What is the pH of a 0.035 M HCl solution?

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Which of the following correctly describes what is meant by the term neutralization?

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What is the hydronium ion concentration of pure water at 25°C?

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What is always a characteristic of a solution that contains a buffer?

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Calculate the molar concentration of a sodium hydroxide solution if 60.00 mL of this solution were required to neutralize 30.00 mL of a 0.150 M hydrochloric acid solution.NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l)

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Which of the following best represents the autoionization, or self-ionization, of water?

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Consider the following generalized buffer solution equilibrium: BH+(aq) + H2O(l) Consider the following generalized buffer solution equilibrium: BH<sup>+</sup>(aq) + H<sub>2</sub>O(l)   H<sub>3</sub>O<sup>+</sup>(aq) + B(aq) When a small amount of a strong base such as sodium hydroxide is added to the solution, which of the four species shown would experience an increase in concentration? (Hint: Use LeChatelier's principle.) H3O+(aq) + B(aq) When a small amount of a strong base such as sodium hydroxide is added to the solution, which of the four species shown would experience an increase in concentration? (Hint: Use LeChatelier's principle.)

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A solution containing a buffer has an initial pH of 8.78.If a student adds 5 drops of HCl(aq) to this solution, what would be a reasonable pH for the resulting solution?

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A particular buffer solution consists of a weak acid and its conjugate base.How could this buffer solution be modified so as to increase its buffer capacity against added base?

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