Exam 20: Electrochemistry

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Determine E°cell for the reaction: Cl2 + 2 F- → 2 Cl- + F2. The half reactions are: F2(s) + 2 e- → 2 F-(aq)   E° = +2.866 V Cl2(s) + 2 e- → 2 Cl-(aq)   E° = 1.358 V

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For the reaction: Mg(s) + AgNO3(aq) → Ag(s) + Mg(NO3)2(aq) Ag+(aq) + e- → Ag(s) E° = 0.800 V Mg2+(aq) + 2 e- → Mg(s) E° = -2.356 V For the reaction, determine E° for the cell.

(Multiple Choice)
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For the reaction: Mg(s) + AgNO3(aq) → Ag(s) + Mg(NO3)2(aq) Ag+(aq) + e- → Ag(s) E° = 0.800 V Mg2+(aq) + 2 e- → Mg(s) E° = -2.356 V Estimate Keq at 25°C.

(Multiple Choice)
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Determine E°cell for the reaction: 2 Ag+ + Mg → 2 Ag + Mg2+. The half reactions are: Mg2+(aq) + 2 e- → Mg(s) E° = -2.356 V Ag+(aq) + e- → Ag(s) E° = 0.800 V

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What is the cell potential for the following cell at 25°C? Zn ∣ Zn2+ (0.0456 M) || Cu2+(0.120 M) ∣ Cu Cu2+ + 2 e- → Cu(s)   E° = 0.340 V Zn2+ + 2 e- → Zn(s)   E° = -0.763 V

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Which of the following are commonly used as alternate standard electrodes: I. Ag(s) | AgCl(s) | Cl- (1.0 M) II. Hg(l) | HgCl2(s) | Cl- (1.0 M) III. Ag(s) | AgCl(s) | Cl- (0.1 M) IV. Hg(l) | Hg2Cl2(s) | Cl- (1.0 M) V. Hg(s) | Hg2Cl2(s) | Cl- (1.0 M)

(Multiple Choice)
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What is the cell potential for the following cell at 25°C? Al ∣ Al3+(0.00212 M) || Sn2+(0.435 M) ∣ Sn Al3+ + 3 e- → Al(s)   E° = -1.676 V Sn2+ + 2 e- → Sn(s   E° = -0.137 V

(Multiple Choice)
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In a zinc-lead cell the reaction is: Pb2+ + Zn → Pb + Zn2+     E° = 0.637 V Which of the following statements about this cell is FALSE?

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What is E° of the spontaneous cell made from the Zn2+/Zn (-0.76 V) and Br2/2Br- (1.07 V) half cells?

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Corrosion of metals is an oxidation-reduction process.

(True/False)
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For the following voltaic cell, determine the [Cl-] when PCl2 = 0.500 atm, [Zn2+] = 1.77 × 10-2 M, and Ecell = 2.250 V. The half-reactions at 25°C are: Cl2(g) + 2 e- → 2 Cl-(aq)   E° = +1.358 V Zn2+(aq) + 2 e- → Zn(s)   E° = -0.763 V Zn(s) ∣ Zn2+(aq) || Cl-(aq), Cl2(g) ∣ Pt(s)

(Multiple Choice)
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Determine E°cell for the reaction: Pb + Zn2+ → Pb2+ + Zn. The half reactions are: Pb2+(aq) + 2 e- → Pb(s)   E° = -0.125 V Zn2+(aq) + 2 e- → Zn(s)   E° = -0.763 V

(Multiple Choice)
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For the reaction: Mg(s) + AgNO3(aq) → Ag(s) + Mg(NO3)2(aq) Ag+(aq) + e- → Ag(s) E° = 0.800 V Mg2+(aq) + 2 e- → Mg(s) E° = -2.356 V Determine ΔG°.

(Multiple Choice)
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The Ecell for the following concentration cell at 25°C is 0.006. Pt ∣ H2 (g, 0.025 atm) ∣ H+ (0.012 M) = H+ (1 M) ∣ H2 (g, 1 atm) ∣ Pt 2 H+(aq) + 2 e- → H2(g) E° = 0. V

(True/False)
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Consider the following reaction: 2 Al + 3 Ni2+ → 2 Al3+ + 3 Ni E° = 1.410 v What would be the cell potential at 25°C as calculated from the Nernst equation if [Ni2+] = 0.020 M, [Al3+] = 3.60 M?

(Multiple Choice)
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Determine the Ksp at 25°C of AgCl(s). The half-reactions are: Ag+(aq) + 1 e- → Ag(s) E° = +0.771 V AgCl(s) + 1 e- → Ag(s) + Cl- E° = +0.222 V

(Multiple Choice)
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What is Keq at 25°C of the spontaneous cell made from the Zn2+/Zn (-0.76 V) and Br2/2Br- (1.07 V) half cells?

(Multiple Choice)
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What is the Ecell for the following cell at 25°C? Pt ∣ Fe2+ (0.0562 M), Fe3+ (0.253 M) || Ag+ (0.334 M) ∣ Ag Ag+ + e- → Ag(s)    E° = 0.800 V Fe3+ + e- → Fe2+     E° = -0.771 V

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In a galvanic cell, oxidation occurs at the:

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Cathodic protection is attaching a more active metal to the protected metal.

(True/False)
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