Exam 20: Electrochemistry
Exam 1: Matter - Its Properties and Measurement94 Questions
Exam 2: Atoms and the Atomic Theory100 Questions
Exam 3: Chemical Compounds100 Questions
Exam 4: Chemical Reactions100 Questions
Exam 5: Introduction to Reactions in Aqueous Solutions97 Questions
Exam 6: Gases100 Questions
Exam 7: Thermochemistry101 Questions
Exam 8: Electrons in Atoms100 Questions
Exam 9: The Periodic Table and Some Atomic Properties96 Questions
Exam 10: Chemical Bonding I: Basic Concepts97 Questions
Exam 11: Chemical Bonding II: Additional Aspects97 Questions
Exam 12: Intermolecular Forces: Liquids and Solids102 Questions
Exam 13: Solutions and Their Physical Properties100 Questions
Exam 14: Chemical Kinetics92 Questions
Exam 15: Principles of Chemical Equilibrium99 Questions
Exam 16: Acids and Bases100 Questions
Exam 17: Additional Aspects of Acid-Base Equilibria99 Questions
Exam 18: Solubility and Complex-Ion Equilibria95 Questions
Exam 19: Spontaneous Change: Entropy and Free Energy101 Questions
Exam 20: Electrochemistry103 Questions
Exam 21: Main Group Elements I: Groups 1, 2, 13, and 14116 Questions
Exam 22: Main Group Elements II: Groups 18, 17, 16, 15, and Hydrogen100 Questions
Exam 23: The Transition Elements102 Questions
Exam 24: Complex Ions and Coordination Compounds100 Questions
Exam 25: Nuclear Chemistry 1-41100 Questions
Exam 26: Structures of Organic Compounds96 Questions
Exam 27: Reactions of Organic Compounds94 Questions
Exam 28: Chemistry of the Living State99 Questions
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Determine E°cell for the reaction: Cl2 + 2 F- → 2 Cl- + F2. The half reactions are: F2(s) + 2 e- → 2 F-(aq) E° = +2.866 V
Cl2(s) + 2 e- → 2 Cl-(aq) E° = 1.358 V
(Multiple Choice)
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For the reaction: Mg(s) + AgNO3(aq) → Ag(s) + Mg(NO3)2(aq) Ag+(aq) + e- → Ag(s) E° = 0.800 V
Mg2+(aq) + 2 e- → Mg(s) E° = -2.356 V
For the reaction, determine E° for the cell.
(Multiple Choice)
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For the reaction: Mg(s) + AgNO3(aq) → Ag(s) + Mg(NO3)2(aq) Ag+(aq) + e- → Ag(s) E° = 0.800 V
Mg2+(aq) + 2 e- → Mg(s) E° = -2.356 V
Estimate Keq at 25°C.
(Multiple Choice)
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Determine E°cell for the reaction: 2 Ag+ + Mg → 2 Ag + Mg2+. The half reactions are: Mg2+(aq) + 2 e- → Mg(s) E° = -2.356 V
Ag+(aq) + e- → Ag(s) E° = 0.800 V
(Multiple Choice)
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What is the cell potential for the following cell at 25°C? Zn ∣ Zn2+ (0.0456 M) || Cu2+(0.120 M) ∣ Cu
Cu2+ + 2 e- → Cu(s) E° = 0.340 V
Zn2+ + 2 e- → Zn(s) E° = -0.763 V
(Multiple Choice)
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Which of the following are commonly used as alternate standard electrodes:
I. Ag(s) | AgCl(s) | Cl- (1.0 M)
II. Hg(l) | HgCl2(s) | Cl- (1.0 M)
III. Ag(s) | AgCl(s) | Cl- (0.1 M)
IV. Hg(l) | Hg2Cl2(s) | Cl- (1.0 M)
V. Hg(s) | Hg2Cl2(s) | Cl- (1.0 M)
(Multiple Choice)
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What is the cell potential for the following cell at 25°C? Al ∣ Al3+(0.00212 M) || Sn2+(0.435 M) ∣ Sn
Al3+ + 3 e- → Al(s) E° = -1.676 V
Sn2+ + 2 e- → Sn(s E° = -0.137 V
(Multiple Choice)
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In a zinc-lead cell the reaction is: Pb2+ + Zn → Pb + Zn2+ E° = 0.637 V
Which of the following statements about this cell is FALSE?
(Multiple Choice)
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What is E° of the spontaneous cell made from the Zn2+/Zn (-0.76 V) and Br2/2Br- (1.07 V) half cells?
(Multiple Choice)
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For the following voltaic cell, determine the [Cl-] when PCl2 = 0.500 atm, [Zn2+] = 1.77 × 10-2 M, and Ecell = 2.250 V. The half-reactions at 25°C are: Cl2(g) + 2 e- → 2 Cl-(aq) E° = +1.358 V
Zn2+(aq) + 2 e- → Zn(s) E° = -0.763 V
Zn(s) ∣ Zn2+(aq) || Cl-(aq), Cl2(g) ∣ Pt(s)
(Multiple Choice)
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Determine E°cell for the reaction: Pb + Zn2+ → Pb2+ + Zn. The half reactions are: Pb2+(aq) + 2 e- → Pb(s) E° = -0.125 V
Zn2+(aq) + 2 e- → Zn(s) E° = -0.763 V
(Multiple Choice)
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For the reaction: Mg(s) + AgNO3(aq) → Ag(s) + Mg(NO3)2(aq) Ag+(aq) + e- → Ag(s) E° = 0.800 V
Mg2+(aq) + 2 e- → Mg(s) E° = -2.356 V
Determine ΔG°.
(Multiple Choice)
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The Ecell for the following concentration cell at 25°C is 0.006.
Pt ∣ H2 (g, 0.025 atm) ∣ H+ (0.012 M) = H+ (1 M) ∣ H2 (g, 1 atm) ∣ Pt
2 H+(aq) + 2 e- → H2(g) E° = 0. V
(True/False)
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Consider the following reaction: 2 Al + 3 Ni2+ → 2 Al3+ + 3 Ni E° = 1.410 v
What would be the cell potential at 25°C as calculated from the Nernst equation if [Ni2+] = 0.020 M, [Al3+] = 3.60 M?
(Multiple Choice)
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Determine the Ksp at 25°C of AgCl(s). The half-reactions are: Ag+(aq) + 1 e- → Ag(s) E° = +0.771 V
AgCl(s) + 1 e- → Ag(s) + Cl- E° = +0.222 V
(Multiple Choice)
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What is Keq at 25°C of the spontaneous cell made from the Zn2+/Zn (-0.76 V) and Br2/2Br- (1.07 V) half cells?
(Multiple Choice)
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What is the Ecell for the following cell at 25°C? Pt ∣ Fe2+ (0.0562 M), Fe3+ (0.253 M) || Ag+ (0.334 M) ∣ Ag
Ag+ + e- → Ag(s) E° = 0.800 V
Fe3+ + e- → Fe2+ E° = -0.771 V
(Multiple Choice)
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Cathodic protection is attaching a more active metal to the protected metal.
(True/False)
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