Exam 8: Reaction Rates and Equilibrium

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The equilibrium constants for a series of reaction of the general type: AB + CD The equilibrium constants for a series of reaction of the general type: AB + CD   AD + BC Were measured and are shown below.In which reaction is the concentration of the products the largest at equilibrium? AD + BC Were measured and are shown below.In which reaction is the concentration of the products the largest at equilibrium?

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A catalyzed,aqueous chemical reaction occurs.Which of the following conditions will reach completion the soonest?

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A reaction rate can be described in terms of the change in concentration of either a reactant or a product.

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For the reaction NO2 (g)+ N2O(g) For the reaction NO<sub>2</sub> (g)+ N<sub>2</sub>O(g)   3 NO(g)the equilibrium constant expression is:  3 NO(g)the equilibrium constant expression is: For the reaction NO<sub>2</sub> (g)+ N<sub>2</sub>O(g)   3 NO(g)the equilibrium constant expression is:

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For the following reaction,which of the given changes will increase the value of the equilibrium constant? AB + CD For the following reaction,which of the given changes will increase the value of the equilibrium constant? AB + CD   AD + BC + heat AD + BC + heat

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Chemical reactions always occur once the molecules of two substances collide.

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An inhibitor will have what effect on a reaction?

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You purchase a glow stick during an evening parade.After it ends,your roommate tells you that if you place it in the freezer,it will glow for a longer time.Assuming she knows what she is talking about,why would this be true?

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When a spontaneous process in accompanied by an energy increase,then a large entropy increase must also occur.

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Homogeneous catalysts are thought to function by

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Equilibrium: The following question(s)refer to the equilibrium given below in which all reactants and products are gases. CH4 + H2O Equilibrium: The following question(s)refer to the equilibrium given below in which all reactants and products are gases. CH<sub>4</sub> + H<sub>2</sub>O   CH<sub>3</sub>OH + H<sub>2</sub> + heat Indicate the effect of the changing condition on the position of equilibrium. -Refer to Equilibrium.Remove H<sub>2</sub> from the mixture. CH3OH + H2 + heat Indicate the effect of the changing condition on the position of equilibrium. -Refer to Equilibrium.Remove H2 from the mixture.

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Consider the following energy diagram.Which letter represents the activation energy for the forward reaction? Consider the following energy diagram.Which letter represents the activation energy for the forward reaction?

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For the reaction below,which of the following would take place once pure A and B are mixed together? A + B For the reaction below,which of the following would take place once pure A and B are mixed together? A + B   C C

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Catalysts may lower the activation energy.

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Based upon the energy diagram given below,which letter represents the enthalpy for the reaction? Based upon the energy diagram given below,which letter represents the enthalpy for the reaction?

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Activation energy is the total energy released when a reaction takes place.

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Which is assumed to be true in most explanations of how reactions occur?

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A heterogeneous catalyst will normally dissolve in the reaction mixture.

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Equilibrium: The following question(s)refer to the equilibrium given below in which all reactants and products are gases. CH4 + H2O Equilibrium: The following question(s)refer to the equilibrium given below in which all reactants and products are gases. CH<sub>4</sub> + H<sub>2</sub>O   CH<sub>3</sub>OH + H<sub>2</sub> + heat Indicate the effect of the changing condition on the position of equilibrium. -Refer to Equilibrium.Add a catalyst to the mixture. CH3OH + H2 + heat Indicate the effect of the changing condition on the position of equilibrium. -Refer to Equilibrium.Add a catalyst to the mixture.

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Which of the following would be the equilibrium expression for the system given below? N2(g)+ 3F2(g) Which of the following would be the equilibrium expression for the system given below? N<sub>2</sub>(g)+ 3F<sub>2</sub>(g)   2NF<sub>3</sub>(g) 2NF3(g)

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