Exam 8: Reaction Rates and Equilibrium

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A room filled with a 2:1 mixture of hydrogen and oxygen gases can be safely inhaled.However,with a single spark,it can react explosively.Since the explosion would be considered a spontaneous process,what did the spark provide?

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When the equilibrium expression is written for the reaction N2(g)+ 3F2(g) When the equilibrium expression is written for the reaction N<sub>2</sub>(g)+ 3F<sub>2</sub>(g)   2NF<sub>3</sub>(g) What is the exponent of the concentration of fluorine,F<sub>2</sub>? 2NF3(g) What is the exponent of the concentration of fluorine,F2?

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Which statement is a correct application of Le Châtelier's principle?

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If the reaction A + B →\rightarrow C is exothermic,the concentration of C should increase with increasing temperature.

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Which of the following interpretations of the spontaneous chemical reaction is correct? V + W →\rightarrow Y + Z + heat

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Which statement applies to equilibria in general?

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All chemical reactions require at least some amount of activation energy to proceed.

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The reaction conditions for a specific reaction,BCD + HA →\rightarrow ABCDH,are correct,but the reaction does not occur.What could be the reason?

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Which of the statements is correct when referring to the following reaction? H2(g)+ I2(g) Which of the statements is correct when referring to the following reaction? H<sub>2</sub>(g)+ I<sub>2</sub>(g)   2HI(g) 2HI(g)

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A reaction is spontaneous when the conditions are

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Which of the following is an endergonic process?

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Equilibrium: The following question(s)refer to the equilibrium given below in which all reactants and products are gases. CH4 + H2O Equilibrium: The following question(s)refer to the equilibrium given below in which all reactants and products are gases. CH<sub>4</sub> + H<sub>2</sub>O   CH<sub>3</sub>OH + H<sub>2</sub> + heat Indicate the effect of the changing condition on the position of equilibrium. -Refer to Equilibrium.Cool the mixture. CH3OH + H2 + heat Indicate the effect of the changing condition on the position of equilibrium. -Refer to Equilibrium.Cool the mixture.

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Butane,C4H10,burning in air,is an example of a substance combining with oxygen to produce CO2 and H2O.If pure oxygen were to be supplied,the rate of combustion would increase significantly.Then there is more energy given off when 10 g of butane burns in pure oxygen,rather than in air.

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Most automobiles function by burning gasoline by a process similar to the equation shown,in which octane is burned. C8H18 + O2 →\rightarrow CO2 + H2O + heat (not balanced) Using the concept of entropy,interpret the implications of this reaction.

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In an exergonic process,the system _____ .

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The effect of a catalyst is to eliminate the activation energy requirement of chemical reactions.

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A process that gains or accepts energy as it takes place is a(n)_____ .

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Decreasing the temperature will decrease the number of effective collisions.

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If we add a catalyst to the following equation,which way will the equilibrium shift? CO + H2O + heat If we add a catalyst to the following equation,which way will the equilibrium shift? CO + H<sub>2</sub>O + heat   CO<sub>2</sub> + H<sub>2</sub> CO2 + H2

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Ice has a(n)____ entropy than that of liquid water.

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