Question 1

Predict the product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  V 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  V

Question 2

Provide the reagents necessary to carry out the following conversion.

Accepted Answer

1. @#IMG-DLM&_TB4454_00 
2. HN

Question 3

A compound with molecular formula C4H11N exhibits a triplet at $\delta$  0.9 (3H), a doublet at $\delta$  1.1 (3H), a quintet at $\delta$  1.4 (2H), a singlet at $\delta$  1.7 (2H) and a sextet at $\delta$  2.8 (2H) in its 1H NMR spectrum. Its IR spectrum shows two medium absorption bands near 3400 cm-1. What is the structure for this compound?

Accepted Answer

The answer of A compound with molecular formula C4H11N exhibits...

Question 4

Provide the reagents necessary to convert (S)-3-methyl-3-phenylpentanoic acid to (S)-3-methyl-3-phenylpentanamine.

Accepted Answer

1. SOCl₂/py

Question 5

What is the structure for N-ethylbenzylamine?

Accepted Answer

The answer of What is the structure for N-ethylbenzylamine?...

Question 6

Provide a stepwise synthesis of 1-cyclopentylethanamine using the Gabriel synthesis.

Accepted Answer

@#IMG-DLM&_TB4454_00

Question 7

Predict the major product for the following reaction.   2

Accepted Answer

The answer of Predict the major product for the following...

Question 8

Provide a stepwise synthesis to carry out the following conversion.

Accepted Answer

@#IMG-DLM&_TB4454_00

Question 9

Predict the major product for the following reaction.

Accepted Answer

The answer of Predict the major product for the following...

Question 10

Provide the structures of the products in each step of the following reaction sequence.

Accepted Answer

@#IMG-DLM&_TB4454_00

Question 11

Predict the product(s) for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  V 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  V

Question 12

Predict the major product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  V 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  V

Question 13

A compound with molecular formula C6H15N displays the following IR, 1H NMR and 13C NMR spectra. Propose a structure for this compound.

SDBS

Accepted Answer

Question 14

Predict the major product for the following reaction.

Accepted Answer

The answer of Predict the major product for the following...

Question 15

Predict the product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  V 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  V

Question 16

Predict the major product for the following reaction.

Accepted Answer

The answer of Predict the major product for the following...

Question 17

Chloroquine is used as an antimalarial drug. Rank the three nitrogen atoms in decreasing (strongest to weakest) order of basicity.

Accepted Answer

A)  III > I > II 
B)  I > III > II 
C)  II > I > III 
D)  I > II > III 
E)  III > II > I 
A)  III > I > II 
B)  I > III > II 
C)  II > I > III 
D)  I > II > III 
E)  III > II > I

Question 18

Predict the product(s) for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  V 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  V

Question 19

Predict the product for the following reaction sequence.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  none of these 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  none of these

Question 20

Which of the following is a tertiary amine?

Accepted Answer

A)  CH3CH2CH2CH2NH2 
B)  CH3CH2NHCH2CH(CH3)2 
C)  (CH3CH2)2NCH2CH(CH3)2 
D)  (CH3CH2)4N+ OH- 
E)  (CH3CH2)3CNH2 
A)  CH3CH2CH2CH2NH2 
B)  CH3CH2NHCH2CH(CH3)2 
C)  (CH3CH2)2NCH2CH(CH3)2 
D)  (CH3CH2)4N+ OH- 
E)  (CH3CH2)3CNH2

Exam 22: Amines

Predict the product for the following reaction.

Provide the reagents necessary to carry out the following conversion.

Provide the reagents necessary to convert (S)-3-methyl-3-phenylpentanoic acid to (S)-3-methyl-3-phenylpentanamine.

What is the structure for N-ethylbenzylamine?

Provide a stepwise synthesis of 1-cyclopentylethanamine using the Gabriel synthesis.

Predict the major product for the following reaction. 2

Provide a stepwise synthesis to carry out the following conversion.

Predict the major product for the following reaction.

Provide the structures of the products in each step of the following reaction sequence.

Predict the product(s) for the following reaction.

Predict the major product for the following reaction.

A compound with molecular formula C6H15N displays the following IR, 1H NMR and 13C NMR spectra. Propose a structure for this compound. SDBS

Predict the major product for the following reaction.

Predict the product for the following reaction.

Predict the major product for the following reaction.

Chloroquine is used as an antimalarial drug. Rank the three nitrogen atoms in decreasing (strongest to weakest) order of basicity.

Predict the product(s) for the following reaction.

Predict the product for the following reaction sequence.

Which of the following is a tertiary amine?

A Review of General Chemistry: Electrons, Bonds, and Molecular Properties

Molecular Representations

Acids and Bases

Alkanes and Cycloalkanes

Stereoisomerism

Chemical Reactivity and Mechanisms

Alkyl Halides: Nucleophilic Substitution and Elimination Reactions

Addition Reactions of Alkenes

Alkynes

Radical Reactions

Synthesis

Alcohols and Phenols

Ethers and Epoxides; Thiols and Sulfides

Infrared Spectroscopy and Mass Spectrometry

Nuclear Magnetic Resonance Spectroscopy

Conjugated Pi Systems and Pericyclic Reactions

Aromatic Compounds

Aromatic Substitution Reactions

Aldehydes and Ketones

Carboxylic Acids and Their Derivatives

Alpha Carbon Chemistry: Enols and Enolates

Introduction to Organometallic Compounds

Carbohydrates

Amino Acids, Peptides, and Proteins

Lipids

Synthetic Polymers

Filters

A compound with molecular formula C₆H₁₅N displays the following IR, ¹H NMR and ¹³C NMR spectra. Propose a structure for this compound. SDBS