Question 1

Provide the IUPAC name for the following compound.

Accepted Answer

(1S,2R)-1-

Question 2

Predict the product(s) for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  none of these 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  none of these

Question 3

Provide a stepwise curved arrow mechanism for the following reaction.

Accepted Answer

@#IMG-DLM&_TB4454_00

Question 4

Provide the reagents necessary to prepare the following compound using alkoxymercuration-demercuration.

Accepted Answer

@#IMG-DLM&_TB4454_00

Question 5

Predict the major product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  none of these 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  none of these

Question 6

Predict the product for the following reaction and provide a curved arrow mechanism for the formation of the product.

Accepted Answer

@#IMG-DLM&_TB4454_00

Question 7

Which one of the following compounds will be least soluble in water?

Accepted Answer

A)  diethyl ether 
B)  methyl propyl ether 
C)  1-butanol 
D)  2-butanol 
E)  pentane 
A)  diethyl ether 
B)  methyl propyl ether 
C)  1-butanol 
D)  2-butanol 
E)  pentane

Question 8

Provide the structure for (R)-1,1-dimethoxy-3-phenoxycyclopentane.

Accepted Answer

The answer of Provide the structure for (R)-1,1-dimethoxy-3-phenoxycyclopentane....

Question 9

What is the IUPAC name for CH3CH2OCH2CH2CH2CH2OCH2CH3?

Accepted Answer

A)  1,4-ethoxyoctane 
B)  diethoxy butyl ether 
C)  1,2-diethoxymethane 
D)  1,2-diethoxyhexane 
E)  1,4-diethoxybutane 
A)  1,4-ethoxyoctane 
B)  diethoxy butyl ether 
C)  1,2-diethoxymethane 
D)  1,2-diethoxyhexane 
E)  1,4-diethoxybutane

Question 10

Provide the structure for 2-iodo-4-isopropyl-1-methoxybenzene.

Accepted Answer

The answer of Provide the structure for 2-iodo-4-isopropyl-1-methoxybenzene....

Question 11

Which one of the following reactions would produce t-butyl methyl ether in high yield?

Accepted Answer

A)  t-butyl chloride + sodium methoxide 
B)  t-butanol + methanol in presence of H2SO4 at 140°C 
C)  t-butyl bromide + bromomethane in the presence of NaOH 
D)  sodium t-butoxide + bromomethane 
A)  t-butyl chloride + sodium methoxide 
B)  t-butanol + methanol in presence of H2SO4 at 140°C 
C)  t-butyl bromide + bromomethane in the presence of NaOH 
D)  sodium t-butoxide + bromomethane

Question 12

Predict the product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
A)  I 
B)  II 
C)  III 
D)  IV

Question 13

Which of the following crown ether solvates potassium ions?

Accepted Answer

A)  12-crown-5 
B)  12-crown-4 
C)  15-crown-5 
D)  18-crown-6 
E)  none of these 
A)  12-crown-5 
B)  12-crown-4 
C)  15-crown-5 
D)  18-crown-6 
E)  none of these

Question 14

Which of the following compounds is(are) classified as ethers?

Accepted Answer

A)  I 
B)  II & IV 
C)  III 
D)  I & III 
E)  all of these 
A)  I 
B)  II & IV 
C)  III 
D)  I & III 
E)  all of these

Question 15

What is the correct structure for benzyl phenyl ether?

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  none of these 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  none of these

Question 16

What is the IUPAC name for the following compound?

Accepted Answer

5-methyl-2

Question 17

Provide the structure for oxane.

Accepted Answer

The answer of Provide the structure for oxane....

Question 18

Predict the product for the following reaction.

Accepted Answer

The answer of Predict the product for the following reaction....

Question 19

Predict the product for the following reaction.

Accepted Answer

A)  propene 
B)  diethyl ether 
C)  1-hexanol 
D)  1-propoxypropane 
A)  propene 
B)  diethyl ether 
C)  1-hexanol 
D)  1-propoxypropane

Question 20

Provide the reagents necessary to carry out the following reaction.

Accepted Answer

The answer of Provide the reagents necessary to carry out...

Exam 13: Ethers and Epoxides; Thiols and Sulfides

Provide the IUPAC name for the following compound.

Predict the product(s) for the following reaction.

Provide a stepwise curved arrow mechanism for the following reaction.

Provide the reagents necessary to prepare the following compound using alkoxymercuration-demercuration.

Predict the major product for the following reaction.

Predict the product for the following reaction and provide a curved arrow mechanism for the formation of the product.

Which one of the following compounds will be least soluble in water?

Provide the structure for (R)-1,1-dimethoxy-3-phenoxycyclopentane.

What is the IUPAC name for CH3CH2OCH2CH2CH2CH2OCH2CH3?

Provide the structure for 2-iodo-4-isopropyl-1-methoxybenzene.

Which one of the following reactions would produce t-butyl methyl ether in high yield?

Predict the product for the following reaction.

Which of the following crown ether solvates potassium ions?

Which of the following compounds is(are) classified as ethers?

What is the correct structure for benzyl phenyl ether?

What is the IUPAC name for the following compound?

Provide the structure for oxane.

Predict the product for the following reaction.

Predict the product for the following reaction.

Provide the reagents necessary to carry out the following reaction.

A Review of General Chemistry: Electrons, Bonds, and Molecular Properties

Molecular Representations

Acids and Bases

Alkanes and Cycloalkanes

Stereoisomerism

Chemical Reactivity and Mechanisms

Alkyl Halides: Nucleophilic Substitution and Elimination Reactions

Addition Reactions of Alkenes

Alkynes

Radical Reactions

Synthesis

Alcohols and Phenols

Infrared Spectroscopy and Mass Spectrometry

Nuclear Magnetic Resonance Spectroscopy

Conjugated Pi Systems and Pericyclic Reactions

Aromatic Compounds

Aromatic Substitution Reactions

Aldehydes and Ketones

Carboxylic Acids and Their Derivatives

Alpha Carbon Chemistry: Enols and Enolates

Amines

Introduction to Organometallic Compounds

Carbohydrates

Amino Acids, Peptides, and Proteins

Lipids

Synthetic Polymers

Filters

What is the IUPAC name for CH₃CH₂OCH₂CH₂CH₂CH₂OCH₂CH₃?