Question 1

Which of the following is the correct structure of 2-methyl-1-butene?

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
A)  I 
B)  II 
C)  III 
D)  IV

Question 2

Provide a curved arrow mechanism for the following reaction.

Accepted Answer

The answer of Provide a curved arrow mechanism for the...

Question 3

Which of the following is not a possible step in a substitution reaction?

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
A)  I 
B)  II 
C)  III 
D)  IV

Question 4

Provide a curved arrow mechanism for the following reaction.

Accepted Answer

The answer of Provide a curved arrow mechanism for the...

Question 5

Draw the transition state for the following reaction.
(S)-1-iodo-3-methylpentane + NaSCH3

Accepted Answer

Question 6

Provide the reagents necessary to carry out the following conversion.

Accepted Answer

1. TsCl/py

Question 7

What is (are) the most likely product(s) for the following reaction?

Accepted Answer

The answer of What is (are) the most likely product(s)...

Question 8

Predict the product for the following SN2 reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  None of these 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  None of these

Question 9

Provide the reagents necessary to carry out the following conversion.

Accepted Answer

The answer of Provide the reagents necessary to carry out...

Question 10

What is the IUPAC name for the following compound?

Accepted Answer

A)  2-Bromo-4-pentylhexane 
B)  (2S,4S)-2-Bromo-4,5-diethylheptane 
C)  3,4-Diethyl-6-bromoheptane 
D)  2-Bromo-4-methylhexane 
E)  (2R,4R)-2-Bromo-4,5-diethylheptane 
A)  2-Bromo-4-pentylhexane 
B)  (2S,4S)-2-Bromo-4,5-diethylheptane 
C)  3,4-Diethyl-6-bromoheptane 
D)  2-Bromo-4-methylhexane 
E)  (2R,4R)-2-Bromo-4,5-diethylheptane

Question 11

Predict the product for the following reaction.

Accepted Answer

The answer of Predict the product for the following reaction....

Question 12

Predict the product for the following SN2 reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  V 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  V

Question 13

Which of the following describes the difference between protic and aprotic solvents?

Accepted Answer

A)  protic solvents stabilize anions only 
B)  aprotic solvents stabilize anions only 
C)  protic solvents stabilize cations only 
D)  aprotic solvents stabilize both cations and anions 
E)  protic solvents stabilize both cations and anions 
A)  protic solvents stabilize anions only 
B)  aprotic solvents stabilize anions only 
C)  protic solvents stabilize cations only 
D)  aprotic solvents stabilize both cations and anions 
E)  protic solvents stabilize both cations and anions

Question 14

Which of the following is a tertiary alkyl halide?

Accepted Answer

A)  1-Bromo-2-methylpropane 
B)  2-Bromopropane 
C)  1-Bromobutane 
D)  2-Bromo-2-methylpropane 
A)  1-Bromo-2-methylpropane 
B)  2-Bromopropane 
C)  1-Bromobutane 
D)  2-Bromo-2-methylpropane

Question 15

Provide the structure for cis-1,2-dibromocyclopentane.

Accepted Answer

The answer of Provide the structure for cis-1,2-dibromocyclopentane....

Question 16

Identify the IUPAC name for the following compound.

Accepted Answer

A)  1-methyl-2-cyclohexene 
B)  2-methylcyclohexene 
C)  3-methylcyclohexene 
D)  1-methyl-5-cyclohexene 
A)  1-methyl-2-cyclohexene 
B)  2-methylcyclohexene 
C)  3-methylcyclohexene 
D)  1-methyl-5-cyclohexene

Question 17

Which of the following is the rate equation for the following SN1 reaction?

Accepted Answer

A)  Rate = k[H2O] 
B)  Rate = k[1-chloro-1-methylcyclohexane] [H2O] 
C)  Rate = k[chloride ion] 
D)  Rate = k[1-chloro-1-methylcyclohexane] 
A)  Rate = k[H2O] 
B)  Rate = k[1-chloro-1-methylcyclohexane] [H2O] 
C)  Rate = k[chloride ion] 
D)  Rate = k[1-chloro-1-methylcyclohexane]

Question 18

Which of the following is the strongest nucleophile?

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
A)  I 
B)  II 
C)  III 
D)  IV

Question 19

Which of the following is a substitution reaction?

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
A)  I 
B)  II 
C)  III 
D)  IV

Question 20

What is (are) the most likely product(s) for the following reaction?

Accepted Answer

The answer of What is (are) the most likely product(s)...

Exam 7: Alkyl Halides: Nucleophilic Substitution and Elimination Reactions

Which of the following is the correct structure of 2-methyl-1-butene?

Provide a curved arrow mechanism for the following reaction.

Which of the following is not a possible step in a substitution reaction?

Provide a curved arrow mechanism for the following reaction.

Draw the transition state for the following reaction. (S)-1-iodo-3-methylpentane + NaSCH3

Provide the reagents necessary to carry out the following conversion.

What is (are) the most likely product(s) for the following reaction?

Predict the product for the following SN2 reaction.

Provide the reagents necessary to carry out the following conversion.

What is the IUPAC name for the following compound?

Predict the product for the following reaction.

Predict the product for the following SN2 reaction.

Which of the following describes the difference between protic and aprotic solvents?

Which of the following is a tertiary alkyl halide?

Provide the structure for cis-1,2-dibromocyclopentane.

Identify the IUPAC name for the following compound.

Which of the following is the rate equation for the following SN1 reaction?

Which of the following is the strongest nucleophile?

Which of the following is a substitution reaction?

What is (are) the most likely product(s) for the following reaction?

A Review of General Chemistry: Electrons, Bonds, and Molecular Properties

Molecular Representations

Acids and Bases

Alkanes and Cycloalkanes

Stereoisomerism

Chemical Reactivity and Mechanisms

Addition Reactions of Alkenes

Alkynes

Radical Reactions

Synthesis

Alcohols and Phenols

Ethers and Epoxides; Thiols and Sulfides

Infrared Spectroscopy and Mass Spectrometry

Nuclear Magnetic Resonance Spectroscopy

Conjugated Pi Systems and Pericyclic Reactions

Aromatic Compounds

Aromatic Substitution Reactions

Aldehydes and Ketones

Carboxylic Acids and Their Derivatives

Alpha Carbon Chemistry: Enols and Enolates

Amines

Introduction to Organometallic Compounds

Carbohydrates

Amino Acids, Peptides, and Proteins

Lipids

Synthetic Polymers

Filters

Draw the transition state for the following reaction. (S)-1-iodo-3-methylpentane + NaSCH₃

Predict the product for the following S_N2 reaction.

Predict the product for the following S_N2 reaction.

Which of the following is the rate equation for the following S_N1 reaction?