Exam 14: Chemical Equilibrium

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For the following reaction,what is △n required in the conversion of Kc to Kp? KClO3(s)⇌ KClO(s)+ O2(g)

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E

Consider the following reaction at equilibrium.What effect will removing NO2 have on the system? SO2(g)+ NO2(g)⇌ SO3(g)+ NO(g)

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of SO2(g). \quad\quad 2SO2(g)+ O2(g)⇌ 2SO3(g) \quad\quad Kc = 1.7 × 108 M-1 \quad\quad [SO3]eq = 0.0034 mol L-1 \quad\quad [O2]eq = 0.0018 mol L-1

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C

Which of the following statements is TRUE?

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The equilibrium constant,Kp,equals 3.40 for the isomerization reaction: cis-2-butene ⇌ trans-2-butene If a flask initially contains 0.250 bar of cis-2-butene and 0.165 bar of trans-2-butene,what is the equilibrium pressure of each gas?

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The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. \quad H2(g)+ Br2(g)⇌ 2HBr \quad (g)K = 3.8 × 104 \quad 2HBr(g)⇌ H2(g)+ Br2 \quad (g)K = ?

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The reaction below has a Kc value of 61 M-2.What is the value of Kp for this reaction at 500 K? \quad N2(g)+ 3H2(g)⇌ 2NH3(g)

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Express the equilibrium constant for the following reaction: 2 CH3Cl(g)+ Cl2(g)? 2 CH2Cl2(g)+ H2(g)

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Express the equilibrium constant for the following reaction: KClO3(s)? KClO(s)+ O2(g)

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Express the equilibrium constant for the following reaction: PCl5(g)? PCl3(g)+ Cl2(g)

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Give the direction of the reaction if K << 1.

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Express the equilibrium constant for the following reaction: 2NH3(g)? N2(g)+ 3H2(g)

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Define Le Châtelier's principle.

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Kc is 1.67 × 1020 mol3 L-3 at 25 °C for the formation of iron(III)oxalate complex ion: Fe3+(aq)+ 3C2O42-(aq)⇌ [Fe(C2O4)3]3-(aq) If 0.0200 mol L-1 Fe3+ is initially mixed with 1.00 mol L-1 oxalate ion,what is the concentration of Fe3+ ion at equilibrium?

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Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g) A reaction mixture initially contains 0.86 bar NO and 0.86 bar SO3.Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

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How is the reaction quotient different from an equilibrium constant for a given reaction?

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Cyclohexane,C6H12,undergoes a molecular rearrangement in the presence of AlCl3 to form methylcyclopentane,CH3C5H9, according to the equation: \quad\quad C6H12 ⇌ CH3C5H9 If Kc = 0.143 at 25 °C for this reaction,find the equilibrium concentrations of C6H12 and CH3C5H9 if the initial concentrations are 0.200 mol L-1 and 0.075 mol L-1,respectively.

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Consider the following reaction: CH4(g)+ 2H2S(g)⇌ CS2(g)+ 4H2(g) A reaction mixture initially contains 0.50 mol L-1 CH4 and 0.75 mol L-1 H2S.If the equilibrium concentration of H2 is 0.44 mol L-1,find the equilibrium constant (mol L-1)for the reaction.

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Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g) A reaction mixture initially contains 1.24 bar NO and 0.92 bar SO3.Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

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In a reaction mixture containing only products,what is the value of Q?

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