Exam 14: Chemical Equilibrium

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Which of the following statements is TRUE?

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Express the equilibrium constant for the following reaction: \quad\quad 2Na(s)+ 2H2O(l)? 2NaOH(aq)+ H2(g)

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The following reaction is exothermic.Which change will shift the equilibrium to the left? 2SO2(g)+ O2(g)⇌ 2SO3(g)

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At a certain temperature,nitogen and hydrogen react to form ammonia: \quad N2(g)+ 3H2(g)⇌ 2NH3(g) When initial amounts of N2,H2,and NH3 are mixed,the concentration of NH3 increases.Which statement below is TRUE?

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Consider the following reaction,equilibrium pressures,and equilibrium constant at a particular temperature.Determine the equilibrium pressure of CO. \quad\quad CO(g)+ 2H2(g)⇌ CH3OH(l) \quad\quad Kp = 2.25 × 104 bar-3 \quad\quad\quad\quad\quad\quad\quad\quad\quad\quad\quad\quad\quad P(H2)eq = 0.52 bar

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Express the equilibrium constant for the following reaction: 2P(g)+ 3Cl2(g)? 2PCl3(g)

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Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g) A reaction mixture initially contains 2.0 bar NO2 and 1.0 bar SO2.Determine the equilibrium pressure of SO2 if Kp for the reaction at this temperature is 0.0118.

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Consider the following reaction: COCl2(g)⇌ CO(g)+ Cl2(g) A reaction mixture initially contains 1.6 mol L-1 COCl2.Determine the equilibrium concentration of CO if Kc for the reaction at this temperature is 8.33 × 10-4 M.Calculate this based on the assumption that the answer is negligible compared to 1.6.

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Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [H2]eq = 0.14 mol L-1,[I2]eq = 0.39 mol L-1,[HI]eq = 1.6 mol L-1. \quad\quad H2(g)+ I2(g)⇌ 2HI(g)

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Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [HCl]eq = 0.13 mol L-1,[HI]eq = 5.6 × 10-16 mol L-1,[Cl2]eq = 0.0019 mol L-1. \quad\quad 2HCl(g)+ I2(s)⇌ 2HI(g)+ Cl2(g)

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of H2O(g). \quad\quad C2H4(g)+ H2O(g)⇌ C2H5OH(g)Kc = 9.0 × 103 M-1 \quad\quad [C2H4]eq = 0.015 mol L-1 \quad\quad [C2H5OH]eq = 1.69 mol L-1

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The equilibrium constant is equal to 5.00 L mol-1 at 1300 K for the reaction: 2SO2(g)+ O2(g)⇌ 2SO3(g) If initial concentrations are [SO2] = 6.00 mol L-1,[O2] = 0.45 mol L-1,and [SO3] = 9.00 mol L-1,the system is

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Consider the following reaction and its equilibrium constant: I2(g)⇌ 2I(g) \quad\quad Kp = 0.209 atm A reaction mixture contains 0.89 atm I2 and 1.77 atm I.Which of the following statements is TRUE concerning this system?

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Consider the following reaction and its equilibrium constant: 4CuO(s)+ CH4(g)⇌ CO2(g)+ 4Cu(s)+ 2H2O(g)Kc = 1.10 A reaction mixture contains 0.22 mol L-1 CH4,0.67 mol L-1 CO2 and 1.3 mol L-1 H2O.Which of the following statements is TRUE concerning this system?

(Multiple Choice)
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The equilibrium constant is given for two of the reactions below.Determine the value of the missing equilibrium constant. \quad A(g)+ B(g)⇌ AB \quad\quad (g)K = 0.24 \quad AB(g)+ A(g)⇌ A2B \quad (g)K = 3.8 \quad 2A(g)+ B(g)⇌ A2B \quad (g)K = ?

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Consider the following reaction at equilibrium.What effect will increasing the temperature have on the system? C3H8(g)+ 5O2(g)⇌ 3CO2(g)+ 4H2O(l)ΔrH° = -2220 kJ

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Express the equilibrium constant for the following reaction: \quad\quad B(OH)3(aq) + 2H2O(l)? B(OH)3(OH)-(aq)+ H3O+(aq)

(Multiple Choice)
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For the reaction: N2(g)+ 2O2(g)⇌ 2NO2(g),Kc = 8.3 × 10-10 M-1 at 25 °C.What is the concentration of N2 gas at equilibrium when the concentration of NO2 is five times the concentration of O2 gas?

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of CO2(g). \quad\quad NH2COONH4(s)⇌ 2NH3(g)+ CO2(g) \quad Kc = 1.58 × 10-8 M3 \quad\quad [NH3]eq = 2.9 × 10-3 mol L-1

(Multiple Choice)
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Calculate P (NO)eq,if P(NOCl)eq = 0.33 bar,P(Cl2)eq = 0.50 bar,and Kp = 1.9 × 10-2 bar . \quad\quad 2NOCl(g)⇌ 2NO(g)+ Cl2(g)

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