Exam 14: Chemical Equilibrium

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For the following reaction,what is △n required in the conversion of Kc to Kp? P4(s)+ 5O2(g)⇌ P4O10(s)

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The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. \quad N2O4(g)⇌ 2NO2 \quad (g)K = 1.46 \quad 2N2O4(g)⇌ 4NO2 \quad (g)K = ?

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In a reaction mixture containing only reactants,what is the value of Q?

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g). \quad N2O4(g)⇌ 2NO2(g) \quad\quad Kc = 0.21 M \quad [N2O4]eq = 0.068 mol L-1

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For the following reaction,what is Δn required in the conversion of Kc to Kp? \quad 2SO2(g)+ O2(g)⇌ 2SO3(g)

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Phosphorus trichloride and phosphorus pentachloride equilibrate in the presence of molecular chlorine according to the following reaction: PCl3\mathrm { PCl } _ { 3 } (g)+ Cl2\mathrm { Cl } _ { 2 } (g)? PCl5\mathrm { PCl } _ { 5 } (g) An equilibrium mixture at 450 K contains PPCl3\mathrm { P } _ { \mathrm { PCl } _ { 3 } } = 0.124 bar, PCl2\mathrm { P } _ { \mathrm { Cl } _ { 2 } } = 0.157 bar,and PPCl5\mathrm { P } _ { \mathrm { PCl } _ { 5 } } = 1.30 bar.What is the value of Kp at this temperature?

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Express the equilibrium constant for the following reaction: CH3Cl(g)+ 1/2 Cl2(g)? CH2Cl2(g)+ 1/2 H2(g)

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Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g) A reaction mixture initially contains 2.0 bar NO and 1.0 bar SO3.Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

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Calculate the value of [N2]eq if [H2]eq = 2.0 mol L-1,[NH3]eq = 0.50 mol L-1,and Kc = 2.0. \quad\quad N2(g)+ 3H2(g)⇌ 2NH3(g)

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The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. \quad 2SO2(g)+ O2(g)⇌ 2SO3 \quad (g)K = 1.7 × 106 \quad SO3(g)⇌ 1/2 O2(g)+ SO2 \quad (g)K = ?

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The equilibrium constant,Kp,equals 3.40 at 25 °C for the isomerization reaction: \quad\quad cis-2-butene ⇌ trans-2-butene If a flask initially contains 5.00 bar of each gas,in what direction will the system shift to reach equilibrium?

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For which of the following reactions will Kc = Kp?

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For the following reaction,what is △n required in the conversion of Kc to Kp? 2Na(s)+ 2H2O(l)⇌ 2NaOH(aq)+ H2(g)

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Express the equilibrium constant for the following reaction: H2(g)+ Br2(g)? 2HBr(g)

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The equilibrium constant is given for one of two reactions below.Determine the value of the missing equilibrium constant. \quad N2O4(g)⇌ 2NO2(g) \quad K = 1.46 \quad 3N2O4(g)⇌ 6NO2(g) \quad K = ?

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Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(CO)eq = 6.8 × 10-11 atm,P(O2)eq = 1.3 × 10-3 atm,P(CO2)eq = 0.041 atm. \quad\quad 2 CO(g)+ O2(g)⇌ 2 CO2(g)

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The following reaction is exothermic.Which change will shift the equilibrium to the left? 2SO2(g)+ O2(g)⇌ 2SO3(g)

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The following reaction is exothermic.Which change will shift the equilibrium to the left? 2SO2(g)+ O2(g)⇌ 2SO3(g)

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Consider the following reaction at equilibrium.What effect will adding CO2 have on the system? \quad\quad CO2(g)+ C(graphite)⇌ 2CO(g)

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Consider the following reaction at equilibrium.What effect will reducing the pressure of the reaction mixture have on the system? Xe(g)+ 2F2(g)⇌ XeF4(g)

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