Exam 14: Chemical Equilibrium

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g). \quad N2O4(g)⇌ 2NO2(g) \quad\quad Kc = 0.21 M \quad [N2O4]eq = 1.82 mol L-1

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Why is a thermodynamic equilibrium constant unitless?

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Dinitrogen tetroxide partially decomposes according to the following equilibrium: N2\mathrm { N } _ { 2 } O4\mathrm { O } _ { 4 } (g)? 2NO22 \mathrm { NO } _ { 2 } (g) A 1.000 L flask is charged with 6.00 × 10-2 mol of N2\mathrm { N } _ { 2 } O4\mathrm { O } _ { 4 } .At equilibrium,3.21 × 10-2 mol of N2\mathrm { N } _ { 2 } O4\mathrm { O } _ { 4 } remains. KcK _ { c } for this reaction is ________.

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Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g) A reaction mixture initially contains 0.384 bar NO2 and 0.224 bar SO2.Determine the equilibrium pressure of SO2 if Kp for the reaction at this temperature is 0.0118.

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At a certain temperature,Kc equals 1.40 × 102 M-1 for the reaction: 2CO(g)+ O2(g)⇌ 2CO2(g) If a 3.00 L flask contains 0.400 mol of CO2 and 0.100 mol of O2 at equilibrium,how many moles of CO are also present in the flask?

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Consider the following reaction at equilibrium.What effect will reducing the volume of the reaction mixture have on the system? \quad\quad CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g)

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Consider the following reaction at equilibrium.What effect will decreasing the temperature have on the system? \quad\quad CO2(g)+ 2H2O(l)⇌ CH4(g)+ 2O2(g)ΔrH° = +890 kJ

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g). \quad N2O4(g)⇌ 2NO2(g) \quad Kc = 0.21 M \quad [N2O4]eq = 1.34 mol L-1

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For the following reaction,what is Δn required in the conversion of Kc to Kp? \quad N2O4(g)⇌ 2NO2(g)

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Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [PCl5]eq = 0.56 mol L-1,[PCl3]eq = 0.23 mol L-1,[Cl2]eq = 4.4 mol L-1. \quad\quad PCl5(g)⇌ PCl3(g)+ Cl2(g)

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For the following reaction,what is Δn required in the conversion of Kc to Kp? \quad CH4(g)+ H2O(g)⇌ CO(g)+ 3H2(g)

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Which of the following statements is correct?

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For which reaction will Kp = Kc?

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The KpK _ { p } for the reaction below is 1.49 × 108 bar-1 at 100.0 °C: CO(g)+ Cl2\mathrm { Cl } _ { 2 } (g)? COCl2\mathrm { COCl } _ { 2 } (g) In an equilibrium mixture of the three gases, PCO\mathrm { PCO } = PCl2\mathrm { P } _ { \mathrm { Cl } _ { 2 } } = 1.92 × 10-4 bar.The partial pressure of the product,phosgene ( COCl2\mathrm { COCl } _ { 2 } ),is ________ bar.

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Consider the following reaction at equilibrium.What effect will increasing the volume of the reaction mixture have on the system? 2H2S(g)+ 3O2(g)⇌ 2H2O(g)+ 2SO2(g)

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Phosphorus pentachloride decomposes to phosphorus trichloride at high temperatures according to the equation: PCl5( g)⇌PCl3( g)+Cl2( g)\mathrm { PCl } _ { 5 } ( \mathrm {~g} ) \rightleftharpoons \mathrm { PCl } _ { 3 } ( \mathrm {~g} ) + \mathrm { Cl } _ { 2 } ( \mathrm {~g} ) At 250° 0.125 mol L-1 PCl5 is added to the flask.If Kc = 1.80 mol L-1,what are the equilibrium concentrations of each gas?

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Consider the following reaction and its equilibrium constant: I2(g)+ Br2(g)⇌ 2IBr(g)Kc = 1.1 × 102 A reaction mixture contains 0.41 mol L-1 I2,0.27 mol L-1 Br2 and 3.5 mol L-1 IBr.Which of the following statements is TRUE concerning this system?

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Consider the following reaction: CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g) A reaction mixture initially contains 2.9 mol L-1 O2.Determine the equilibrium concentration of O2 if Kc for the reaction at this temperature is 1.5.

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Consider the following reaction at equilibrium.What effect will adding more SO3 have on the system? SO2(g)+ NO2(g)⇌ SO3(g)+ NO(g)

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Which of the following statements is TRUE?

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