Exam 12: Solutions

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At a given temperature the vapour pressures of benzene and toluene are 183 mmHg and 59.2 mmHg,respectively.Calculate the total vapour pressure over a solution of benzene and toluene with Xbenzene = 0.580.

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Determine the freezing point of a solution that contains 78.8 g of naphthalene (C10H8,molar mass = 128.16 g mol-1)dissolved in 722 mL of benzene (d = 0.877 g mL-1).Pure benzene has a melting point of 5.50 °C and a freezing point depression constant of 4.90 °C m-1.

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Choose the aqueous solution with the lowest vapour pressure.These are all solutions of nonvolatile solutes and you should assume ideal van't Hoff factors where applicable.

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Which of the following defines dissolving?

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What is the expected freezing point of a 0.50 mol kg-1 solution of Li2SO4 in water? Kf for water is 1.86 °C m-1.

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Choose the aqueous solution below with the highest freezing point.These are all solutions of nonvolatile solutes and you should assume ideal van't Hoff factors where applicable.

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Calculate the molality of a solution that is prepared by mixing 25.5 mL of CH3OH (d = 0.792 g mL-1)and 387 mL of CH3CH2CH2OH (d = 0.811 g mL-1).

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Which of the following ions should have the most exothermic ΔhydrationH?

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Define the Tyndall effect.

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A nonelectrolyte compound with a molar mass of 862 g mol-1 was dissolved in enough water to make 100 mL of solution at 25 °C and produced an osmotic pressure of 38.4 mbar.Calculate the mass of the compound,in mg,used to make this solution.

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What mass of CuCl2 is contained in 75.85 g of a 22.4% by mass solution of CuCl2 in water?

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The boiling point elevation of an aqueous sucrose solution is found to be 0.39 °C.What mass of sucrose (molar mass = 342.30 g mol-1)would be needed to dissolve in 500.0 g of water? Kb (water)= 0.512 °C m-1.

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Place the following aqueous solutions of nonvolatile,nonionic compounds in order of decreasing osmotic pressure. I.0.011 mol L-1 sucrose II.0.00095 mol L-1 glucose III.0.0060 mol L-1 glycerin

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A 125.0 mL sample of an aqueous solution at 25 °C contains 29.4 mg of an unknown nonelectrolyte compound.If the solution has an osmotic pressure of 24.4 mbar,what is the molar mass of the unknown compound?

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Calculate the solution temperature required to produce an osmotic pressure of 1.18 mbar using 3.72 mg of a protein with a molar mass of 4176 g mol-1 that is dissolved in enough water to create 20.9 mL of solution.

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Identify the major force between acetone and chloroform.

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Place the following solutions in order of increasing osmotic pressure. I.0.15 mol L-1 C2H6O2 \quad II.0.15 mol L-1 MgCl2 \quad III.0.15 mol L-1 NaCl

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What volume of a 0.716 mol L-1 KBr solution is needed to provide 30.5 g of KBr?

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What is the weight percent of vitamin C in a solution made by dissolving 6.50 g of vitamin C,C6H8O6,in 55.0 g of water?

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A small amount,6.78 g,of pentane (C5H12)is mixed with 100.00 g hexane (C6H14).Calculate the vapour pressure of the resulting solution.The vapour pressures of pure pentane and hexane are 425 Torr and 151 Torr,respectively.Assume ideal behaviour.

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