Exam 5: Equilibrium

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Consider the reaction PCl5(g) ff PCl3(g)+ Cl2(g) At a certain temperature,If the initial concentration of PCl5(g)Is 2.0 M, At equilibrium the concentration of Cl2(g) Is 0.30 M.Calculate the value of Kc at this temperature.

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The phase diagram for a pure substance is shown below. The phase diagram for a pure substance is shown below.    At 100 atm and 250 K, The substance exists as At 100 atm and 250 K, The substance exists as

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the triple point for water,4.6 Torr and 0.01 ο\omicron C,varies depending on conditions?

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Consider the following reaction at a certain temperature: PCl5(g) ff PCl3(g)+ Cl2(g) Kc = 0.100 At equilibrium, [PCl5] = 2.00 M and [PCl3] = [Cl2] = 1.00 M.If suddenly 1.00 M PCl3(g)And Cl2(g) Is added,What is the equilibrium concentration of PCl5(g)?

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Which of the following reactions is not affected by an increase in pressure?

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An animal cell assumes its normal volume when it is placed in a solution with a total solute molarity of 0.3 M .If the cell is placed in a solution with a total solute molarity of 0.1 M,

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Given: SO2(g) ff O2(g)+ S(s) Kc = 2.5 ? 10?53 SO3(g) ff 12\frac { 1 } { 2 } O2(g)+ SO2(g) Kc = 4.0 ? 10?13 Calculate Kc for the reaction 2S(s)+ 3O2(g) ff 2SO3(g)

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A gas is a form of matter that can be liquefied at any temperature by pressure alone.

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The equilibrium constant, Kc,For the reaction 2SO2(g)+ O2(g) ff 2SO3(g) Is 11.7 at 1100 K.A mixture of SO2, O2,And SO3, Each with a concentration of 0.015 M,Was introduced into a container at 1100 K.Which of the following is true?

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Estimate the enthalpy of vaporization of CCl4 given that at 25 ο\omicron C and 58 ο\omicron C its vapor pressure is 107 and 405 Torr, respectively.Assume that the enthalpy of vaporization is independent of the temperature.

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For the equilibrium N2O4(g) ff 2NO2(g),plot,on the same graph,the forward and reverse reaction rates as a function of time.If possible, mark on the graph where equilibrium is reached.

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For any reaction at equilibrium, Δ\Delta G < 0

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Calculate the value of K at 700 K for the reaction H2(g)+ I2(g)? 2HI(g) Given that Kc = 54 at the same temperature.

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Calculate the vapor pressure at25 ο\omicron C of a mixture of benzene and toluene in which the mole fraction of benzene is 0.650 .The vapor pressure at 25 ο\omicron C of benzene is 94.6 Torr and that of toluene is 29.1 Torr.

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Which liquid would you expect to be the more volatile,CH3CHO or CH3OCH3?

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At 25?C, Kc = 4.1 * 108 for the reaction N2(g)+ 3H2(g) ff 2NH3(g) Calculate K at 25?C for this reaction.

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What is the relationship between K and Kc for the reaction below? N2(g)+ 3H2(g) ff 2NH3(g)

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Which of the following is likely to have the largest exothermic hydration enthalpy?

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Calculate Δ\Delta G at 298 K for the reaction C2H5OH(l) →\rightarrow C2H5OH(g,0.0400 bar) Given Δ\Delta G ο\omicron = 6.2 kJ at 298 K.

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Of the following five materials, which has the lowest freezing point and the highest boiling point?

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