Exam 5: Equilibrium

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Consider the reaction NO(g)+ 12\frac { 1 } { 2 } O2(g) →\rightarrow NO2(g) If Δ\Delta H ο\omicron = -56.52 kJ and Δ\Delta S ο\omicron = -72.60 J.K-1 at 298 K, What is the equilibrium constant for the reaction at 298 K?

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Consider the reaction CO2(g)+ C(s) →\rightarrow 2CO(g) At equilibrium,at a certain temperature,the partial pressures of CO2(g)and CO(g)are 23.5 and 8.21 atm,respectively.Calculate the value of KP.

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The vapor pressures of pure carbon disulfide and carbon tetrachloride are 360 and 99.8 Torr, respectively,At 296 K.What is the vapor pressure of a solution containing 50.0 g of each compound?

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The following phase diagram is for a pure substance. The following phase diagram is for a pure substance.   Below what temperature does the substance exist as a liquid? Below what temperature does the substance exist as a liquid?

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Consider the reaction 4NH3(g)+ 3O2(g) ff 2N2(g)+ 6H2O(g), K = 1080 at a certain temperature. Initially,All reactants and products have concentrations equal to 12 M. At equilibrium,The approximate concentration of oxygen is

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Which of the following has the smallest freezing point depression and the smallest boiling point elevation?

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Consider the reaction CuSO4(s) →\rightarrow CuO(s)+ SO3(g) If Δ\Delta G ο\omicron = -14.6 kJ at 950 ο\omicron C for this reaction,What is Δ\Delta G for an SO3(g) Pressure of 50 bar at this temperature?

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For CaCl2,the enthalpies of hydration and solution are -2337 and -81 kJ.mol-1,respectively,at 25 ο\omicron C.Calculate the lattice enthalpy of calcium chloride.

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Why is the vapor pressure of trans-dibromoethene is lower than the vapor pressure of cis-dibromoethene?

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A mixture consisting of 0.250 M N2(g) and 0.500 M H2(g) Reaches equilibrium according to the equation below: N2(g)3H2(g) ff 2NH3(g) At equilibrium, The concentration of ammonia is 0.150 M.Calculate the concentration of H2(g) At equilibrium.

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The value of K for a given reaction is a constant and does not have units.

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Which of the following has the highest vapor pressure?

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Consider the reaction CuSO4(s) →\rightarrow CuO(s)+ SO3(g) If Δ\Delta G ο\omicron = -14.6 kJ at 950 ο\omicron C for this reaction,What is Δ\Delta G for an SO3(g) Pressure of 20 bar at this temperature.

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For the reaction 2NOCl(g) ff 2NO(g)+ Cl2(g),if,initially,[NOCl(g)] = 2.8 M,at equilibrium [NO(g)] = 1.2 M.Calculate the equilibrium concentration of NOCl(g).

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On what conditions does the location of the triple point for water-4.6 Torr and 0.01 ο\omicron C -depend?

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The equilibrium constant K for the dissociation of N2O4(g) to NO2(g) Is 1700 at 500 K.Predict its value at 300 K.For this reaction,?H? is 56.8 kJ.mol-1.

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Given: 4NH3(g)+ 5O2(g) ff 4NO(g)+ 6H2O(g) K Calculate the equilibrium constant for the following reaction. 2NO(g)+ 3H2O(g) ff 2NH3(g)+ 52\frac { 5 } { 2 } O2(g)

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The phase diagram for CO2 is given below .The triple point is at 5.1 atm and 217 K.The phase diagram for CO<sub>2</sub> is given below .The triple point is at 5.1 atm and 217 K.   What happens if CO<sub>2</sub>(l)At 30 atm and 450 K is released into a room at 1 atm and 298 K? What happens if CO2(l)At 30 atm and 450 K is released into a room at 1 atm and 298 K?

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A plot of ln(vapor pressure) versus 1/T for methanol gives a straight line with an intercept of 13.6.The entropy of vaporization of methanol is

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Consider the reaction N2(g)3H2(g) ff 2NH3(g) If the initial concentrations of nitrogen and hydrogen are each 1.0 M, and X is the equilibrium concentration of ammonia,what is the correct equilibrium expression?

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