Exam 18: Amines and Heterocycles

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Instructions: Give the major organic product(s)of each of the following reaction or sequence of reactions.Show all relevant stereochemistry. Give major product(s):Instructions: Give the major organic product(s)of each of the following reaction or sequence of reactions.Show all relevant stereochemistry. Give major product(s):

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What is the m/z for the a-cleavage of the following amine?What is the m/z for the a-cleavage of the following amine?

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Predict the major organic product obtained from the following sequence of reactions.Predict the major organic product obtained from the following sequence of reactions.

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Which of the following compounds are tertiary (3 ∘\circ )amines?  Which of the following compounds are tertiary (3<sup> \circ </sup>)amines?

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Rank the following compounds in order of increasing basicity.Label the least basic compound "1" and the most basic compound "4".Place the number corresponding to the compound's rank in the blank below the compound.Rank the following compounds in order of increasing basicity.Label the least basic compound 1 and the most basic compound 4.Place the number corresponding to the compound's rank in the blank below the compound.

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What is the correct assignment of the names of the following aromatic compounds? What is the correct assignment of the names of the following aromatic compounds?

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Instructions: Give the major organic product(s)of each of the following reaction or sequence of reactions.Show all relevant stereochemistry. Give major product(s):Instructions: Give the major organic product(s)of each of the following reaction or sequence of reactions.Show all relevant stereochemistry. Give major product(s):

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The pKa of the 4-methoxyanilinium ion is 5.34.What is the pKb for 4-methoxyaniline?

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