Exam 7: Thermochemistry

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Hydrogen peroxide decomposes to water and oxygen at constant pressure by the following reaction: Hydrogen peroxide decomposes to water and oxygen at constant pressure by the following reaction:      (l)→   O(l)+   (g)    H = -196 kJ Calculate the value of q (kJ)in this exothermic reaction when 4.00 g of hydrogen peroxide decomposes at constant pressure? Hydrogen peroxide decomposes to water and oxygen at constant pressure by the following reaction:      (l)→   O(l)+   (g)    H = -196 kJ Calculate the value of q (kJ)in this exothermic reaction when 4.00 g of hydrogen peroxide decomposes at constant pressure? (l)→ Hydrogen peroxide decomposes to water and oxygen at constant pressure by the following reaction:      (l)→   O(l)+   (g)    H = -196 kJ Calculate the value of q (kJ)in this exothermic reaction when 4.00 g of hydrogen peroxide decomposes at constant pressure? O(l)+ Hydrogen peroxide decomposes to water and oxygen at constant pressure by the following reaction:      (l)→   O(l)+   (g)    H = -196 kJ Calculate the value of q (kJ)in this exothermic reaction when 4.00 g of hydrogen peroxide decomposes at constant pressure? (g) Hydrogen peroxide decomposes to water and oxygen at constant pressure by the following reaction:      (l)→   O(l)+   (g)    H = -196 kJ Calculate the value of q (kJ)in this exothermic reaction when 4.00 g of hydrogen peroxide decomposes at constant pressure? H = -196 kJ Calculate the value of q (kJ)in this exothermic reaction when 4.00 g of hydrogen peroxide decomposes at constant pressure?

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The enthalpy of a system is the internal energy minus the pressure-volume product.

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H2S(g)+ 3/2 O2(g)→ H2O (l)+ SO2(g)ΔrH° = -562.3 kJ/mol 1/8 S8(s)+ O2(g)→ SO2(g)ΔrH° = -297.0 kJ/mol H2(g)+ 1/2O2 → H2O (l)ΔrH° = -266.9 kJ/mol Compute ΔrH° for H2(g)+ 1/8 S8 (s)→ H2S(g)in kJ/mol.

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The heat of combustion of several fuels are listed in the table below.On a per gram basis,which fuel releases the most energy? The heat of combustion of several fuels are listed in the table below.On a per gram basis,which fuel releases the most energy?

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What is the enthalpy of reaction for the neutralization reaction occurring between dilute Ba(OH)2(aq)and dilute HNO3(aq)? Values of ΔfH° from data tables are given below. Hint: Balance the equation so the coefficients are the lowest possible set of whole numbers. What is the enthalpy of reaction for the neutralization reaction occurring between dilute Ba(OH)<sub>2</sub>(aq)and dilute HNO<sub>3</sub>(aq)? Values of Δ<sub>f</sub>H° from data tables are given below. Hint: Balance the equation so the coefficients are the lowest possible set of whole numbers.

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Enthalpy is an extensive property.

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The heat of combustion,ΔrHcomb,of 1-butene(l),C4H8(l),is -2696.9 kJ/mol.From the following values of ΔfH° CO2(g)= -393.5 kJ/mol and ΔfH° H2O(l)= -285.8 kJ/mol,calculate the standard enthalpy of formation of butene(l).

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14.0 g of metal at 24.0 °C has 250 joules of heat added to it.The metal's specific heat is 0.105 J/g °C.What is its final temperature?

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Calculate the kinetic energy of a 150 g baseball moving at a speed of 39.m Calculate the kinetic energy of a 150 g baseball moving at a speed of 39.m   (87 mph). (87 mph).

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A sample gives off 2505 cal when burned in a bomb calorimeter.The temperature of the calorimeter assembly increases by 2.24 °C.What is the heat capacity of the calorimeter?

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When 50.0 mL of 0.400 mol L-1 Ca(NO3)2 is added to 50.0 mL of 0.800 mol L-1 NaF,CaF2 precipitates,as shown in the net ionic equation below.The initial temperature of both solutions is 23.0 °C.Assuming that the reaction goes to completion,and that the resulting solution has a mass of 100.00 g and a specific heat of 4.18 J g-1°C-1 ,calculate the final temperature of the solution. Ca2+(aq)+ 2 F-(aq)→ CaF2(s) When 50.0 mL of 0.400 mol L<sup>-1</sup> Ca(NO<sub>3</sub>)<sub>2</sub> is added to 50.0 mL of 0.800 mol L<sup>-1</sup> NaF,CaF<sub>2</sub> precipitates,as shown in the net ionic equation below.The initial temperature of both solutions is 23.0 °C.Assuming that the reaction goes to completion,and that the resulting solution has a mass of 100.00 g and a specific heat of 4.18 J g<sup>-1</sup>°C<sup>-1</sup> ,calculate the final temperature of the solution. Ca<sup>2+</sup>(aq)+ 2 F<sup>-</sup>(aq)→ CaF<sub>2</sub>(s)    H = -11.5 kJ H = -11.5 kJ

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How much heat is required to raise the temperature of 175 g of aluminum from 21.0 °C to 145 °C? The specific heat of aluminum is 0.903 J g-1 °C-1.

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Calculate the work needed to make room for products in the combustion of sulfur,S8(s),to SO2(g)at STP.

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The specific heat of copper is 0.385 J g-1k-1.If 34.2 g of copper,initially at 21.0 °C,absorbs 4.689 kJ,what will be the final temperature of the copper?

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Choose the INCORRECT statement.

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The standard enthalpy of formation for CuSO4 ∙ 5 H2O(s)is -2278.0 kJ/mol at 25 °C.The chemical equation to which this value applies is:

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A mixture of 125 g of iron and 250 g of water is heated from 25.0 °C to 70.0 °C.How much heat is absorbed by the mixture? (Specific heat of water = 4.18 J/g °C;iron = 0.473 J/g °C)

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Using the heat of combustion of methanol as -726.6 kJ/mol and the following data: Using the heat of combustion of methanol as -726.6 kJ/mol and the following data:   Determine Δ<sub>r</sub>H° for the following reaction: CO(g)+ 2 H<sub>2</sub>(g)→ CH<sub>3</sub>OH(l) Determine ΔrH° for the following reaction: CO(g)+ 2 H2(g)→ CH3OH(l)

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250.0 g of hot coffee at 95.0 °C are placed in a 0.2000 kg mug at 20.0 °C.The specific heat of the coffee is 4.00 J/g °C,while that of the mug is 0.80 J/g °C.Assuming no heat is lost to the surroundings,what is the final temperature of the system: mug + coffee?

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Consider the reaction: Consider the reaction:    Compute Δ<sub>r</sub>H° for this reaction. Compute ΔrH° for this reaction.

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