Exam 8: Let the Titrations Begin

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For the graphical equivalence point determination for a precipitation reaction,which of the following is(are)TRUE? I The steepest slope of the titration curve is the equivalence point. II The equivalence point occurs where the first derivative of the titration curve reaches its largest value. III The equivalence point occurs where the second derivative of the titration curve equals zero.

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E

The end point of some precipitation titrations for mixtures can be up to 3% high.The error is attributed to:

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B

The key step to titration calculations is to relate:

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A

Which of the following terms is INCORRECTLY defined?

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A Na2CO3 standard solution is prepared by transferring 2.4817 grams of primary standard-grade sodium carbonate to a 250.0-mL volumetric flask,dissolving the sample in ~100 mL of distilled deionized water and diluted to the mark.A 25.00-mL aliquot is taken and titrated with 42.65 mL of HCl solution.Calculate the concentration of the HCl solution.

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Calculate pPb when 25.00 mL of 0.150 M CO32− is titrated with 17.00 mL of 0.150 M Pb2+.Ksp = 7.4 x 10−14 for PbCO3.

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A(n)____________________ is a compound with a physical property that changes abruptly near the equivalence point.

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Calculate pPb at the equivalence point when 25.00 mL of 0.120 M CO32− is titrated with 0.120 M Pb2+.Ksp = 7.4 x 10−14 for PbCO3.

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Calculate pPb at the equivalence point when 25.00 mL of 0.100 M CO32- is titrated with 0.100 M Pb2+.Ksp = 7.4 x 10−14 for PbCO3.

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A NaOH solution is standardized using the monoprotic primary standard potassium hydrogen phthalate,KHP (204.22 g/mol. )If 0.6986 g of KHP requires 43.92 mL of NaOH,what is the NaOH concentration?

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Calculate pPb when 25.00 mL of 0.200 M CO32− is titrated with 28.00 mL of 0.200 M Pb2+.Ksp = 7.4 x 10−14 for PbCO3.

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For the precipitation titration of analyte X− by titrant M+,which of the following statements is NOT true?

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Common____________________ indicators are anionic dyes that are attracted to positively charged particles produced immediately after the equivalence point.

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Argentometric titrations are titrations using:

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An aqueous mixture that is 0.100 M Ni2+ and 0.100 M Co2+ M is titrated with a 0.100 M CO32−.Which cation precipitates first and what is pCO32− at the first and second equivalence points.Ksp = 1.0 x 10−10 for CoCO3 and Ksp = 1.3 x 10−7 for NiCO3.

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Calculate pPb when 25.00 mL of 0.100 M CO32− is titrated with 28.00 mL of 0.100 M Pb2+.Ksp = 7.4 x 10−14 for PbCO3.

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Calculate pPb when 25.00 mL of 0.100 M CO32− is titrated with 21.00 mL of 0.100 M Pb2+.Ksp = 7.4 x 10−14 for PbCO3.

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The end point for the Volhard titration is indicated by:

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A compound available in high purity,does not decompose under ordinary storage conditions and stable while being dried by heating or vacuum is a:

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A 1.9450 g sample containing only Na2CO3 and NaHCO3 is titrated with 35.31 mL of 0.8724 M HCl.Calculate the percentage sodium carbonate and sodium bicarbonate.

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