Exam 2: Chemical Measurements
Exam 1: The Analytical Process20 Questions
Exam 2: Chemical Measurements21 Questions
Exam 3: Tools of the Trade19 Questions
Exam 4: Experimental Error20 Questions
Exam 5: Statistics22 Questions
Exam 6: Quality Assurance and Calibration Methods20 Questions
Exam 7: Chemical Equilibrium20 Questions
Exam 8: Let the Titrations Begin20 Questions
Exam 9: Activity and the Systematic Treatment of Equilibrium20 Questions
Exam 10: Monoprotic Acid-Base Equilibria20 Questions
Exam 11: Polyprotic Acid-Base Equilibria20 Questions
Exam 12: Acid-Base Titrations20 Questions
Exam 13: Edta Titrations20 Questions
Exam 14: Advanced Topics in Equilibrium20 Questions
Exam 15: Fundamentals of Electrochemistry20 Questions
Exam 16: Electrodes and Potentiometry20 Questions
Exam 17: Redox Titrations20 Questions
Exam 18: Electroanalytical Techniques20 Questions
Exam 19: Fundamentals of Spectrophotometry23 Questions
Exam 20: Applications of Spectrophotometry20 Questions
Exam 21: Spectrophotometers20 Questions
Exam 22: Atomic Spectroscopy20 Questions
Exam 23: Mass Spectrometry20 Questions
Exam 24: Introduction to Analytical Separations20 Questions
Exam 25: Gas Chromatography20 Questions
Exam 26: High-Performance Liquid Chromatography20 Questions
Exam 27: Chromatographic Methods and Capillary Electrophoresis20 Questions
Exam 28: Gravimetric and Combustion Analysis20 Questions
Exam 29: Sample Preparation19 Questions
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The maximum contaminant level for arsenic is 0.010 ppm for drinking water per EPA regulation.The arsenic concentration for the drinking water of a municipality was measured to be 4.92 10−6 M arsenic.What is the arsenic concentration of the water sample in ppm? Does the water sample meet EPA guidelines? Assume the drinking water sample has a density of 1.0000 g/mL.
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(Short Answer)
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Correct Answer:
0.369 ppm,exceeds EPA regulation
What volume of 12.1 M HCl must be diluted to prepare a 0.2500 M HCl solution with a volume of 2.000 L?
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(Multiple Choice)
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Correct Answer:
A
The calorie content of a candy bar is 230 calories per serving (1 bar).Calculate the specific energy (kJ/g)of the candy bar.(1 candy bar = 52.7 g,1 calorie = 4.184 J)
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(Multiple Choice)
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Correct Answer:
B
A mixture of 50.00 grams propane,C3H8,and 100.00 grams oxygen,O2,is combusted.____________________is the limiting reactant and____________________ grams of____________________ is in excess.(C3H8 = 44.10 g/mol) C3H8 (g)+ 5 O2 (g) 3 CO2 (g)+ 4 H2O (g)
(Multiple Choice)
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On average one gallon of kerosene contains 135,000 BTUs of heat energy per gallon combusted.Convert the energy content of kerosene to SI units.(1 BTU = 1055 J)
(Short Answer)
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Calculate the molarity of a 30.0% hydrogen peroxide solution.The reported density of 30% hydrogen peroxide is 1.135 g/cm3.(H2O2 = 34.0147 g/mol)
(Multiple Choice)
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Calculate the mass NaCH3CO2 contained in 500.0 mL of a 0.1500 M NaCH3CO2 solution.(NaCH3CO2 = 82.0343 g/mol)
(Multiple Choice)
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The recommended daily allowance of calcium for men between the ages of 19 to 50 is 1 000 mg Ca.Three multivitamin tablets are analyzed for calcium gravimetrically with the precipitation of calcium cation by oxalate anion.If the mass dry calcium oxalate obtained is 2.0136 g,how many tablets must a man take in a given day to meet the recommended daily allowance?
Ca2+ (aq)+ C2O42− (aq) CaC2O4 (s)
(Short Answer)
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When solutions of Pb2+ and CrO42− are mixed the precipitate PbCrO4 is produced.What volume of 0.1750 M CrO42− removes all lead from 50.00 mL of a 0.3400 M Pb2+ solution?
(Multiple Choice)
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Arrange the four microscopic views below of four different solutions in order of increasing concentration. 
(Multiple Choice)
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An NaCl solution is labeled as having a concentration of 33.5% by mass.If the NaCl solution has a density of 1.0492 g/mL,what is the molarity of the solution? (NaCl= 58.44 g/mol)
(Short Answer)
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What volume of a 36% HCl solution must be diluted to prepare 1.000 L of a 0.1000 M HCl solution? The density of 36% HCl is 1.18 g/mL.
(Multiple Choice)
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The planet Mars orbits 2.279 1011 m from the Sun.Express the distance using the appropriate prefix.
(Multiple Choice)
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Aqueous lead precipitates when mixed with aqueous carbonate.
Pb2+ (aq)+ CO32− (aq) PbCO3 (s)
If 5.000 g Pb(NO3)2 and 2.500 g Na2CO3 are mixed in water,which ion is the limiting reactant? What mass PbCO3 is precipitated? (PbCO3 = 267.21 g/mol,Pb(NO3)2 = 331.2 g/mol,Na2CO3 = 105.9888 g/mol)
(Essay)
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The sulfur content of an ore is determined gravimetrically by reacting the ore with concentrated nitric acid and potassium chlorate,converting all sulfur to sulfate.The excess nitrate and chlorate is removed by reaction with concentrated hydrochloric acid and the sulfate is precipitated using barium cation. Ba2+ (aq)+ SO42- (aq) BaSO4 (s)
Analysis of 10.1830 grams of a sulfur containing ore yielded 13.0221 grams of BaSO4.What is the percent by mass sulfur in the ore? (BaSO4 = 233.43 g/mol)
(Multiple Choice)
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A student must prepare 500.0 mL of solution containing 0.999 grams of solid copper(II)sulfate.Which of the following statements are FALSE regarding the proper procedure to prepare this solution?
I The 0.999 grams of solid copper(II)sulfate is dissolved in a 500.0-mL volumetric flask containing 500.0 mL of water.
II The 0.999 grams of solid copper(II)sulfate is dissolved in a 500.0-mL volumetric flask containing 400 mL of distilled water before dilution to 500.0-mL.
III The 0.999 grams of solid copper(II)sulfate is placed in an empty 500.0-mL volumetric flask,diluted to 500.0 mL and allowed to dissolve.
(Multiple Choice)
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Which of the statements below are TRUE for expressing the concentration of a 54.9-ppm Fe solution in terms of molarity?
I Iron's molar mass must be known to calculate the moles iron in solution.
II Iron's density must be known to calculate the mass iron in solution.
III The solution density must be known to calculate the solution volume.
IV The type of glassware used to prepare the solution must be known.
(Multiple Choice)
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A satellite in low Earth orbit with a circular orbit has an orbital speed of 7.3 km/s relative to the Earth's surface.Calculate the satellite's speed in miles per hour.
(Multiple Choice)
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Calculate the mass of Na2CO3 needed to prepare a 15.00 mM solution with a volume of 500.0 mL.(Na2CO3 = 105.9888 g/mol)
(Multiple Choice)
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What volume of a 50.0% by mass NaOH solution must be diluted to prepare a 0.3500 M NaOH solution with a volume of 500 mL? The density of 50% NaOH solution is 1.515 g/mL at 25°C.(NaOH = 40.00 g/mol)
(Short Answer)
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