Exam 6: Thermochemistry

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Calculate the amount (mass)of acetic acid (C2H4O2, molar mass = 60.052 g mol-1)that causes a bomb calorimeter with a heat capacity of 8.43 kJ °C-1 to have a temperature increase from 24.5 °C to 36.8 °C. The Δ\Delta rU for the combustion of acetic acid is -874.2 kJ mol-1.

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Two solutions, initially at 24.60 °C, are mixed in a coffee cup calorimeter (Ccal = 15.5 J °C-1). When a 100.0 mL volume of 0.100 mol L-1 AgNO3 solution is mixed with a 100.0 mL sample of 0.200 mol L-1 NaCl solution, the temperature in the calorimeter rises to 25.30 °C. Determine the Δ\Delta rH° for the reaction as written below. Assume that the density and specific heat capacity of the solutions is the same as that of water. NaCl(aq)+ AgNO3(aq)? AgCl(s)+ NaNO3(aq) Δ\Delta rH° = ?

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For For   U to always be -, what must be true? U to always be -, what must be true?

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Using the following equation for the combustion of octane, calculate the amount of grams of carbon dioxide formed from 100.0 g of octane. The molar mass of octane is 114.33 g mol-1. The molar mass of carbon dioxide is 44.0095 g mol-1. 2C8H18 + 25O2 → 16CO2 + 18H2O ΔrH° = -11018 kJ

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Use the standard reaction enthalpies given below to determine ΔrH° for the following reaction: P4(g)+ 10Cl2(g)→ 4PCl5(s)ΔrH° = ? Given: PCl5(s)→ PCl3(g)+ Cl2(g)ΔrH°= +157 kJ P4(g)+ 6Cl2(g)→ 4PCl3(g)ΔrH° = -1207 kJ

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A 12.8 g sample of ethanol (C2H5OH)is burned in a bomb calorimeter with a heat capacity of 5.65 kJ °C-1. Using the information below, determine the final temperature of the calorimeter if the initial temperature is 25.0°C. The molar mass of ethanol is 46.07 g mol-1. C2H5OH(l)+ 3O2(g)→ 2CO2(g)+ 3H2O(g)ΔrU = -1235 kJ mol-1

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Calculate the amount of heat (in kJ)required to raise the temperature of a 79.0 g sample of ethanol from 298.0 K to 385.0 K. The specific heat capacity of ethanol is 2.42 J g-1 °C-1.

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Where does the energy absorbed during an endothermic reaction go?

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Use the information provided to determine ΔrH° for the following reaction: ΔfH°(kJ mol-1)CH4(g)+ 4 Cl2(g)→ CCl4(g)+ 4 HCl(g)ΔrH° = ? CH4(g) -75 CCl4(g) -96 HCl(g) -92

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Match the following. --q

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The specific heat capacity of liquid water is 4.184 J g-1 K-1. How many joules of heat are needed to raise the temperature of 6.00 g of water from 36.0 °C to 75.0 °C?

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A piece of iron (C = 0.449 J g-1 °C-1 and a piece of gold (C = 0.128 J g-1 °C-1)have identical masses. If the iron has an initial temperature of 498 K and the gold has an initial temperature of 298 K, which of the following statements is TRUE of the outcome when the two metals are placed in contact with one another? Assume no heat is lost to the surroundings.

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According to the following reaction, how much energy is evolved during the reaction of 2.50 L B2H6 and 5.65 L Cl2 (both gases are initially at STP)? The molar mass of B2H6 is 27.67 g mol-1. B2H6(g)+ 6Cl2(g)→ 2BCl3(g)+ 6HCl(g)ΔrH° = -1396 kJ

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An unknown metal alloy, specific heat capacity = 0.372 J g-1 °C-1, has a temperature change of +21.7 °C after a heat transfer of 216.4 J. Calculate the mass of the alloy in question.

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Explain the difference between ΔH and ΔU.

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Identify a substance that is NOT in its standard state.

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Using the following thermochemical equation, determine the amount of heat produced per kg of CO2 formed during the combustion of benzene (C6H6). 2C6H6(l)+ 15O2(g)→ 12CO2(g)+ 6H2O(g)ΔrH° = -6278 kJ

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How much energy is required to decompose 765 g of PCl3 according to the reaction below? The molar mass of PCl3 is 137.32 g mol-1 and may be useful. 4PCl3(g)→ P4(s)+ 6Cl2(g)ΔrH° = +1207 kJ

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Determine the final temperature of a gold nugget (mass = 376 g)that starts at 398 K and loses 4.85 kJ of heat to a snowbank when it is lost. The specific heat capacity of gold is 0.128 J g-1 °C-1.

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In the presence of excess oxygen, methane gas burns in a constant-pressure system to yield carbon dioxide and water: CH4 (g)+ 2O2 (g)→ + CO2(g)+ 2H2O (l)ΔrH = -890.0 kJ Calculate the value of q (kJ)in this exothermic reaction when 1.90 g of methane is combusted at constant pressure.

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