Exam 6: Thermochemistry

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A 4.98 g sample of aniline (C6H5NH2, molar mass = 93.13 g mol-1)was combusted in a bomb calorimeter with a heat capacity of 4.25 kJ °C-1. If the temperature rose from 29.5 °C to 69.8 °C, determine the value of ΔrU for the combustion of aniline.

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Choose the reaction that illustrates ΔfH° for NaHCO3.

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Match the following. -+ΔU

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Match the following. --ΔU

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How much energy is evolved during the reaction of 48.7 g of Al according to the reaction below? Assume that there is excess Fe2O3. Fe2O3(s)+ 2Al(s)→ Al2O3(s)+ 2Fe(s)ΔrH° = -852 kJ

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Which of the following is not a major contributor to energy consumption?

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An 8.21 g sample of glycerol (C3H8O3, molar mass = 92.0938 g mol-1)was combusted in a bomb calorimeter with a heat capacity of 10.61 kJ °C-1. If the temperature increased from 22.1 °C to 36.0 °C, determine ΔrU for the combustion of glycerol.

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Match the following. -energy associated with the temperature of an object

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Why are the standard heats of formation for elements in their most stable form assigned a value of 0?

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Use the standard reaction enthalpies given below to determine ΔrH° for the following reaction: 4SO3(g)→ 4S(s)+ 6O2(g) ΔrH° = ? Given: SO2(g)→ S(s)+ O2(g) ΔrH° = +296.8 kJ 2SO2(g)+ O2(g)→ 2SO3(g)ΔrH° = -197.8 kJ

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8.000 moles of H2(g)reacts with 4.000 mol of O2(g)to form 8.000 mol of H2O(l)at 25 °C and a constant pressure of 1.0133 bar. If 546.4 kJ of heat are released during this reaction, and PΔV is equal to -29.60 kJ, then

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Which of the following signs on q and w represent a system that is doing work on the surroundings as well as losing heat to the surroundings?

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Identify what a coffee cup calorimeter measures.

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The temperature rises from 25.00 °C to 29.00 °C when 3.50 g of sucrose undergoes combustion in a bomb calorimeter. Calculate ΔrU for the combustion of sucrose in kJ mol-1 sucrose. The heat capacity of the calorimeter is 4.90 kJ °C-1. The molar mass of sugar is 342.3 g mol-1.

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When 50.0 mL of 0.400 mol L-1 Ca(NO3)2 is added to 50.0 mL of 0.800 mol L-1 NaF, CaF2 precipitates, as shown in the net ionic equation below. The initial temperature of both solutions is 23.0 °C. Assuming that the reaction goes to completion, and that the resulting solution has a mass of 100.00 g and a specific heat of 4.18 J g-1°C-1, calculate the final temperature of the solution. Ca2+(aq)+ 2F-(aq)→ CaF2(s) When 50.0 mL of 0.400 mol L<sup>-1</sup> Ca(NO<sub>3</sub>)<sub>2</sub> is added to 50.0 mL of 0.800 mol L<sup>-1</sup> NaF, CaF<sub>2</sub> precipitates, as shown in the net ionic equation below. The initial temperature of both solutions is 23.0 °C. Assuming that the reaction goes to completion, and that the resulting solution has a mass of 100.00 g and a specific heat of 4.18 J g<sup>-1</sup>°C<sup>-1</sup>, calculate the final temperature of the solution. Ca<sup>2+</sup>(aq)+ 2F<sup>-</sup>(aq)→ CaF<sub>2</sub>(s)   H = -11.5 kJ H = -11.5 kJ

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How much heat is absorbed/released when 40.00 g of NH3(g)reacts in the presence of excess O2(g)to produce NO(g)and H2O(l)according to the following chemical equation? 4NH3(g)+ 5O2(g)→ 4NO(g)+ 6H2O(l)ΔrH° = 1168 kJ

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Identify an energy source that is NOT renewable.

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The specific heat capacity of liquid mercury is 0.14 J g-1 K-1. How many joules of heat are needed to raise the temperature of 5.00 g of mercury from 15.0 °C to 36.5 °C?

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Match the following. -energy associated with the relative positions of electrons and nuclei in atoms and molecules

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Define specific heat capacity.

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