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Exam 7: Alkyl Halides and Nucleophilic Substitution

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Exam 1: Structure and Bonding70 Questionsadd course
Exam 2: Acids and Bases48 Questionsadd course
Exam 3: Introduction to Organic Molecules and Functional Groups48 Questionsadd course
Exam 4: Alkanes56 Questionsadd course
Exam 5: Stereochemistry68 Questionsadd course
Exam 6: Understanding Organic Reactions43 Questionsadd course
Exam 7: Alkyl Halides and Nucleophilic Substitution64 Questionsadd course
Exam 8: Alkyl Halides and Elimination Reactions45 Questionsadd course
Exam 9: Alcohols, Ethers and Epoxides49 Questionsadd course
Exam 10: Alkenes47 Questionsadd course
Exam 11: Alkynes45 Questionsadd course
Exam 12: Oxidation and Reduction43 Questionsadd course
Exam 13: Mass Spectrometry and Infrared Spectroscopy42 Questionsadd course
Exam 14: Nuclear Magnetic Resonance Spectroscopy43 Questionsadd course
Exam 15: Radical Reactions43 Questionsadd course
Exam 16: Conjugation, Resonance, and Dienes44 Questionsadd course
Exam 17: Benzene and Aromatic Compounds40 Questionsadd course
Exam 18: Electrophilic Aromatic Substitution51 Questionsadd course
Exam 19: Carboxylic Acids and the Acidity of the O-H Bond44 Questionsadd course
Exam 20: Introduction to Carbonyl Chemistry; Organometallic Reagents; Oxidation and Reduction53 Questionsadd course
Exam 21: Aldehydes and Ketones Nucleophilic Addition45 Questionsadd course
Exam 22: Carboxylic Acids and Derivatives47 Questionsadd course
Exam 23: Substitution Reactions of Carbonyl Compounds at the Alpha-Carbon41 Questionsadd course
Exam 24: Carbonyl Condensation Reactions45 Questionsadd course
Exam 25: Amines58 Questionsadd course
Exam 26: Carbon-Carbon Bond Forming Reactions in Organic Synthesis41 Questionsadd course
Exam 27: Pericyclic Reactions52 Questionsadd course
Exam 28: Carbohydrates41 Questionsadd course
Exam 29: Amino Acids and Proteins41 Questionsadd course
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For the following reaction, use the identity of the alkyl halide and nucleophile to determine which substitution mechanism occurs. Then determine which solvent affords the faster reaction. For the following reaction, use the identity of the alkyl halide and nucleophile to determine which substitution mechanism occurs. Then determine which solvent affords the faster reaction.

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Question 21

What is the IUPAC name of the following compound? What is the IUPAC name of the following compound?

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Question 22

Which of the following anions is the most nucleophilic in polar aprotic solvents?

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Question 23

Which of the following statements is not true?

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Question 24

Rank the following in order of decreasing leaving group ability, putting the best first. I II III IV

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Question 25

Rank the following ions in order of increasing nucleophlicity in polar protic solvents, starting with the least nucleophilic ion. I II III IV

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Question 26

What is the product of the nucleophilic substitution reaction shown below? What is the product of the nucleophilic substitution reaction shown below?

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Question 27

What is the product of the nucleophilic substitution reaction shown below? What is the product of the nucleophilic substitution reaction shown below?

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Question 28

What is the starting material in the reaction shown below? What is the starting material in the reaction shown below?

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Question 29

Which of the following statements about the SN2 mechanism for nucleophilic substitution reactions is true?

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Question 30

Which of the following statements about the Hammond postulate is true?

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Question 31

Which of the following statements about an SN1 reaction mechanism is true?

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Question 32

Which of the following statements about the reactions of alkyl halides is true?

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Question 33

Which of the following statements is not true?

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Question 34

What is the IUPAC name of the following compound? What is the IUPAC name of the following compound?

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Question 35

The reaction of tert-butyl bromide, (CH3)3CBr, with ethanol affords the substitution product tert-butyl ethyl ether, (CH3)3COCH2CH3, in acidic conditions. What would happen to the rate of the reaction if the concentration of ethanol was doubled?

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Question 36

What is the IUPAC name of the following compound? What is the IUPAC name of the following compound?

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Question 37

Which of the following carbocations is the most stable? Which of the following carbocations is the most stable?

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Question 38

What is the IUPAC name of the following compound? What is the IUPAC name of the following compound?

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Question 39

Which of the following alkyl halides is a vinyl alkyl halide? Which of the following alkyl halides is a vinyl alkyl halide?

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Question 40
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