Exam 7: Kinetics

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Consider the reaction NOBr(g) →\rightarrow NO(g)+ ½Br2(g) A plot of [NOBr]-sup>1 vs t gives a straight line with a slope of 2.00 M-1.s-1.The order of the reaction and the rate constant,Respectively,Are

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A first-order reaction has a rate constant of 0.00300 s-1 .The time required for 60% reaction is

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If the average rate of formation of H2(g) is 3.90 (mol H2).L-1.s-1 for the reaction2PH3(g) →\rightarrow 2P(g)+ 3H2(g),The unique average reaction rate is

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For a second-order reaction, a straight line is obtained from a plot of

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Consider the reaction 2N2O5(g) →\rightarrow 4NO2(g)+ O2(g) Rate = k[N2O5] Calculate the time for the concentration of N2O5 to fall to one-fourth its initial value if the half-life is 133 s.

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What is the rate constant for a first-order reaction with a half-life of 9.0 ms?

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If the average rate of decomposition of PH3(g) is 3.2 (mol PH3).L-1.min-1 for the reaction 2PH3(g) →\rightarrow 2P(g)+ 3H2(g), The unique average reaction rate is

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An elementary process has an activation energy of 92 kJ/mol .If the enthalpy change for the reaction is -62 kJ/mol, What is the activation energy for the reverse reaction?

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Consider the mechanism ClO-(aq)+ H2O(l) ff HOCl(aq)+ OH-(aq) K,fast I-(aq)+ HOCl(aq) →\rightarrow HOI(aq)+ Cl-(aq) k,slow HOI(aq)+ OH-(aq) →\rightarrow OI-(aq)+ H2O(l) k,fast Draw the reaction profile for this mechanism.

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Consider the following mechanism for the destruction of ozone. O3 + NO →\rarr NO2 + O2 NO2 + O →\rarr NO + O2 What is the catalyst in this reaction?

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Consider the reaction 2N2O(g) →\rightarrow 2N2(g)+ O2(g) Rate = k[N2O]For an initial concentration of N2O of 0.50 M,What is the concentration of N2O remaining after 2.0 min if k = 3.4 * 10-3 s-1?

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A second-order reaction has a rate constant of 1.25 M-1.s-1 .If the initial reactant concentration is 1.0 M,Calculate the time required for 90% reaction.

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The concentration-time dependence is shown below for two first-order reactions is: The concentration-time dependence is shown below for two first-order reactions is:     Which reaction has the larger rate constant? Which reaction has the larger rate constant?

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A catalyst facilitates a reaction by

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What is the half-life of a reaction that has a rate constant of 280 s-1?

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The reaction profile for the mechanism NO2(g)+ F2(g) →\rightarrow NO2F(g)+ F(g) Slow F(g)+ NO2(g) →\rightarrow NO2F(g) Fast Shows

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The reduction of M3+ by Cr2+ was studied with [Cr2+] 100 times the concentration of Cr2+ .When [Cr2+] = 0.0050 M,The rate was 2.5 s-1.The rate constant for this reaction is

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If the rate of a reaction increases by a factor of 64 when the concentration of reactant increases by a factor of 4, the order of the reaction with respect to this reactant is

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The rate law for the following mechanism is ClO-(aq)+ H2O(l) ff HOCl(aq)+ OH-(aq) K,Fast I-(aq)+ HOCl(aq) →\rightarrow HOI(aq)+ Cl-(aq) K1,Slow HOI(aq)+ OH-(aq) →\rightarrow OI-(aq)+ H2O(l) K2,Fast

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Technetium-99m, used to image the heart and brain,Has a half-life of 6.00 h. What fraction of technetium-99m remains in the body after 1 day?

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