Exam 19: Electrochemistry

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What is the half-reaction that occurs at the cathode during electrolysis of an aqueous potassium iodide solution? Reduction Half-Reaction E° (V) K+(aq)+ e- What is the half-reaction that occurs at the cathode during electrolysis of an aqueous potassium iodide solution? Reduction Half-Reaction E° (V) K<sup>+</sup>(aq)+ e<sup>-</sup>  K(s) -2.93 Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s) -2.37 2H<sub>2</sub>O(l)+ 2e<sup>-</sup>  H<sub>2</sub>(g)+ 2OH<sup>-</sup>(aq) -0.83 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g) 0.00 I<sub>2</sub>(s)+ 2e<sup>-</sup>  2I<sup>-</sup>(aq) 0.54 O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l) 1.23K(s) -2.93 Mg2+(aq)+ 2e- What is the half-reaction that occurs at the cathode during electrolysis of an aqueous potassium iodide solution? Reduction Half-Reaction E° (V) K<sup>+</sup>(aq)+ e<sup>-</sup>  K(s) -2.93 Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s) -2.37 2H<sub>2</sub>O(l)+ 2e<sup>-</sup>  H<sub>2</sub>(g)+ 2OH<sup>-</sup>(aq) -0.83 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g) 0.00 I<sub>2</sub>(s)+ 2e<sup>-</sup>  2I<sup>-</sup>(aq) 0.54 O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l) 1.23Mg(s) -2.37 2H2O(l)+ 2e- What is the half-reaction that occurs at the cathode during electrolysis of an aqueous potassium iodide solution? Reduction Half-Reaction E° (V) K<sup>+</sup>(aq)+ e<sup>-</sup>  K(s) -2.93 Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s) -2.37 2H<sub>2</sub>O(l)+ 2e<sup>-</sup>  H<sub>2</sub>(g)+ 2OH<sup>-</sup>(aq) -0.83 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g) 0.00 I<sub>2</sub>(s)+ 2e<sup>-</sup>  2I<sup>-</sup>(aq) 0.54 O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l) 1.23H2(g)+ 2OH-(aq) -0.83 2H+(aq)+ 2e- What is the half-reaction that occurs at the cathode during electrolysis of an aqueous potassium iodide solution? Reduction Half-Reaction E° (V) K<sup>+</sup>(aq)+ e<sup>-</sup>  K(s) -2.93 Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s) -2.37 2H<sub>2</sub>O(l)+ 2e<sup>-</sup>  H<sub>2</sub>(g)+ 2OH<sup>-</sup>(aq) -0.83 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g) 0.00 I<sub>2</sub>(s)+ 2e<sup>-</sup>  2I<sup>-</sup>(aq) 0.54 O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l) 1.23H2(g) 0.00 I2(s)+ 2e- What is the half-reaction that occurs at the cathode during electrolysis of an aqueous potassium iodide solution? Reduction Half-Reaction E° (V) K<sup>+</sup>(aq)+ e<sup>-</sup>  K(s) -2.93 Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s) -2.37 2H<sub>2</sub>O(l)+ 2e<sup>-</sup>  H<sub>2</sub>(g)+ 2OH<sup>-</sup>(aq) -0.83 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g) 0.00 I<sub>2</sub>(s)+ 2e<sup>-</sup>  2I<sup>-</sup>(aq) 0.54 O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l) 1.232I-(aq) 0.54 O2(g)+ 4H+(aq)+ 4e- What is the half-reaction that occurs at the cathode during electrolysis of an aqueous potassium iodide solution? Reduction Half-Reaction E° (V) K<sup>+</sup>(aq)+ e<sup>-</sup>  K(s) -2.93 Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s) -2.37 2H<sub>2</sub>O(l)+ 2e<sup>-</sup>  H<sub>2</sub>(g)+ 2OH<sup>-</sup>(aq) -0.83 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g) 0.00 I<sub>2</sub>(s)+ 2e<sup>-</sup>  2I<sup>-</sup>(aq) 0.54 O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l) 1.232H2O(l) 1.23

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What is E°cell for the cell reaction 2Cr(s)+ 3Sn4+ (aq​)→ 3Sn2+(aq)+ 2Cr3+ (aq​)? Cr3+ (aq​)+ 3e- What is E°<sub>cell</sub> for the cell reaction 2Cr(s)+ 3Sn<sup>4+</sup> (aq​)→ 3Sn<sup>2+</sup>(aq)+ 2Cr<sup>3+</sup> (aq​)? Cr<sup>3+</sup><sup> </sup>(aq​)+ 3e<sup>-</sup>  Cr(s); E° = -0.74V       ​Cr(s); E° = -0.74V What is E°<sub>cell</sub> for the cell reaction 2Cr(s)+ 3Sn<sup>4+</sup> (aq​)→ 3Sn<sup>2+</sup>(aq)+ 2Cr<sup>3+</sup> (aq​)? Cr<sup>3+</sup><sup> </sup>(aq​)+ 3e<sup>-</sup>  Cr(s); E° = -0.74V       ​ What is E°<sub>cell</sub> for the cell reaction 2Cr(s)+ 3Sn<sup>4+</sup> (aq​)→ 3Sn<sup>2+</sup>(aq)+ 2Cr<sup>3+</sup> (aq​)? Cr<sup>3+</sup><sup> </sup>(aq​)+ 3e<sup>-</sup>  Cr(s); E° = -0.74V       ​ What is E°<sub>cell</sub> for the cell reaction 2Cr(s)+ 3Sn<sup>4+</sup> (aq​)→ 3Sn<sup>2+</sup>(aq)+ 2Cr<sup>3+</sup> (aq​)? Cr<sup>3+</sup><sup> </sup>(aq​)+ 3e<sup>-</sup>  Cr(s); E° = -0.74V       ​ ​

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The cell potential of an electrochemical cell with the cell reaction Al(s)+ Cr3+(aq)→ Cr(s)+ Al3+(aq) Is 1.63 V.What is the maximum electrical work obtainable from this cell when 0.50 g of Al is consumed?

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If an electrolysis plant operates its electrolytic cells at a total current of 1.4 × 106 A,how long will it take to produce one metric ton (one million grams)of Mg(s)from seawater containing Mg2+? (1 faraday = 96,485 coulombs)

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Molten magnesium chloride is electrolyzed using inert electrodes and reactions represented by the following two half-reactions: 2Cl-(l)→ Cl2(g)+ 2e- Mg2+(l)+ 2e- → Mg(s) Concerning this electrolysis,which of the following statements is true?

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Consider the following cell reaction: 2Cr(s)+ 6H+(aq)→ 2Cr3+(aq)+ 3H2(g); E°cell = 0.74V Under standard-state conditions,what is E° for the following half-reaction? Cr3+(aq)+ 3e− → Cr(s)

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Consider the following reduction potentials: Cd2+(aq)+ 2e- Consider the following reduction potentials: Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 V Br<sub>2</sub>(l)+ 2e<sup>-</sup>  2Br<sup>-</sup>(aq); E° = 1.07 V Under standard-state conditions,which of the following reactions is spontaneous?Cd(s); E° = -0.40 V Pb2+(aq)+ 2e- Consider the following reduction potentials: Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 V Br<sub>2</sub>(l)+ 2e<sup>-</sup>  2Br<sup>-</sup>(aq); E° = 1.07 V Under standard-state conditions,which of the following reactions is spontaneous?Pb(s); E° = -0.13 V Cu2+(aq)+ 2e- Consider the following reduction potentials: Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 V Br<sub>2</sub>(l)+ 2e<sup>-</sup>  2Br<sup>-</sup>(aq); E° = 1.07 V Under standard-state conditions,which of the following reactions is spontaneous?Cu(s); E° = 0.34 V Br2(l)+ 2e- Consider the following reduction potentials: Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 V Br<sub>2</sub>(l)+ 2e<sup>-</sup>  2Br<sup>-</sup>(aq); E° = 1.07 V Under standard-state conditions,which of the following reactions is spontaneous?2Br-(aq); E° = 1.07 V Under standard-state conditions,which of the following reactions is spontaneous?

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Which reaction would be most likely to occur at the anode of a voltaic cell?

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Consider the following standard reduction potentials: 2H+(aq)+ 2e- Consider the following standard reduction potentials: 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V Sn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Sn(s); E° = -0.15 V Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Which pair of substances will react spontaneously under standard-state conditions?H2(g); E° = 0.00 V Sn2+(aq)+ 2e- Consider the following standard reduction potentials: 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V Sn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Sn(s); E° = -0.15 V Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Which pair of substances will react spontaneously under standard-state conditions?Sn(s); E° = -0.15 V Cd2+(aq)+ 2e- Consider the following standard reduction potentials: 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V Sn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Sn(s); E° = -0.15 V Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Which pair of substances will react spontaneously under standard-state conditions?Cd(s); E° = -0.40 V Which pair of substances will react spontaneously under standard-state conditions?

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Which of the following cell reactions would require the use of an inert electrode?

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Which of the following statements is true about a voltaic cell for which E°cell = 1.00 V?

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Consider the following standard electrode potentials: Ag+(aq)+ e- Consider the following standard electrode potentials: Ag<sup>+</sup>(aq)+ e<sup>-</sup>  Ag(s); E° = 0.80 V Mn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mn(s); E° = -1.18 V Which of the following statements is false concerning the electrochemical cell given below? Mn(s)| Mn<sup>2+</sup>(aq)|| Ag<sup>+</sup>(aq)| Ag(s)Ag(s); E° = 0.80 V Mn2+(aq)+ 2e- Consider the following standard electrode potentials: Ag<sup>+</sup>(aq)+ e<sup>-</sup>  Ag(s); E° = 0.80 V Mn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mn(s); E° = -1.18 V Which of the following statements is false concerning the electrochemical cell given below? Mn(s)| Mn<sup>2+</sup>(aq)|| Ag<sup>+</sup>(aq)| Ag(s)Mn(s); E° = -1.18 V Which of the following statements is false concerning the electrochemical cell given below? Mn(s)| Mn2+(aq)|| Ag+(aq)| Ag(s)

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Copper is electroplated from CuSO4 solution.A constant current of 4.06 A is applied by an external power supply.How long will it take to deposit 1.00 ×102 g of Cu? The atomic weight of copper is 63.546.

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Consider the following cell reaction: 2Hg2+(aq)+ H2(g)→ 2H+(aq)+ Hg22+(aq); E°cell = 0.92 V Under standard-state conditions,what is E° for the following half-reaction? Hg2+(aq)+ 2e- → Hg22+(aq)

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Which of the following statements is true concerning the electrochemical cell depicted below? Zn | Zn2+(aq)|| Cu2+(aq)| Cu Zn2+(aq)+ 2e− Which of the following statements is true concerning the electrochemical cell depicted below? Zn | Zn<sup>2+</sup>(aq)|| Cu<sup>2+</sup>(aq)| Cu Zn<sup>2+</sup>(aq)+ 2e−  Zn(s); E° = -2.87 V Cu<sup>2+</sup>(aq)+ 2e−  Cu(s); E° = -2.38 VZn(s); E° = -2.87 V Cu2+(aq)+ 2e− Which of the following statements is true concerning the electrochemical cell depicted below? Zn | Zn<sup>2+</sup>(aq)|| Cu<sup>2+</sup>(aq)| Cu Zn<sup>2+</sup>(aq)+ 2e−  Zn(s); E° = -2.87 V Cu<sup>2+</sup>(aq)+ 2e−  Cu(s); E° = -2.38 VCu(s); E° = -2.38 V

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Which of the following statements is true concerning the voltaic cell shown below? Which of the following statements is true concerning the voltaic cell shown below?

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An amalgam is an alloy of _____ with any other metal.

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How many faradays are involved in the conversion of a mole of Mn2O3 to MnO2 ?

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What half-reaction occurs at the cathode during the electrolysis of molten potassium bromide?

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A voltaic cell is made by placing a zinc electrode in a compartment in which the Zn2+ concentration is 2.0 × 10-5 M and by placing a Pt electrode in the other compartment,in which the H+ concentration is 3.4 M and PH2 = 1.00 atm.The Zn2+/Zn half-cell reduction potential is -0.76 V,and the H+/H2 half-cell reduction potential is 0.00 V.What is the equilibrium constant at 25°C for the spontaneous cell reaction?

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