Exam 19: Electrochemistry

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A solution of A solution of   is electrolytically reduced to Mn<sup>3+</sup>.A current of 5.19 A is passed through the solution for 15.0 min.What is the number of moles of Mn<sup>3+</sup> produced in this process? (1 faraday = 96,486 coulombs) is electrolytically reduced to Mn3+.A current of 5.19 A is passed through the solution for 15.0 min.What is the number of moles of Mn3+ produced in this process? (1 faraday = 96,486 coulombs)

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Which of the following statements is true concerning half-cell I as the voltaic cell shown below discharges? Which of the following statements is true concerning half-cell I as the voltaic cell shown below discharges?

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What is the SI unit of potential difference?

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Gold (atomic weight = 197)is plated from a solution of chlorauric acid,HAuCl4; it deposits on the cathode.Calculate the time it takes to deposit 0.77 g of gold,passing a current of 0.10 A.(1 faraday = 96,485 coulombs)

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Which of the following statements about batteries is false?

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Calculate the maximum electrical work obtainable at 25oC from the following voltaic cell. Cd(s)|Cd2+(0.840M​)||Cl2(g​,0.0354atm)|Cl-(0.0473M​)|Pt;Eºcell = 1.76V

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What is the copper(II)-ion concentration at 25°C in the cell Zn(s)| Zn2+(1.0 M)|| Cu2+(aq)| Cu(s)if the measured cell potential is 1.08 V? The standard cell potential is 1.10 V.

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Which of the following is true for a reaction that is nonspontaneous as written?

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Given: Pb2+(aq)+ 2e- Given: Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V NO<sub>3</sub><sup>-</sup>(aq)+4H<sup>+</sup>(aq)+ 3e<sup>-</sup> NO(g)+ 2H<sub>2</sub>O(l); E° = 0.96 V O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l); E° = 1.23 V PbO<sub>2</sub>(s)+ SO<sub>4</sub><sup>2-</sup>(aq)+ 4H<sup>+</sup>(aq)+ 2e<sup>-</sup>  PbSO<sub>4</sub>(s)+ 2H<sub>2</sub>O(l); E° = 1.69 V Under standard-state conditions,which of the following is the best oxidizing agent?Pb(s); E° = -0.13 V 2H+(aq)+ 2e- Given: Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V NO<sub>3</sub><sup>-</sup>(aq)+4H<sup>+</sup>(aq)+ 3e<sup>-</sup> NO(g)+ 2H<sub>2</sub>O(l); E° = 0.96 V O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l); E° = 1.23 V PbO<sub>2</sub>(s)+ SO<sub>4</sub><sup>2-</sup>(aq)+ 4H<sup>+</sup>(aq)+ 2e<sup>-</sup>  PbSO<sub>4</sub>(s)+ 2H<sub>2</sub>O(l); E° = 1.69 V Under standard-state conditions,which of the following is the best oxidizing agent?H2(g); E° = 0.00 V NO3-(aq)+4H+(aq)+ 3e-Given: Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V NO<sub>3</sub><sup>-</sup>(aq)+4H<sup>+</sup>(aq)+ 3e<sup>-</sup> NO(g)+ 2H<sub>2</sub>O(l); E° = 0.96 V O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l); E° = 1.23 V PbO<sub>2</sub>(s)+ SO<sub>4</sub><sup>2-</sup>(aq)+ 4H<sup>+</sup>(aq)+ 2e<sup>-</sup>  PbSO<sub>4</sub>(s)+ 2H<sub>2</sub>O(l); E° = 1.69 V Under standard-state conditions,which of the following is the best oxidizing agent?NO(g)+ 2H2O(l); E° = 0.96 V O2(g)+ 4H+(aq)+ 4e- Given: Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V NO<sub>3</sub><sup>-</sup>(aq)+4H<sup>+</sup>(aq)+ 3e<sup>-</sup> NO(g)+ 2H<sub>2</sub>O(l); E° = 0.96 V O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l); E° = 1.23 V PbO<sub>2</sub>(s)+ SO<sub>4</sub><sup>2-</sup>(aq)+ 4H<sup>+</sup>(aq)+ 2e<sup>-</sup>  PbSO<sub>4</sub>(s)+ 2H<sub>2</sub>O(l); E° = 1.69 V Under standard-state conditions,which of the following is the best oxidizing agent?2H2O(l); E° = 1.23 V PbO2(s)+ SO42-(aq)+ 4H+(aq)+ 2e- Given: Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V NO<sub>3</sub><sup>-</sup>(aq)+4H<sup>+</sup>(aq)+ 3e<sup>-</sup> NO(g)+ 2H<sub>2</sub>O(l); E° = 0.96 V O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l); E° = 1.23 V PbO<sub>2</sub>(s)+ SO<sub>4</sub><sup>2-</sup>(aq)+ 4H<sup>+</sup>(aq)+ 2e<sup>-</sup>  PbSO<sub>4</sub>(s)+ 2H<sub>2</sub>O(l); E° = 1.69 V Under standard-state conditions,which of the following is the best oxidizing agent?PbSO4(s)+ 2H2O(l); E° = 1.69 V Under standard-state conditions,which of the following is the best oxidizing agent?

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The Faraday constant is defined as

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Given: 2H+(aq)+ 2e- Given: 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V K<sup>+</sup>(aq)+ e<sup>-</sup>  K(s); E° = 2.7182818285 V F<sub>2</sub>(g)+ 2e<sup>-</sup>  2FS1U1 1-</sup>(aq); E° = 2.87 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>  Al(s); E° = -1.66 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Under standard-state conditions,which is the strongest reducing agent?H2(g); E° = 0.00 V K+(aq)+ e- Given: 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V K<sup>+</sup>(aq)+ e<sup>-</sup>  K(s); E° = 2.7182818285 V F<sub>2</sub>(g)+ 2e<sup>-</sup>  2FS1U1 1-</sup>(aq); E° = 2.87 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>  Al(s); E° = -1.66 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Under standard-state conditions,which is the strongest reducing agent?K(s); E° = 2.7182818285 V F2(g)+ 2e- Given: 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V K<sup>+</sup>(aq)+ e<sup>-</sup>  K(s); E° = 2.7182818285 V F<sub>2</sub>(g)+ 2e<sup>-</sup>  2FS1U1 1-</sup>(aq); E° = 2.87 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>  Al(s); E° = -1.66 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Under standard-state conditions,which is the strongest reducing agent?2FS1U1 1-(aq); E° = 2.87 V Al3+(aq)+ 3e- Given: 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V K<sup>+</sup>(aq)+ e<sup>-</sup>  K(s); E° = 2.7182818285 V F<sub>2</sub>(g)+ 2e<sup>-</sup>  2FS1U1 1-</sup>(aq); E° = 2.87 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>  Al(s); E° = -1.66 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Under standard-state conditions,which is the strongest reducing agent?Al(s); E° = -1.66 V Pb2+(aq)+ 2e- Given: 2H<sup>+</sup>(aq)+ 2e<sup>-</sup>  H<sub>2</sub>(g); E° = 0.00 V K<sup>+</sup>(aq)+ e<sup>-</sup>  K(s); E° = 2.7182818285 V F<sub>2</sub>(g)+ 2e<sup>-</sup>  2FS1U1 1-</sup>(aq); E° = 2.87 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>  Al(s); E° = -1.66 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Under standard-state conditions,which is the strongest reducing agent?Pb(s); E° = -0.13 V Under standard-state conditions,which is the strongest reducing agent?

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What is the equilibrium constant (K)at 25°C for the following cell reaction? Sn(​s​)+ Pb2+ ​(​aq​)→ Sn2+ (​aq​)+ Pb(​s​); ​E​°cell = 0.014 V

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In the following electrochemical cell,what is the role of the platinum? Cu(s)| Cu2+(aq)|| Fe3+(aq),Fe2+(aq)| Pt(s)

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Which statement concerning the anode in an electrochemical cell is correct?

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A lead storage battery involves the following two half-reactions: PbSO4(s)+ 2e- → Pb(s)+ SO42-(aq); E° = -0.36 V PbO2(s)+ 4H+(aq)+ SO42-(aq)+ 2e- → PbSO4(s)+ 2H2O(l); E° = 1.69 V During the discharge reaction of the lead storage battery at 1.0 M concentrations,the cell potential and the reducing agent are,respectively,

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Which of the following statements is true for a voltaic (galvanic)cell?

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When balancing oxidation-reduction reactions in acidic solution by the half-reaction method,the addition of the reactant H+ is required to balance the product

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The following cell is initially at standard-state conditions.Which of the following statements is true after the cell is allowed to discharge (do work)for a period of time? The following cell is initially at standard-state conditions.Which of the following statements is true after the cell is allowed to discharge (do work)for a period of time?   Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Zn(s); E° = -0.76 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 V Zn2+(aq)+ 2e- The following cell is initially at standard-state conditions.Which of the following statements is true after the cell is allowed to discharge (do work)for a period of time?   Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Zn(s); E° = -0.76 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 V Zn(s); E° = -0.76 V Cu2+(aq)+ 2e- The following cell is initially at standard-state conditions.Which of the following statements is true after the cell is allowed to discharge (do work)for a period of time?   Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Zn(s); E° = -0.76 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 VCu(s); E° = 0.34 V

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The cell potential of the following cell is determined using an unspecified concentration of acid.What is [H+] given that the measured cell potential is -0.464 V and the anode reduction potential (E°)is 0.222 V at 25°C? ​ Ag(s)| AgCl(s)| Cl−(1.0 M)|| H+(aq,? M)| H2(g,1.0 atm)| Pt(s)

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According to the following cell notation,which species is undergoing oxidation? Zn | Zn2+(aq)|| Mn2+(aq)| MnO2(s)| Pt(s)

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