Exam 15: Chemical Equilibrium

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Living things are in equilibrium with their surroundings.

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According to the collision theory of chemical reactions:

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A system is said to be in dynamic equilibrium when:

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What is the [ What is the [   ] at equilibrium,given AgCl,   ? ] at equilibrium,given AgCl, What is the [   ] at equilibrium,given AgCl,   ? ?

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For the reaction For the reaction   what happens to the equilibrium position if the pressure decreases? what happens to the equilibrium position if the pressure decreases?

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Suppose a wall divides a playground,and twenty balls lie on the ground on the east side,while forty balls lie on the west side.If a child on the east side of the wall always tosses a ball over the wall at the same time a child on the west side tosses a ball over the wall,then:

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What happens to the equilibrium position of an exothermic reaction when you add heat?

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Decreasing the amount of carbon dioxide in the reaction below will cause the reaction to proceed to the right so that equilibrium will be restored. Decreasing the amount of carbon dioxide in the reaction below will cause the reaction to proceed to the right so that equilibrium will be restored.

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What is the What is the   expression for the ionic compound barium phosphate,Ba<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>? expression for the ionic compound barium phosphate,Ba3(PO4)2?

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It is not necessary to have a balanced equation before writing an equilibrium constant expression.

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For the reaction LiOH (s)⇌ Li+ (aq)+ OH- (aq), For the reaction LiOH (s)⇌ Li<sup>+</sup> (aq)+ OH<sup>-</sup> (aq),   = 4.6 ×   ,and the equilibrium concentration for hydroxide ion is [OH<sup>-</sup>] = 0.042 M.What is [Li<sup>+</sup>] at equilibrium? = 4.6 × For the reaction LiOH (s)⇌ Li<sup>+</sup> (aq)+ OH<sup>-</sup> (aq),   = 4.6 ×   ,and the equilibrium concentration for hydroxide ion is [OH<sup>-</sup>] = 0.042 M.What is [Li<sup>+</sup>] at equilibrium? ,and the equilibrium concentration for hydroxide ion is [OH-] = 0.042 M.What is [Li+] at equilibrium?

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Given the choice of adding ions of Mg 2+ (aq),Ca 2+ (aq),Sr 2+ (aq)or Ba 2+ (aq)to a solution of carbonate ions,CO3 2-,which choice would precipitate an insoluble carbonate compound first? Use the following Given the choice of adding ions of Mg <sup>2+</sup> (aq),Ca <sup>2+ </sup>(aq),Sr <sup>2+</sup> (aq)or Ba <sup>2+</sup> (aq)to a solution of carbonate ions,CO<sub>3</sub> <sup>2-</sup>,which choice would precipitate an insoluble carbonate compound first? Use the following   data:  data: Given the choice of adding ions of Mg <sup>2+</sup> (aq),Ca <sup>2+ </sup>(aq),Sr <sup>2+</sup> (aq)or Ba <sup>2+</sup> (aq)to a solution of carbonate ions,CO<sub>3</sub> <sup>2-</sup>,which choice would precipitate an insoluble carbonate compound first? Use the following   data:

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What is the value for the What is the value for the   for a compound MX<sub>2</sub>(s)if at equilibrium   and   ? for a compound MX2(s)if at equilibrium What is the value for the   for a compound MX<sub>2</sub>(s)if at equilibrium   and   ? and What is the value for the   for a compound MX<sub>2</sub>(s)if at equilibrium   and   ? ?

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The Equilibrium Constant, Keq ,is a way to quantify the relative concentrations of the reactants and products of a reaction at equilibrium.

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Consider the reaction: Consider the reaction:    Which of the following will cause a shift in the equilibrium to the right?  1.Add more N<sub>2</sub>O 2.Remove O<sub>2</sub> 3.Remove N<sub>2</sub> Which of the following will cause a shift in the equilibrium to the right? 1.Add more N2O 2.Remove O2 3.Remove N2

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Le Chatelier's principle states that a chemical system must have a shift in direction in order to force the system to reach equilibrium.

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Calculate [ Calculate [   ] at equilibrium given that the   for the reaction  ] at equilibrium given that the Calculate [   ] at equilibrium given that the   for the reaction  for the reaction Calculate [   ] at equilibrium given that the   for the reaction

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Which equilibrium constant represents a reaction that favors the formation of the products to the greatest extent?

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If you have a chamber of gases at equilibrium,compressing the gases to half the original volume would have the same effect as doubling the pressure.

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The rate of a chemical reaction is the amount of reactant that changes to product in a specific amount of time.

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