Exam 13: Chemical Kinetics
Exam 1: Matter, Measurement, and Problem Solving120 Questions
Exam 2: Atoms and Elements116 Questions
Exam 3: Molecules, Compounds and Chemical Equations144 Questions
Exam 4: Chemical Quantities and Aqueous Reactions199 Questions
Exam 5: Gases157 Questions
Exam 6: Thermochemistry110 Questions
Exam 7: The Quantum-Mechanical Model of the Atom100 Questions
Exam 8: Periodic Properties of the Elements120 Questions
Exam 9: Chemical Bonding I: Lewis Theory125 Questions
Exam 10: Chemical Bonding II: Molecular Shapes, Valence Bond Theory, and109 Questions
Exam 11: Liquids, Solids, and Intermolecular Forces123 Questions
Exam 12: Solutions127 Questions
Exam 13: Chemical Kinetics125 Questions
Exam 14: Chemical Equilibrium112 Questions
Exam 15: Acids and Bases126 Questions
Exam 16: Aqueous Ionic Equilibrium148 Questions
Exam 17: Free Energy and Thermodynamics103 Questions
Exam 18: Electrochemistry115 Questions
Exam 19: Radioactivity and Nuclear Chemistry105 Questions
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The aquation of tris-(1,10-phenanthroline)iron(II)in acid solution takes place according to the equation:
Fe(phen)32+ + 3 H3O+ + 3 H2O → Fe(H2O)62+ + 3 phenH+.
If the activation energy,Ea,is 126 kJ/mol and the rate constant at 30°C is 9.8 × 10-3 min-1,what is the rate constant at 35°C?
(Multiple Choice)
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What is the overall order of the following reaction,given the rate law?
2 X + 3 Y → 2 Z Rate = k[X]1[Y]2
(Multiple Choice)
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What is the difference between average reaction rate and instantaneous reaction rate?
(Essay)
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For a reaction that follows the general rate law Rate = k[A][B]2,what will happen to the rate of reaction if the concentration of B is increased by a factor of 3.00? The rate will
(Multiple Choice)
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The rate constant for the first-order decomposition of N2O is 3.40 s-1.What is the half-life of the decomposition?
(Multiple Choice)
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Is the activation energy for a forward reaction the same as the activation energy for the reverse of the same reaction?
(Essay)
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The first-order reaction,SO2Cl2 → SO2 + Cl2,has a rate constant equal to 2.20 × 10-5 s-1 at 593 K.What percentage of the initial amount of SO2Cl2 will remain after 6.00 hours?
(Multiple Choice)
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Given the following balanced equation,determine the rate of reaction with respect to [NOCl].
2 NO(g)+ Cl2(g)→ 2 NOCl(g)
(Multiple Choice)
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If the activation energy for a given compound is found to be 103 kJ/mol,with a frequency factor of 4.0 × 1013 s-1,what is the rate constant for this reaction at 398 K?
(Multiple Choice)
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Which rate law is consistent with the proposed mechanism for the reaction?
NO2(g)+ CO(g)→ NO2(g)+ CO2(g)
Mechanism:
2 NO2(g)→ NO3(g)+ NO(g)(fast)
NO3(g)+ CO(g)→ NO2(g)+ CO2(g)(slow)
(Multiple Choice)
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What are the units of k in the following rate law?
Rate = k[X][Y]1/2
(Multiple Choice)
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Given the following balanced equation,determine the rate of reaction with respect to [SO3].If the rate of O2 loss is 3.56 × 10-3 M/s,what is the rate of formation of SO3?
2 SO2(g)+ O2(g)→ 2 SO3(g)
(Multiple Choice)
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Given the following balanced equation,determine the rate of reaction with respect to [SO2].
2 SO2(g)+ O2(g)→ 2 SO3(g)
(Multiple Choice)
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What are the units of k in the following rate law?
Rate = k[X]2
(Multiple Choice)
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The rate constant for a second-order reaction is 0.54 M-1s-1.What is the half-life of this reaction if the initial concentration is 0.33 M?
(Multiple Choice)
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Explain what the exponential factor in the Arrhenius equation represents.
(Essay)
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Given the following balanced equation,determine the rate of reaction with respect to [H2].
N2(g)+ 3 H2(g)→ 2 NH3(g)
(Multiple Choice)
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The second-order decomposition of NO2 has a rate constant of 0.255 M-1s-1.How much NO2 decomposes in 4.00 s if the initial concentration of NO2 (1.00 L volume)is 1.33 M?
(Multiple Choice)
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