Exam 13: Chemical Kinetics

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For a reaction that follows the general rate law Rate = k[A][B]2,what will happen to the rate of reaction if the concentration of A is increased by a factor of 5.00? The rate will

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Which of the following conditions must be met for a chemical reaction to happen in gas phase?

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Carbon-14,which is present in all living tissue,radioactively decays via a first-order process.A one-gram sample of wood taken from a living tree gives a rate for carbon-14 decay of 13.6 counts per minute.If the half-life for carbon-14 is 5720 years,how old is a wood sample that gives a rate for carbon-14 decay of 11.9 counts per minute?

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Given the following balanced equation,determine the rate of reaction with respect to [O2]. 2 O3(g)→ 3 O2(g)

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Determine the rate law and the value of k for the following reaction using the data provided. 2 N2O5(g)→ 4 NO2(g)+ O2(g) Determine the rate law and the value of k for the following reaction using the data provided. 2 N<sub>2</sub>O<sub>5</sub>(g)→ 4 NO<sub>2</sub>(g)+ O<sub>2</sub>(g)

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Given the following rate law,how does the rate of reaction change if the concentration of X is halved and the concentration of Y is doubled? Rate = k [X][Y]2

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Which of the following represents the equation for a zeroth-order half-life?

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What are the units of k in the following rate law? Rate = k[X][Y]

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The half-life for the decay of radium is 1620 years.What is the rate constant for this first-order process?

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Hydrogen iodide decomposes at 800 K via a second-order process to produce hydrogen and iodine according to the following chemical equation. 2HI(g)→ H2(g)+ I2(g) At 800 K it takes 142 seconds for the initial concentration of HI to decrease from 6.75 × 10-2 M to 3.50 × 10-2 M.What is the rate constant for the reaction at this temperature?

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The first-order decay of radon has a half-life of 3.823 days.How many grams of radon remain after 7.22 days if the sample initially weighs 250.0 grams?

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The elementary reaction 2NO2(g)→ 2NO(g)+ O2(g) Is second order in NO2 and the rate constant at 501 K is 7.93 × 10-3 M-1s-1.The reaction half-life at this temperature when [NO2]0 = 0.45 M is ________ s.

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What is a catalyst and what function does it serve?

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The graph represents the first-order decomposition of N2O5(g)to form NO2(g)and O2(g). N2O5(g)→ 2NO2(g)+1/2O2(g) What will be the N2O5 concentration after 7.0 hours? The graph represents the first-order decomposition of N<sub>2</sub>O<sub>5</sub>(g)to form NO<sub>2</sub>(g)and O<sub>2</sub>(g). N<sub>2</sub>O<sub>5</sub>(g)→ 2NO<sub>2</sub>(g)+1/2O<sub>2</sub>(g) What will be the N<sub>2</sub>O<sub>5</sub> concentration after 7.0 hours?

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A decomposition reaction has a half-life that does not depend on the initial concentration of the reactant.What is the order of the reaction?

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If the activation energy for a given compound is found to be 42.0 kJ/mol,with a frequency factor of 8.0 × 1010 s-1,what is the rate constant for this reaction at 298 K?

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Determine the rate law and the value of k for the following reaction using the data provided. S2O82⁻(aq)+ 3 I⁻(aq)→ 2 SO42⁻(g)+ I3⁻(aq) Determine the rate law and the value of k for the following reaction using the data provided. S<sub>2</sub>O<sub>8</sub><sup>2</sup>⁻(aq)+ 3 I⁻(aq)→ 2 SO<sub>4</sub><sup>2</sup>⁻(g)+ I<sub>3</sub>⁻(aq)

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What is the overall order of the following reaction,given the rate law? NO(g)+ O3(g)→ NO2(g)+ O2(g)Rate = k[NO][O3]

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How many half-lives are required for the concentration of reactant to decrease to 3.1% of its original value?

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What are the units of k in a first order reaction?

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