Exam 17: Gibbs Energy and Thermodynamics

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Calculate ΔrG at 298 K under the conditions shown below for the following reaction: Fe2O3(s)+ 3CO(g)→ 2Fe(s)+ 3CO2(g)ΔG° = -28.0 kJ mol-1 P(CO)= 1.4 atm, P(CO2)= 2.1 atm

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Which of the following processes have a ΔrS > 0?

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Consider a reaction that has a positive ΔrH and a positive ΔrS. Which of the following statements is TRUE?

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Which one of the following has the highest standard molar entropy, S°, at 25 °C?

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Consider a reaction that has a positive ΔrH and a negative ΔrS. Which of the following statements is TRUE?

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Define the second law of thermodynamics.

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Choose the statement below that is TRUE.

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Which of the following relationships is correct at constant T and P?

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Which of the following is TRUE if ln K is zero?

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Given the following equation, N2O(g)+ NO2(g)→ 3NO(g)ΔrG° = -23.0 kJ mol-1 Calculate ΔrG° for the following reaction: 3N2O(g)+ 3NO2(g)→ 9NO(g)

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Use Hess's law to calculate ΔrG° using the following information: NO(g)+ O(g)→ NO2(g)ΔrG° = ? 2O3(g)→ 3O2(g)ΔrG° = +489.6 kJ mol-1 O2(g)→ 2O(g)ΔrG° = +463.4 kJ mol-1 NO(g)+ O3(g)→ NO2(g)+ O2(g)ΔrG° = - 199.5 kJ mol-1

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