Exam 9: Chemical Bonding I: Lewis Theory

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Place the following in order of decreasing XO bond length, where "X" represents the central atom in each of the following compounds or ions: SiO32⁻ CO2 CO32⁻

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Choose the best Lewis structure for BF3.

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Use the data given below to construct a Born-Haber cycle to determine the second ionization energy of Ca. ΔH°(kJ mol-1) Ca(s)→ Ca(g)193 Ca(g)→ Ca⁺(g)+ e⁻ 590. 2O(g)→ O2(g)-498 O(g)+ e⁻ → O⁻(g) -141 O⁻(g)+ e⁻ → O2⁻(g)878 Ca(s)+ Use the data given below to construct a Born-Haber cycle to determine the second ionization energy of Ca. ΔH°(kJ mol<sup>-1</sup>) Ca(s)→ Ca(g)193 Ca(g)→ Ca⁺(g)+ e⁻ 590. 2O(g)→ O<sub>2</sub>(g)-498 O(g)+ e⁻ → O⁻(g) -141 O⁻(g)+ e⁻ → O<sup>2</sup>⁻(g)878 Ca(s)+   O<sub>2</sub>(g)→ CaO(s)-635 Ca<sup>2</sup>⁺(g)+ O<sup>2</sup>⁻(g)→ CaO(s)-3414 O2(g)→ CaO(s)-635 Ca2⁺(g)+ O2⁻(g)→ CaO(s)-3414

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Which of the following statements is TRUE?

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Choose the compound below that should have the lowest melting point according to the ionic bonding model.

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Draw the Lewis structure for BrO3⁻. Make sure to include any important resonance structures.

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Using Lewis structures and formal charge, which of the following ions is most stable? OCN⁻ ONC⁻ NOC⁻

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Using periodic trends, place the following bonds in order of decreasing ionic character. Sb-Cl P-Cl As-Cl

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Of the following elements, which has the highest electronegativity?

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Place the following in order of decreasing magnitude of lattice energy. K2O Rb2S Li2O

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Choose the bond below that is most polar.

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Choose the bond below that is most polar.

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Which of the following resonance structures for OCN⁻ will contribute most to the correct structure of OCN⁻?

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Which compound has the highest carbon-carbon bond strength?

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Draw the Lewis structure for the acetate ion CH3CO2⁻, including any important resonance structures. Label each atom with its formal charge.

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Use the data given below to construct a Born-Haber cycle to determine the lattice energy of CaO. ΔH°(kJ mol-1) Ca(s)→ Ca(g)193 Ca(g)→ Ca⁺(g)+ e⁻ 590 Ca⁺(g)→ Ca2⁺(g)+ e⁻ 1010 2O(g)→ O2(g)-498 O(g)+ e⁻ → O⁻(g) -141 O⁻(g)+ e⁻ → O2⁻(g)878 Ca(s)+ Use the data given below to construct a Born-Haber cycle to determine the lattice energy of CaO. ΔH°(kJ mol<sup>-1</sup>) Ca(s)→ Ca(g)193 Ca(g)→ Ca⁺(g)+ e⁻ 590 Ca⁺(g)→ Ca<sup>2</sup>⁺(g)+ e⁻ 1010 2O(g)→ O<sub>2</sub>(g)-498 O(g)+ e⁻ → O⁻(g) -141 O⁻(g)+ e⁻ → O<sup>2</sup>⁻(g)878 Ca(s)+   O<sub>2</sub>(g)→ CaO(s)-635 O2(g)→ CaO(s)-635

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How are electron affinity and electronegativity different?

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Which of the following ionic compounds would be expected to have the highest lattice energy?

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Choose the best Lewis structure for CH2Cl2.

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Explain why the lattice energy of MgS is approximately four times as large as that of NaCl.

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