Exam 22: Heat Engines, Entropy, and the Second Law of Thermodynamics

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An engine is designed to obtain energy from the temperature gradient of the ocean. What is the thermodynamic efficiency of such an engine if the temperature of the surface of the water is 59°F (15°C) and the temperature well below the surface is 41°F (5°C)?

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By operating a reversible heat engine with an ideal gas as the working substance in a Carnot cycle and measuring the ratio Qc/Qh, we can calculate

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The change in entropy of 1.00 kg of water that is heated from 50°C to 100°C is (in cal/K)

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An ideal gas is allowed to undergo a free expansion. If its initial volume is V1 and its final volume is V2, the change in entropy is

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What is the probability of rolling either a 7 or 11 on a single roll of a pair of dice?

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An ideal heat engine can have an efficiency of 1 if the temperature of the low temperature reservoir is

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A gasoline engine absorbs 2 500 J of heat and performs 1 000 J of mechanical work in each cycle. The efficiency of the engine is

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The change in entropy of a mass m of a solid substance which has a latent heat of fusion L and melts at a temperature T is

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For a pair of dice, how many microstates are there that result in the macrostate of rolling a 7?

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One kilogram of chilled water at 32°F (0°C) is placed in a freezer which is kept at 0°F (−18°C). Approximately how much electric energy (in kilocalories) is needed to operate the compressor to cool this water to 0°F if the room temperature is maintained at 75°F (24°C)? (Lice = 3.33 × 105 J/kg; cice = 2.09 × 103 J/kg⋅°C)

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Find the change in entropy (in J/K) when 5.00 moles of an ideal gas undergo a free expansion from an initial volume of 20 cm3 to a final volume of 100 cm3.

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An 800-MW electric power plant has an efficiency of 30%. It loses its waste heat in large cooling towers. Approximately how much waste heat (in MJ) is discharged to the atmosphere per second?

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On a cold day, a heat pump absorbs heat from the outside air at 14°F (−10°C) and transfers it into a home at a temperature of 86°F (30°C). Determine the maximum κ of the heat pump.

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All real engines are less efficient than the Carnot engine because

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One kilogram of chilled water (0°C) is placed in a freezer which is kept at 0°F (−18°C). Approximately how much electric energy (in kilocalories) is needed just to freeze the water if the room temperature is maintained at 75°F (24°C)? (Lice = 333 J/g; cice = 209 J/g⋅°C.)

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