Exam 16: Aldehydes and Ketones

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The reaction below illustrates oxidation of an aldehyde. The reaction below illustrates oxidation of an aldehyde.

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In the correct order,what are the three reactions that convert all-trans-retinal into 11-cis-retinal so that the process of vision can continue?

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Acetals are ethers.

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Aldehydes and ketones undergo addition reactions with alcohols (ROH)to form hemiacetals and acetals.

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What type of compound is shown below? What type of compound is shown below?

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The Tollens reagent is which of the following?

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The simplest ketone has a much higher boiling point than the simplest aldehyde.

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What is the name of the compound below? What is the name of the compound below?

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Triamcinolone acetonide (structure shown),a synthetic corticosteroid drug,contains an acetal. Triamcinolone acetonide (structure shown),a synthetic corticosteroid drug,contains an acetal.

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In a process similar to the one characterized by glucose,the ketone below forms the indicated hemiacetal product. In a process similar to the one characterized by glucose,the ketone below forms the indicated hemiacetal product.

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The IUPAC name of the compound below is 2-methyl-2-propylpropanal. The IUPAC name of the compound below is 2-methyl-2-propylpropanal.

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What is the structure of 3-hydroxy-2-methylbenzaldehyde?

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The carbohydrate glucose exists predominantly as a cyclic hemiacetal.

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Acetals are stable molecules,but they can be converted back to aldehydes and ketones by treatment with acid and water.

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The ketone below produces the indicated product upon oxidation with K2Cr2O7. The ketone below produces the indicated product upon oxidation with K<sub>2</sub>Cr<sub>2</sub>O<sub>7</sub>.

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When light hits the retina,the 11-cis double bond of 11-cis-retinal is isomerized to its more stable trans isomer,and the all-trans-retinal is formed.

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What is the structure of 2-bromo-5-hydroxyheptanal?

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Aldehydes play an important role in the sun tanning industry as the active ingredient in commercial tanning agents that produce sunless tans.

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D-Glucose,shown below,will give a positive Tollens test. D-Glucose,shown below,will give a positive Tollens test.

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Which reactant would be needed to form the alcohol product shown below by a reduction reaction? Which reactant would be needed to form the alcohol product shown below by a reduction reaction?

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