Exam 14: Chemical Kinetics

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The reaction CH3- N≡C - CH3- C≡N Is a first- order reaction. At 230.3°C, k = 6.29 × 10- 4 s- 1. If [CH3- N≡C] is 1.00 × 10- 3 initially, [CH3- N≡C] is after 1.000 × 103 s.

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The kinetics of the reaction below were studied and it was determined that the reaction rate increased by a factor of 9 when the concentration of B was tripled. The reaction is order in B. A + B → P

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The following reaction occurs in aqueous solution: NH4+ (aq) + NO2- →N2 (g) + 2H2O (l) The data below is obtained at 25°C. The following reaction occurs in aqueous solution: NH<sub>4</sub><sup>+</sup><sup> </sup>(aq) + NO<sub>2</sub><sup>-</sup><sup> </sup><sup> </sup>→N<sub>2</sub><sub> </sub>(g) + 2H<sub>2</sub>O (l) The data below is obtained at 25°C.   The order of the reaction in NH<sub>4</sub><sup>+</sup><sup> </sup>is _ . The order of the reaction in NH4+ is _ .

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The rate of disappearance of HBr in the gas phase reaction 2HBr (g) →H2 (g) + Br2 (g) Is 0.301 M s- 1 at 150°C. The rate of appearance of Br2 is M s- 1.

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In the energy profile of a reaction, the species that exists at the maximum on the curve is called the )

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For the reaction aA + Bb → cC + dD the rate law is .

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The earth's ozone layer is located in the .

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Of the following, all are valid units for a reaction rate except _.

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The rate law for a reaction is Rate = k [A][B]2 Which one of the following statements is false?

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Units of the rate constant of a reaction are independent of the overall reaction order.

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