Exam 14: Chemical Kinetics

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The combustion of ethylene proceeds by the reaction C2H4 (g) + 3O2 (g) → 2CO2 (g) + 2H2O (g) When the rate of disappearance of O2 is 0.23 M s- 1, the rate of disappearance of C2H4 is M s- 1.

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A burning splint will burn more vigorously in pure oxygen than in air because

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Which substance in the reaction below either appears or disappears the fastest? 4NH3 + 7O2 → 4NO2 + 6H2O

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The concentration of S2O82- remaining at 800 s is _ M.

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The active site of nitrogenase is a cofactor that contains two transition metals. These transition metals are .

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The rate law of a reaction is rate = k[D][X]. The units of the rate constant are _ _.

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A particular first- order reaction has a rate constant of 1.35 × 102 s- 1 at 25°C. What is the magnitude of k at 75°C if Ea = 85.6 kJ/mol?

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A reaction was found to be zero order in A. Increasing the concentration of A by a factor of 3 will cause the reaction rate to .

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A first- order reaction has a rate constant of 0.33 min- 1. It takes min for the reactant concentration to decrease from 0.13 M to 0.088 M.

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The overall order of a reaction is 2. The units of the rate constant for the reaction are .

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SO2Cl2 decomposes in the gas phase by the reaction SO2Cl2 (g) →SO2 (g) + Cl2 (g) The reaction is first order in SO2Cl2 and the rate constant is 3.0 × 10- 6 s- 1at 600 K. A vessel is charged with 3.3 atm of SO2Cl2 at 600 K. The partial pressure of SO2 at 3.0 × 105 s is _ _ atm.

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For a first- order reaction, a plot of versus is linear.

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are used in automotive catalytic converters.

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The reaction A - B is first order in [A]. Consider the following data. The reaction A - B is first order in [A]. Consider the following data.   -The half- life of this reaction is s. -The half- life of this reaction is s.

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The rate law of the overall reaction The rate law of the overall reaction   is rate = k[A]<sup>2</sup>. Which of the following will not increase the rate of the reaction? is rate = k[A]2. Which of the following will not increase the rate of the reaction?

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The reaction A - B is first order in [A]. Consider the following data. The reaction A - B is first order in [A]. Consider the following data.   -The concentration of A is M after 40.0 s. -The concentration of A is M after 40.0 s.

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Nitrogen fixation is a difficult process because .

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Of the following, will lower the activation energy for a reaction.

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The data in the table below were obtained for the reaction: 2 ClO2 (aq) + 2 OH- (aq) →ClO3- (aq) + ClO2- (aq) + H2O (1) The data in the table below were obtained for the reaction: 2 ClO<sub>2 </sub>(aq) + 2 OH<sup>- </sup>(aq) →ClO<sub>3</sub><sup>- </sup>(aq) + ClO<sub>2</sub><sup>- </sup>(aq) + H<sub>2</sub>O (1)   -What is the order of the reaction with respect to ClO<sub>2</sub>? -What is the order of the reaction with respect to ClO2?

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As the temperature of a reaction is increased, the rate of the reaction increases because the

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